Thallium triiodide, more precisely thallium(I) triiodide is a chemical compound of thallium and iodine with empirical formula TlI3. Unlike the other thallium trihalides, which contain thallium(III), TlI3 is actually a thallium(I) salt containing thallium(I) cations Tl+ and triiodide anions [I3]−, and thus has the chemical formula Tl+[I3]−. It is a black crystalline solid.