Example: Ideal Gas Law The
ideal gas law relates the
state variables of pressure (P), volume (V), and temperature (T) via :PV=nRT which can be written as :f(P,V,T) = PV-nRT = 0 so each state variable can be written as an implicit function of the other state variables: : \begin{align} P &= P(V,T) = \frac{nRT}{V} \\[1em] V &= V(P,T) = \frac{nRT}{P} \\[1em] T &= T(P,V) = \frac{PV}{nR} \end{align} From the above expressions, we have : \begin{align} -1 &= \left( \frac{\partial P}{\partial V} \right) \left( \frac{\partial V}{\partial T} \right) \left( \frac{\partial T}{\partial P} \right) \\[1em] &= \left( -\frac{nRT}{V^2} \right) \left( \frac{nR}{P} \right) \left( \frac{V}{nR} \right) \\[1em] &= \left( -\frac{nRT}{PV} \right) \\[1em] & = -\frac{P}{P} = -1 \end{align}
Geometric Realization A geometric realization of the triple product rule can be found in its close ties to the velocity of a traveling wave :\phi(x,t) = A \cos (kx - \omega t) shown on the right at time
t (solid blue line) and at a short time later
t+Δ
t (dashed). The wave maintains its shape as it propagates, so that a point at position
x at time
t will correspond to a point at position
x+Δ
x at time
t+Δ
t, :A \cos (kx - \omega t) = A \cos (k (x + \Delta x) - \omega (t + \Delta t)). This equation can only be satisfied for all
x and
t if , resulting in the formula for the
phase velocity : v = \frac{\Delta x}{\Delta t} = \frac{\omega}{k}. To elucidate the connection with the triple product rule, consider the point
p1 at time
t and its corresponding point (with the same height)
p̄1 at
t+Δ
t. Define
p2 as the point at time
t whose x-coordinate matches that of
p̄1, and define
p̄2 to be the corresponding point of
p2 as shown in the figure on the right. The distance Δ
x between
p1 and
p̄1 is the same as the distance between
p2 and
p̄2 (green lines), and dividing this distance by Δ
t yields the speed of the wave. To compute Δ
x, consider the two partial derivatives computed at
p2, : \left( \frac{\partial \phi}{\partial t} \right) \Delta t = \text{rise from }p_2\text{ to }\bar{p}_1\text{ in time }\Delta t\text{ (gold line)} : \left( \frac{\partial \phi}{\partial x} \right) = \text{slope of the wave (red line) at time }t. Dividing these two partial derivatives and using the definition of the slope (rise divided by run) gives us the desired formula for : \Delta x = - \frac{\left( \frac{\partial \phi}{\partial t} \right) \Delta t}{\left( \frac{\partial \phi}{\partial x} \right)}, where the negative sign accounts for the fact that
p1 lies behind
p2 relative to the wave's motion. Thus, the wave's velocity is given by : v = \frac{\Delta x}{\Delta t} = - \frac{\left( \frac{\partial \phi}{\partial t} \right)}{\left( \frac{\partial \phi}{\partial x} \right)}. For infinitesimal Δ
t, \frac{\Delta x}{\Delta t} = \left( \frac{\partial x}{\partial t} \right) and we recover the triple product rule : v = \frac{\Delta x}{\Delta t} = - \frac{\left( \frac{\partial \phi}{\partial t} \right)}{\left( \frac{\partial \phi}{\partial x} \right)}. ==See also==