On 8 October 1839 she married Alexandre Edmond de
Talleyrand-Périgord,
Duke of Dino, son of
Edmond de Talleyrand-Périgord, Duke of Talleyrand and
Princess Dorothea of Courland, at the
Château de Beauregard at
Cellettes (
Loir-et-Cher), her mother's property. With Talleyrand-Périgord, Valentine had six children, of whom four survived: •
Clémentine Marie Wilhelmine de Talleyrand-Périgord (1841–1881), who married Count Alexandre
Orlowski. •
Charles Maurice Camille de Talleyrand-Périgord (1843–1917), 4th duke of Dino, 2nd marquis de Talleyrand. • Elisabeth Alexandrine Florence de Talleyrand-Périgord (1844–1880), who married Count Hans von
Oppersdorff. •
Archambault Anatole Paul de Talleyrand-Périgord (1845–1918), 3rd marquis de Talleyrand. Valentine died on 23 September 1891. ==References==