Van der Pauw method

There are five conditions that must be satisfied to use this technique:1. The sample must have a flat shape of uniform thickness2. The sample must not have any isolated holes3. The sample must be homogeneous and isotropic4. All four contacts must be located at the edges of the sample5. The area of contact of any individual contact should be at least an order of magnitude smaller than the area of the entire sample. The second condition can be weakened. The van der Pauw technique can also be applied to samples with one hole. == Sample preparation ==

In order to use the van der Pauw method, the sample thickness must be much less than the width and length of the sample. In order to reduce errors in the calculations, it is preferable that the sample be symmetrical. There must also be no isolated holes within the sample. The measurements require that four ohmic contacts be placed on the sample. Certain conditions for their placement need to be met: • They must be as small as possible; any errors given by their non-zero size will be of the order D/L, where D is the average diameter of the contact and L is the distance between the contacts. • They must be as close as possible to the boundary of the sample. In addition to this, any leads from the contacts should be constructed from the same batch of wire to minimise thermoelectric effects. For the same reason, all four contacts should be of the same material. == Measurement definitions ==

• The contacts are numbered from 1 to 4 in a counter-clockwise order, beginning at the top-left contact. • The current I12 is a positive DC current injected into contact 1 and taken out of contact 2, and is measured in amperes (A). • The voltage V34 is a DC voltage measured between contacts 3 and 4 (i.e. V4 - V3) with no externally applied magnetic field, measured in volts (V). • The resistivity ρ is measured in ohms⋅metres (Ω⋅m). • The thickness of the sample t is measured in metres (m). • The sheet resistance RS is measured in ohms per square (Ω/sq or \Omega/\Box). == Resistivity measurements ==

The average resistivity of a sample is given by ρ = RS⋅t, where the sheet resistance RS is determined as follows. For an anisotropic material, the individual resistivity components, e.g. ρx or ρy, can be calculated using the Montgomery method. Basic measurements To make a measurement, a current is caused to flow along one edge of the sample (for instance, I12) and the voltage across the opposite edge (in this case, V34) is measured. From these two values, a resistance (for this example, R_{12,34}) can be found using Ohm's law: :R_{12,34} = \frac{V_{34}}{I_{12}} In his paper, van der Pauw showed that the sheet resistance of samples with arbitrary shapes can be determined from two of these resistances - one measured along a vertical edge, such as R_{12,34}, and a corresponding one measured along a horizontal edge, such as R_{23,41}. The actual sheet resistance is related to these resistances by the van der Pauw formula :e^{-\pi R_{12,34}/R_s}+e^{-\pi R_{23,41}/R_s}=1 Reciprocal measurements The reciprocity theorem tells us that R_{AB,CD} = R_{CD,AB} Therefore, it is possible to obtain a more precise value for the resistances R_{12,34} and R_{23,41} by making two additional measurements of their reciprocal values R_{34,12} and R_{41,23} and averaging the results. We define R_{\text{vertical}} = \frac{R_{12,34} + R_{34,12}}{2} and R_{\text{horizontal}} = \frac{R_{23,41} + R_{41,23}}{2} Then, the van der Pauw formula becomes e^{-\pi R_{\text{vertical}}/R_S}+e^{-\pi R_{\text{horizontal}}/R_S}=1 Reversed polarity measurements A further improvement in the accuracy of the resistance values can be obtained by repeating the resistance measurements after switching polarities of both the current source and the voltage meter. Since this is still measuring the same portion of the sample, just in the opposite direction, the values of Rvertical and Rhorizontal can still be calculated as the averages of the standard and reversed polarity measurements. The benefit of doing this is that any offset voltages, such as thermoelectric potentials due to the Seebeck effect, will be cancelled out. Combining these methods with the reciprocal measurements from above leads to the formulas for the resistances being :R_{\text{vertical}} = \frac{R_{12,34} + R_{34,12} + R_{21,43} + R_{43,21}}{4} and :R_{\text{horizontal}} = \frac{R_{23,41} + R_{41,23} + R_{32,14} + R_{14,32}}{4} The van der Pauw formula takes the same form as in the previous section. Measurement accuracy Both of the above procedures check the repeatability of the measurements. If any of the reversed polarity measurements don't agree to a sufficient degree of accuracy (usually within 3%) with the corresponding standard polarity measurement, then there is probably a source of error somewhere in the setup, which should be investigated before continuing. The same principle applies to the reciprocal measurements – they should agree to a sufficient degree before they are used in any calculations. Calculating sheet resistance In general, the van der Pauw formula cannot be rearranged to give the sheet resistance RS in terms of known functions. The most notable exception to this is when Rvertical = R = Rhorizontal; in this scenario the sheet resistance is given by : R_S = \frac{\pi R}{\ln 2} The quotient \pi/\ln 2 is known as the van der Pauw constant and has approximate value 4.53236. In most other scenarios, an iterative method is used to solve the van der Pauw formula numerically for RS. Typically a formula is considered to fail the preconditions for Banach Fixed Point Theorem, so methods based on it do not work. Instead, nested intervals converge slowly but steadily. Recently, however, it has been shown that an appropriate reformulation of the van der Pauw problem (e.g., by introducing a second van der Pauw formula) makes it fully solvable by the Banach fixed point method. Alternatively, a Newton-Raphson method converges relatively quickly. To reduce the complexity of the notation, the following variables are introduced: : s = e^{-\pi/{R_s}} : R_v = R_{vertical} : R_h = R_{horizontal} Then the next approximation R_s^+ is calculated by : R_s^+ = R_s + R_s^2\frac{1-s^{R_v} - s^{R_h}}{\pi (R_v s^{R_v} + R_h s^{R_h})} == Hall measurements ==

Background When a charged particle—such as an electron—is placed in a magnetic field, it experiences a Lorentz force proportional to the strength of the field and the velocity at which it is traveling through it. This force is strongest when the direction of motion is perpendicular to the direction of the magnetic field; in this case the force :F_L = qvB\,\! where q is the charge on the particle in coulombs, v the velocity it is traveling at (centimeters per second), and B the strength of the magnetic field (Wb/cm2). Note that centimeters are often used to measure length in the semiconductor industry, which is why they are used here instead of the SI units of meters. When a current is applied to a piece of semiconducting material, this results in a steady flow of electrons through the material (as shown in parts (a) and (b) of the accompanying figure). The velocity the electrons are traveling at is (see electric current): :v = \frac{I}{nAq} where n is the electron density, A is the cross-sectional area of the material and q the elementary charge (1.602×10−19 coulombs). If an external magnetic field is then applied perpendicular to the direction of current flow, then the resulting Lorentz force will cause the electrons to accumulate at one edge of the sample (see part (c) of the figure). Combining the above two equations, and noting that q is the charge on an electron, results in a formula for the Lorentz force experienced by the electrons: :F_L = \frac{IB}{nA} This accumulation will create an electric field across the material due to the uneven distribution of charge, as shown in part (d) of the figure. This in turn leads to a potential difference across the material, known as the Hall voltage V_H. The current, however, continues to only flow along the material, which indicates that the force on the electrons due to the electric field balances the Lorentz force. Since the force on an electron from an electric field \epsilon is q\epsilon, we can say that the strength of the electric field is therefore :\epsilon = \frac{IB}{qnA} Finally, the magnitude of the Hall voltage is simply the strength of the electric field multiplied by the width of the material; that is, :\begin{align} V_H &= w\epsilon \\ &= \frac{wIB}{qnA} \\ &= \frac{IB}{qnt} \end{align} where t is the thickness of the material. Since the sheet density n_s is defined as the density of electrons multiplied by the thickness of the material, we can define the Hall voltage in terms of the sheet density: :V_H = \frac{IB}{qn_s} Making the measurements Two sets of measurements need to be made: one with a magnetic field in the positive z-direction as shown above, and one with it in the negative z-direction. From here on in, the voltages recorded with a positive field will have a subscript P (for example, V13, P = V3, P - V1, P) and those recorded with a negative field will have a subscript N (such as V13, N = V3, N - V1, N). For all of the measurements, the magnitude of the injected current should be kept the same; the magnitude of the magnetic field needs to be the same in both directions also. First of all with a positive magnetic field, the current I24 is applied to the sample and the voltage V13, P is recorded; note that the voltages can be positive or negative. This is then repeated for I13 and V42, P. As before, we can take advantage of the reciprocity theorem to provide a check on the accuracy of these measurements. If we reverse the direction of the currents (i.e. apply the current I42 and measure V31, P, and repeat for I31 and V24, P), then V13, P should be the same as V31, P to within a suitably small degree of error. Similarly, V42, P and V24, P should agree. Having completed the measurements, a negative magnetic field is applied in place of the positive one, and the above procedure is repeated to obtain the voltage measurements V13, N, V42, N, V31, N and V24, N. Calculations Initially, the difference of the voltages for positive and negative magnetic fields is calculated: V13 = V13, P − V13, N V24 = V24, P − V24, N V31 = V31, P − V31, N V42 = V42, P − V42, N The overall Hall voltage is then :V_H = \frac{V_{13} + V_{24} + V_{31} + V_{42}}{8}. The polarity of this Hall voltage indicates the type of material the sample is made of; if it is positive, the material is P-type, and if it is negative, the material is N-type. The formula given in the background can then be rearranged to show that the sheet density :n_s = \frac{IB}{q|V_H|} Note that the strength of the magnetic field B needs to be in units of Wb/cm2 if ns is in cm−2. For instance, if the strength is given in the commonly used units of teslas, it can be converted by multiplying it by 10−4. == Other calculations ==

Mobility The resistivity of a semiconductor material can be shown to be :\rho = \frac{1}{q(n\mu_n + p\mu_p)} where n and p are the concentration of electrons and holes in the material respectively, and μn and μp are the mobility of the electrons and holes respectively. Generally, the material is sufficiently doped so that there is a difference of many orders-of-magnitude between the two concentrations, allowing this equation to be simplified to :\rho = \frac{1}{qn_m\mu_m} where nm and μm are the doping level and mobility of the majority carrier respectively. If we then note that the sheet resistance RS is the resistivity divided by the thickness of the sample, and that the sheet density nS is the doping level multiplied by the thickness, we can divide the equation through by the thickness to get :R_s = \frac{1}{qn_s\mu_m} This can then be rearranged to give the majority carrier mobility in terms of the previously calculated sheet resistance and sheet density: :\mu_m = \frac{1}{qn_sR_s} == Footnotes ==