Victor Gankin was the principal inventor of the novel (“recycle”) process of
isoprene and other synthetic
rubber components production (references to patents from the CV). The recycle process prevented an impending ecological crisis by replacing the conventional manufacturing process dumping of over 20 thousand none-degradable toxic organic materials annually into the Volga and other rivers. The process allowed for reagents recycling while reducing the manufacturing costs by over 20%. The recycle process was implemented in
Tolyatti,
Chaikovsk,
Nizhnekamsk (Russia). Victor Gankin discovered and described the mechanism of the hydroformylation reaction and the new type of chemically active particles: coordinately unsaturated compounds (coined term Conences). Novel processes invented and developed by Victor were implemented in
Angarsk (butyl alcohols),
Salavat,
Perm. The new paradigms and principles proposed by Victor Gankin are as follows: 1) The physical nature of chemical bonding can be explained in the framework of the classical phenomenological approach. 2) One and the same model describes both covalent and ionic bonding. 3) The valence of atoms is defined by the number of electrons in the outermost layer of the atom and by the maximal number of electrons that can be situated in the outermost layer of the atom. 4) The equalization of bond lengths and energies, and the increase of the thermal stability of chemical compounds, described as identical relative to the energy of the Lewis structures, is explained by the electron-nuclear isomerization. Victor Gankin co-authored several
monographs on oxosynthesis and theoretical chemistry, 152 scientific papers in Soviet and international journals and 129 Russian and international patents. 1959-1963 Victor led the discovery, investigation and full development of the oxosynthesis processes of C4 and C6-C8 aldehydes formation with low
cobalt concentration (0.01%). 1963-1966 Victor led the discovery and laboratory investigation of 3-
methylgexanol production from 2-
methylpentene. Got patent 249,353 (USSR). 1966-1970 Victor led the discovery, investigation and full development of the oxosynthesis process of C4 aldehyde using novel naphtheno-evaporative scheme.
Patents: NN 661,724 (
Italy); 100,2691 (
UK), 1,315,589 (
France); 169,103; 178,814; 245,759 (USSR). 1970-1972 Victor investigated and tested on a pilot scale the novel process of esters production by oxosynthesis using the cobalt catalyst modified by piridins. Process decreased the amount of byproducts by 50% and increased the yield of normal alcohols by 20%. 1971-1974 Victor discovered, investigated and tested on a pilot scale of the novel process of α-branched acids production from olefines. Process allows to obtain individual α-acids higher than C9 able to form stable esters. 1973-1978 Victor discovered, investigated and fully developed the isoprene production from formaldehyde and isobutylene via dimethyldioxane with full catalyst recycle. 1978-1980 Victor discovered and investigated the process of the styrol production from toluene while saving the methyl group in toluene. Patents: NN 4,192,961 (USA); 1,538,670 (UK). 1980-1984 Victor discovered and investigated the novel process of high (>C15) normal dicarbonic acids production from unsaturated carbon acids. 1984-1988 Victor discovered, investigated and tested on a pilot scale the novel process of methylethyl ketone production from isobutyric aldehyde. Process obtains 2-ethylgexanol and methylethyl ketone from propylene by oxosynthesis without byproducts. 1988-1991 Victor discovered, investigated and fully developed the isoprene and dimethyl vinyl carbinol production via methyl butanediol while decreasing the manufacturing costs of both products by 24%. == Bibliography ==