Williams attended
Concordia University until 1998, where he played on their ice hockey team for two seasons where he recorded 25 points. When he left college, Williams was signed by the
Indianapolis Ice formerly of the
IHL. After 33 games with Indianapolis, Williams was signed by the
Columbus Chill of the
ECHL where he tallied 13 points in 43 games. In 1999-2000, Williams was acquired by the
Trenton Titans and played in 1 game for the
AHL's
Lowell Lock Monsters, the furthest he's progress professionally. Williams split time with Trenton and the
Orlando Solar Bears formerly of the
IHL. In 2001-2002 Williams once again changed teams, heading to the
Florida Everblades of the
ECHL where he exploded for a career high 22 points in 70 games. The next season, Williams was traded back to the Titans. In the final three seasons of his playing career, Williams' offensive numbers decreased and his penalty minutes increased dramatically, as he took on more of a leadership role for the Titans. The team's efforts culminated in a
Kelly Cup victory in
2004–05 ECHL season. Vince Williams proceeded to retire following the
2005–06 ECHL season. ==Coaching career==