In June 2015,
NASA reported the exoplanet has a
stratosphere, and the
atmosphere contains
titanium monoxide, which creates the stratosphere. Titanium monoxide is one of only a few compounds that is a strong absorber of visible and
ultraviolet radiation, which heats the atmosphere, and is able to exist in a gas state in a hot atmosphere. This was later confirmed using high-resolution spectroscopy technique with the data taken by High Dispersion Spectrograph mounted on the 8.2 m
Subaru Telescope. The detection titanium monoxide was not be able to be reproduced with the higher quality data obtained by 2020 although with different setting of observations. Only upper limit of titanium monoxide volume mixing rate equal to 1
ppb can be obtained. Later research reconfirmed the existence of titanium monoxide in the atmosphere of WASP-33b, although in concentrations not detectable by
HARPS-N. The neutral
iron and
silicon were also detected. In 2020, with the detection of secondary eclipses (when the planet is blocked by its star), the mass of the planet along with temperature profile across its surface was measured.
WASP-33b has strong winds in its atmosphere, similar to
Venus, shifting the hottest spot 28.7±7.1
degrees to the west. The averaged wind speed is 8.5 km/s in the thermosphere. The illuminated side brightness temperature is , while the nightside brightness temperature is . The
water in dayside atmosphere of WASP-33b is mostly dissociated to
hydroxyl radicals due to high temperature, as planetary emission spectra indicated which was the first detected hydroxyl radicals on a planet outside the
Solar System. ==Non-Keplerian features of motion for WASP-33b==