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Witherite

Witherite is a barium carbonate mineral, BaCO3, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The specific gravity is 4.3, which is high for a translucent mineral. It fluoresces light blue under both long- and short-wave UV light, and is phosphorescent under short-wave UV light.

Discovery
In 1789 the German geologist Abraham Gottlob Werner named the mineral witherite in honour of William Withering. The Matthew Boulton mineral collection of Birmingham Museum and Art Gallery may contain one of the earliest known specimens of witherite. A label in Boulton's handwriting, records: "No.2 Terra Ponderosa Aerata, given me by Dr. Withering". ==Risk to human health==
Risk to human health
The 18th-century naturalist Dr. Leigh recorded its lethal effects after the death of a farmer's wife and child. James Watt Jnr. experimented with the mineral on animals and he recorded the same lethal properties. Until the 18th century farmers at Anglezarke used the mineral as rat poison. ==Industrial use==
Industrial use
An experiment conducted by Josiah Wedgwood, led to it being used in his 'Jasper ware'; the mineral had previously been considered as worthless. Witherite crystallizes in the orthorhombic system. The crystals are invariably twinned together in groups of three, giving rise to pseudo-hexagonal forms somewhat resembling bipyramidal crystals of quartz, the faces are usually rough and striated horizontally. It occurs in veins of lead ore at Hexham in Northumberland, Alston in Cumbria, Anglezarke, near Chorley in Lancashire and a few other localities. Witherite is readily altered to barium sulfate by the action of water containing calcium sulfate in solution and crystals are therefore frequently encrusted with barytes. It is the chief source of barium salts and is mined in considerable amounts in Northumberland. It is used for the preparation of rat poison, in the manufacture of glass and porcelain, and formerly for refining sugar. It is also used for controlling the chromate to sulfate ratio in chromium electroplating baths. Witherite-216507.jpg|Two sharp pseudohexagonal crystals of witherite on calcite from Hardin County, Illinois (size: 6.4 × 5.4 × 3.4 cm) Witherite-65711.jpg|Witherite crystal from the Cave-in-Rock Sub-District, Illinois – Kentucky Fluorspar District, Hardin County, Illinois ==See also==
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