In 2003, when she was a freshman at Beijing Film Academy, Xiong made her acting debut in
Crime Scene, playing a policewoman. In 2004, she played Zhou Jiamin, Queen Zhou the Younger in the historical melodrama
How Much Sorrow Do You Have. That same year, she also starred in the costume mystery drama
Dixue Feicui. In 2005, she had a key supporting role in the historical television series
The Prince of Han Dynasty, playing the daughter (Princess Weichang) of
Huang Xiaoming's and Ruping's characters. That same year, she had a minor role as Qiu Xiang in the costume drama
The First Marriage. In 2006, she was cast in the lead role of Wulan in the
wuxia television series
Big Shots, based on the novel by the same name by
Gu Long. In 2008, she appeared in
The Last Prince, a historical television series starring
Feng Yuanzheng and
Xu Fan. That same year, she co-starred with
Chen Kun and
Li Xiaoran in
Remembrance of Dreams Past. In 2009, she participated in
Ghost Catcher - Legend of Beauty, a
shenmo television series. In 2010, she filmed in
All Men Are Brothers as Yan Xijiao, adapted from
Shi Nai'an's classical novel
Water Margin. That same year, she had a cameo appearance in the fantasy historical drama
Beauty World. She made her film debut in
Choy Lee Fut Kung Fu, a
Kung fu film. In 2011, she headlined the comedy film
Scheme With Me. She then appeared in the film
The First President, in which she played
Soong Ai-ling. She also featured in romance film
Great Wall My Love. In 2012, she had a supporting role in the martial arts film
Tai Chi 0 and its sequel,
Tai Chi Hero. She played the female lead role in Li Qilin's romantic comedy film
Rhapsody of BMW. She then starred in the war television series
Jiu He Ru Hai. In 2013, she starred in the romantic comedy television series
Destiny by Love. She played the female lead role in the suspense thriller film
The Deathday Party. In 2014, she co-starred in the romantic comedy television series
My Amazing Bride, and youth drama
Ice and Fire of Youth. She had a minor role as Mengmeng in romantic comedy film
Ex-Files. In 2015, she dubbed the voice of
Chang'e in the
animated film
Mr. Nian. The same year, she guest-starred on the fantasy series
Noble Aspirations playing Youji, one of four great messengers of the Ghost King Faction. In 2016, Xiong Naijin had a key supporting role in
Phoenix Warriors, a fantasy television series adaptation based on the novel
Meiren Mou by Bing Lansha. In 2017, she starred in the youth film
Invictus Basketball, directed by Li Feng. In 2019, Xiong starred in fantasy drama
L.O.R.D. Critical World. ==Filmography==