Introduction and early storylines Shortly after the character's debut, Zoe was involved in a special episode focusing on
International Women's Day. In July 2022, Zoe was involved in a
knife crime storyline following the stabbing and death of Saul. Brown revealed that Zoe has a "rather frantic and emotional" reaction to Saul's stabbing and that due to "Saul being her friend and colleague", Zoe "jumps into action immediately when receiving the bad news." Zoe attempts to arrest DeMarcus when his prints are found on the knife and the family break into an argument, with Zoe saying that DeMarcus should trust the legal process and give himself to the police; however, DeMarcus ends up running away as his father
Felix Westwood (
Richard Blackwood) restrains Zoe.
Relationship with Sam Chen-Williams Upon her debut, Brown teased a romance with
Sam Chen-Williams (Matthew McGivern), saying that "Sam very much catches Zoe off-guard. She never thought it would come to anything, but the attraction keeps growing." Zoe warns Sam to stop but Sam plants drugs on him, leading to Zoe breaking up with Sam. Zoe plans to have an abortion due to not feeling ready to be a mother yet, and continues to deal with Sam's obsession over getting back together with her, who refuses to accept that the relationship is over. Sam pleads with Zoe to not go through with the termination but she tells him that work is her focus. She added that "For Zoe, they are completely done. Let's leave this alone, it's gone far enough and they weren't even supposed to be together in the first place because they worked together." Zoe is then uncomfortable when she comes home to find Sam in her flat, who has broken in. Brown has previously told
Inside Soap that she hoped that Jamelia would return to
Hollyoaks as she wanted to have the opportunity to work together. Brown revealed that she developed a bond with her offscreen and called Jamelia her "soul family". Jamelia revealed that Sharon's return would "unsettle the family dynamic", saying that "Sharon hasn't always prioritised her daughter and her mum [Pearl] is stuck in the middle. There’s a lot for them to work through and I can't wait for viewers to see how that plays out on screen." Referring to the situation, Brown told
Inside Soap: "Zoe feels betrayed by Sharon and can't believe she told her business to the person she had asked her to keep it from. They don't have the best mother-daughter relationship, Zoe was practically raised by her grandma Pearl as Sharon put her career before being a parent. I actually don't agree with Zoe hiding the pregnancy from Sam, they should've had a conversation. But Zoe thought it was easier not to tell him and get his hopes up, and she was making that decision for herself." In 2024, Jamelia chose to leave
Hollyoaks and Zoe was involved in Sharon's exit story, which aired in April 2024. In the storyline, Sharon decides to move to
Dubai and tries to persuade Zoe to leave with her, but Zoe does not want to leave her friends and family in the village. Zoe later finds herself on "the wrong side of the law" when she is considered a suspect of Rayne's murder due to having been at the scene with other character when Rayne was murdered. Speaking to the
Daily Mirror, Brown said that Zoe "won't be involved as much as she would like to be, with being in the manor at the time of Rayne’s death, she's now been forced on the other side of the law." Zoe becomes frustrated that she is unable to work and breaks up with Hunter, blaming him for being part of the murder investigation. When Hunter's friends, such as
Peri Lomax (
Ruby O'Donnell), accuse Zoe of murdering Rayne, Hunter chooses Zoe over them and tells Zoe that she is his girlfriend; however, Zoe then makes an "incriminating discovery" when she finds the edited the video of Peri admitting to Rayne's murder on Hunter's brother,
Prince McQueen's (
Malique Thompson-Dwyer), laptop, though it is unclear whether he made it or if there is another explanation. Zoe becomes "implicated" when she overhears a conversation between Hunter and Prince revealing that Hunter believes he killed Rayne. Zoe later offers Hunter an "olive branch" and tells him that she wants to regain his trust following the tension between them, which leads him to admit to her that he stole Rayne's phone on the night of her murder. Zoe wants to give the phone to her police colleagues but Hunter asks her not, which "once again" leaves Zoe "torn" between her loyalty to her friends and her job. ==Storylines==