Radiometric dating is based on the known and constant rate of decay of
radioactive isotopes into their
radiogenic daughter isotopes. Particular isotopes are suitable for different applications due to the types of atoms present in the mineral or other material and its approximate age. For example, techniques based on isotopes with half-lives in the thousands of years, such as carbon-14, cannot be used to date materials that have ages on the order of billions of years, as the detectable amounts of the radioactive atoms and their decayed daughter isotopes will be too small to measure within the uncertainty of the instruments.
Radiocarbon dating One of the most widely used and well-known absolute dating techniques is carbon-14 (or
radiocarbon) dating, which is used to date organic remains. This is a radiometric technique since it is based on radioactive decay.
Cosmic radiation entering Earth's atmosphere produces carbon-14, and plants take in carbon-14 as they fix carbon dioxide. Carbon-14 moves up the food chain as animals eat plants and as predators eat other animals. With death, the uptake of carbon-14 stops. It takes 5,730 years for half the carbon-14 to decay to nitrogen; this is the half-life of carbon-14. After another 5,730 years, only one-quarter of the original carbon-14 will remain. After yet another 5,730 years, only one-eighth will be left. By measuring the carbon-14 in
organic material, scientists can determine the date of death of the organic matter in an artifact or
ecofact.
Limitations The relatively short half-life of carbon-14, 5,730 years, makes dating reliable only up to about 60,000 years. The technique often cannot pinpoint the date of an archeological site better than historic records, but is highly effective for precise dates when calibrated with other dating techniques such as
tree-ring dating. An additional problem with carbon-14 dates from archeological sites is known as the
"old wood" problem. In dry, desert climates, organic materials like dead trees can remain in their natural state for hundreds of years. When people eventually use these materials as firewood or building supplies, they become part of the archaeological record. Thus, dating that particular tree does not necessarily indicate when the fire burned or the structure was built. For this reason, many archaeologists prefer to use samples from short-lived plants for radiocarbon dating. The development of
accelerator mass spectrometry (AMS) dating, which allows a date to be obtained from a very small sample, has been very useful in this regard.
Potassium-argon dating Other radiometric dating techniques are available for earlier periods. One of the most widely used is
potassium–argon dating (K–Ar dating).
Potassium-40 is a radioactive isotope of potassium that decays into argon-40. The half-life of potassium-40 is 1.3 billion years, far longer than that of carbon-14, allowing much older samples to be dated. Potassium is common in rocks and minerals, allowing many samples of
geochronological or
archeological interest to be dated.
Argon, a noble gas, is not commonly incorporated into such samples except when produced
in situ through radioactive decay. The date measured reveals the last time that the object was heated past the
closure temperature at which the trapped argon can escape the lattice. K–Ar dating was used to calibrate the
geomagnetic polarity time scale. ==Luminescence dating==