Maxwell Anikwenwa, Bishop of Awka was the first archbishop of the Niger Province, from its erection in 2002 until his retirement in 2010; he had previously been Archbishop of Province II since 2000. He was re-elected in 2007.
Christian Efobi, Bishop of Aguata, was the second Archbishop of the Province, until his retirement in 2018. He had started his second term as archbishop on 24 July 2016.
Godwin Okpala, Bishop of Nnewi, was the third Archbishop, from 4 April 2018 until his retirement in September 2019.
Alexander Chibuzo Ibezim, Bishop of Awka, has been Archbishop of the Province of the Niger since his election during 2019 and installation on 24 September 2019. ==Diocese on the Niger==