Interference of atom
matter waves was first observed by
Immanuel Estermann and
Otto Stern in 1930, when a sodium (Na) beam was diffracted off a surface of
sodium chloride (NaCl). The first modern atom interferometer reported was a
double-slit experiment with metastable helium atoms and a microfabricated double slit by O. Carnal and
Jürgen Mlynek in 1991, and an interferometer using three microfabricated diffraction gratings and Na atoms in the group around
David E. Pritchard at the
Massachusetts Institute of Technology (MIT). Shortly afterwards, an optical version of a
Ramsey spectrometer typically used in atomic clocks was recognized also as an atom interferometer at the
Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig, Germany. The largest physical separation between the partial wave packets of atoms was achieved using laser cooling techniques and stimulated Raman transitions by
Steven Chu and his coworkers in
Stanford University. In 1999, the diffraction of C60
fullerenes by researchers from the
University of Vienna was reported. Fullerenes are comparatively large and massive objects, having an atomic mass of about . The
de Broglie wavelength of the incident beam was about 2.5
pm, whereas the diameter of the molecule is about 1
nm, about 400 times larger. In 2012, these far-field diffraction experiments could be extended to
phthalocyanine molecules and their heavier derivatives, which are composed of 58 and 114 atoms respectively. In these experiments the build-up of such interference patterns could be recorded in real time and with single molecule sensitivity. In 2003, the Vienna group also demonstrated the wave nature of
tetraphenylporphyrin—a flat biodye with an extension of about 2 nm and a mass of 614 Da. For this demonstration they employed a near-field Talbot–Lau interferometer. In the same interferometer they also found interference fringes for C60F48, a fluorinated
buckyball with a mass of about 1600 Da, composed of 108 atoms. In 2011, the interference of molecules as heavy as 6910 Da could be demonstrated in a Kapitza–Dirac–Talbot–Lau interferometer. In 2013, the interference of molecules beyond 10,000 Da has been demonstrated. The 2008 comprehensive review by Alexander D. Cronin, Jörg Schmiedmayer, and
David E. Pritchard documents many new experimental approaches to atom interferometry. More recently atom interferometers have begun moving out of laboratory conditions and have begun to address a variety of applications in real world environments. == Interferometer types ==