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Sodium chloride

Sodium chloride, commonly known as table salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is de-icing of roadways in sub-freezing weather.

Uses
In addition to the many familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 data) include chemicals and de-icing. Chemical functions Salt is used, directly or indirectly, in the production of many chemicals, which consumes most of the world's production. It is used to flocculate and increase the density of the drilling fluid to overcome high downwell gas pressures. Whenever a drill hits a salt formation, salt is added to the drilling fluid to saturate the solution in order to minimize the dissolution within the salt stratum. to promote "salting out" of dyestuff precipitates, and to blend with concentrated dyes to increase yield in dyebaths and make the colors look sharper. One of its main roles is to provide the positive ion charge to promote the absorption of negatively charged ions of dyes. The omnipresence of salt in coastal areas poses a problem in any coating application, because trapped salts cause great problems in adhesion. Naval authorities and ship builders monitor the salt concentrations on surfaces during construction. Maximal salt concentrations on surfaces are dependent on the authority and application. The IMO regulation is mostly used and sets salt levels to a maximum of 50 mg/m2 soluble salts measured as sodium chloride. These measurements are done by means of a Bresle test. Salinization (increasing salinity, aka freshwater salinization syndrome) and subsequent increased metal leaching is an ongoing problem throughout North America and European fresh waterways. In highway de-icing, salt has been associated with corrosion of bridge decks, motor vehicles, reinforcement bar and wire, and unprotected steel structures used in road construction. Surface runoff, vehicle spraying, and windblown salt also affect soil, roadside vegetation, and local surface water and groundwater supplies. Although evidence of environmental loading of salt has been found during peak usage, the spring rains and thaws usually dilute the concentrations of sodium in the area where salt was applied. Substitution Some agencies are substituting beer, molasses, and beet juice instead of road salt. Airlines utilize more glycol and sugar rather than salt-based solutions for deicing. Food industry and agriculture Salt is added to food, either by the food producer or by the consumer, as a flavor enhancer, preservative, binder, fermentation-control additive, texture-control agent, and color developer. The salt consumption in the food industry is subdivided, in descending order of consumption, into other food processing, meat packers, canning, baking, dairy, and grain mill products. Salt is added to promote color development in bacon, ham and other processed meat products. As a preservative, salt inhibits the growth of bacteria. Salt acts as a binder in sausages to form a binding gel made up of meat, fat, and moisture. Salt also acts as a flavor enhancer and as a tenderizer. Medicine Sodium chloride is used together with water as one of the primary solutions for intravenous therapy. Nasal spray often contains a saline solution. Sodium chloride is also available as an oral tablet and is taken to treat low sodium levels. Firefighting Sodium chloride is the principal extinguishing agent in dry-powder fire extinguishers that are used on combustible metal fires, for metals such as magnesium, zirconium, titanium, and lithium (Class D extinguishers). The salt forms an oxygen-excluding crust that smothers the fire. Cleanser Since at least medieval times, people have used salt as a cleansing agent rubbed on household surfaces. It is also used in many brands of shampoo and toothpaste and is commonly used to deice driveways, parking lots, and walkways. Infrared optics Sodium chloride crystals have a transmittance of at least 90% (through 1 mm) for infrared light having wavelengths in the range 0.2–18 μm. They were used in optical components such as windows and lenses, where few non-absorbing alternatives existed in that spectral range. While inexpensive, NaCl crystals are soft and hygroscopic – when exposed to the water in ambient air, they gradually cover with "frost". This limits application of NaCl to dry environments, vacuum-sealed areas, or short-term uses such as prototyping. Materials that are mechanically stronger and less sensitive to moisture, such as zinc selenide and chalcogenide glasses, are more widely used than NaCl. ==Chemistry==
Chemistry
Solid sodium chloride In solid sodium chloride, each ion is surrounded by six ions of the opposite charge as expected on electrostatic grounds. The surrounding ions are located at the vertices of a regular octahedron. In the language of close-packing, the larger chloride ions (167 pm in size) are arranged in a cubic array whereas the smaller sodium ions (116 pm The thermal conductivity of sodium chloride as a function of temperature has a maximum of 2.03 W/(cm K) at and decreases to 0.069 at . It also decreases with doping. , NaCl·2H2O. (red = O, white = H, green = Cl, purple = Na). From cold (sub-freezing) solutions, salt crystallises with water of hydration as hydrohalite (the dihydrate NaCl·2). In 2023, it was discovered that under pressure, sodium chloride can form the hydrates NaCl·8.5H2O and NaCl·13H2O. Aqueous solutions The attraction between the Na+ and Cl− ions in the solid is so strong that only highly polar solvents like water dissolve NaCl well. When dissolved in water, the sodium chloride framework disintegrates as the Na+ and Cl− ions become surrounded by polar water molecules. These solutions consist of metal aquo complex with the formula [Na(H2O)8]+, with the Na–O distance of 250 pm. The chloride ions are also strongly solvated, each being surrounded by an average of six molecules of water. Solutions of sodium chloride have very different properties from pure water. The eutectic point is for 23.31% mass fraction of salt, and the boiling point of saturated salt solution is near . pH of sodium chloride solutions The pH of a sodium chloride solution remains ≈7 due to the extremely weak basicity of the Cl− ion, which is the conjugate base of the strong acid HCl. In other words, NaCl has no effect on system pH in diluted solutions where the effects of ionic strength and activity coefficients are negligible. Stoichiometric and structure variants Common salt has a 1:1 molar ratio of sodium and chlorine. In 2013, compounds of sodium and chloride of different stoichiometries have been discovered; five new compounds were predicted (e.g., Na3Cl, Na2Cl, Na3Cl2, NaCl3, and NaCl7). The existence of some of them has been experimentally confirmed at high pressures and other conditions: cubic and orthorhombic NaCl3, two-dimensional metallic tetragonal Na3Cl and exotic hexagonal NaCl. This indicates that compounds violating chemical intuition are possible, in simple systems under non-ambient conditions. ==Occurrence==
Occurrence
Salt is found in the Earth's crust as the mineral halite (rock salt), and a tiny amount exists as suspended sea salt particles in the atmosphere. These particles are the dominant cloud condensation nuclei far out at sea, which allow the formation of clouds in otherwise non-polluted air. ==Production==
Production
Salt is currently mass-produced by evaporation of seawater or brine from brine wells and salt lakes. Mining of rock salt is also a major source. China is the world's main supplier of salt. In 2017, world production was estimated at 280 million tonnes, the top five producers (in million tonnes) being China (68.0), United States (43.0), India (26.0), Germany (13.0), and Canada (13.0). Salt is also a byproduct of potassium mining. File:Salt mine 0096.jpg|Modern rock salt mine near Mount Morris, New York, United States File:Dead-Sea---Salt-Evaporation-Ponds.jpg|Jordanian and Israeli salt evaporation ponds at the south end of the Dead Sea. File:Piles of Salt Salar de Uyuni Bolivia Luca Galuzzi 2006 a.jpg|Mounds of salt, Salar de Uyuni, Bolivia. ==See also==
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