Born in
Taipei, Taiwan, Hsiao attended the exclusive all-boys
Taipei Municipal Jianguo High School (JGHS). He graduated from JGHS to enroll in the
National Taiwan University and pursued a B.S. in
chemical engineering. In 1985, he was inducted into
Sigma Xi, the scientific research honor society and
Phi Kappa Phi, the oldest all-discipline honor society. He completed his Ph.D. in 1987 under the guidance of Edward T. Samulski and Montgomery T. Shaw. He went on to work at the
University of Massachusetts between 1987 and 1989 as a postdoctoral research fellow in the department of polymer science and engineering under the tutelage of Richard S. Stein and H. Henning Winter. Immediately afterwards, he was sought by the
DuPont Company to work in the Pioneering Laboratory. He stayed with DuPont for 8 years in
Wilmington, Delaware until 1997 as a senior staff scientist in the Central Research and Development Department, after which he embarked upon an academic career at
Stony Brook University. Joining
Stony Brook University as an assistant professor in 1997, Hsiao was promoted to full professor in 2002 and appointed to the chair of the chemistry department in 2007. It was under his leadership, that the chemistry department at Stony Brook was identified as one of the top departments in the nation, and designated a
National Historic Landmark for the invention of
Magnetic Resonance Imaging (MRI) by the
American Chemical Society. Hsiao was the vice president for research at Stony Brook University between 2012 and 2013 for 1.5 years. In this position, he was responsible for the campus-wide advancement of Stony Brook's research mission through strategic planning and oversaw the Research Foundation, supervised all university research administration activities and functions, and was the primary advocate for the university's research enterprise on a state, national and international level. His major contributions to the Stony Brook Research Office (SBRO) were in two areas: (1) greater efficiency and transparency of the research administration activities on campus, and (2) new research initiatives to advance Stony Brook's research mission on a state, national and international level. Since 2008, he has also served as the Chang-Jiang Professor at
Donghua University in Shanghai, and a guest professor at the
Beijing University of Chemical Technology,
Tongji University and the
Changchun Institute of Applied Chemistry of the
Chinese Academy of Sciences. ==Research==