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Cheakamus River derailment

The Cheakamus River derailment occurred on August 5, 2005, when nine cars that were from a Canadian National Railway freight train derailed and crashed into the Cheakamus River in British Columbia. One of the cars contained approximately 40,000 litres of caustic soda, which entered the river, killing more than 500,000 fish from 10 different species, including chinook salmon, coho salmon, pink salmon, and rainbow trout, both freshwater and ocean-dwelling. Juvenile rainbow trout were the most affected at a mortality rate of 90% and it was also estimated that the adult chinook salmon mortality rate reached 50%.

Sodium hydroxide effects in aquatic environments
Sodium hydroxide (NaOH) has the potential to be a dangerous chemical in aquatic environments due to it raising the pH level of the water. At low concentrations, NaOH will be neutralized by other chemicals in the water, such as acids and dissolved carbon dioxide (). Also, NaOH does not bioaccumulate in the aquatic organisms as it is dissolved in the water and has a negative octanol-water partition coefficient. The median lethal dose (LC) concentrations for aquatic organisms for NaOH range between 33 and 189 mg/L. The pH scale is a measure of the concentration of free hydrogen ions in the water. Extremely high pH will harm fish, specifically juveniles, by removing their slimy coats and drying out their skin, eyes and gills. Consequently, raising the pH of an aquatic environment can directly increase the toxicity of other chemicals, such as ammonia (). This is because in basic solutions (), becomes more prevalent than ammonium (), and it is dangerous to aquatic life. When pH exceeds 9, concentrations are over 100 times higher than below pH of 9. Ultimately, high pH can lead to death of organisms in aquatic environments and directly reduce biodiversity in these environments. If not caused by man-made industries or accidents, high pH surges can occur naturally and may be observed when algal blooms occur, otherwise they are virtually impossible to observe without directly measuring the pH of the water. ==See also==
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