Percolation is the study of connectivity in random systems, such as electrical conductivity in random conductor/insulator systems, fluid flow in porous media, gelation in polymer systems, etc. At a critical fraction of connectivity or porosity, long-range connectivity can take place, leading to long-range flow. The point where that connectivity takes place is called the
percolation threshold, and considerable amount of work has been undertaken in finding those critical values for systems of various geometries, and the mathematical behavior of observables near that point. This leads to the study of
critical behavior and the
percolation critical exponents. These exponents allow one to describe the behavior as the threshold is approached. The behavior of the percolating network near a surface will be different from that in the main part of a system, called the "bulk." For example, exact at the percolation threshold, the percolating network in the system is a fractal with large voids and a ramified structure. The surface interrupts this structure, so the percolating cluster is less likely to come in contact to the surface. As an example, consider a lattice system of bond percolation (percolation along the bonds or edges of the lattice). If the lattice is cubic in nature, and p is the probability that a bond is occupied (conducting), then the
percolation threshold is known to be p_c = 0.311608.... At the surface, the lattice becomes a simple square lattice, where the bond threshold p_c is simply 1/2. Therefore, when the bulk of the system is at its threshold, the surface is way below its threshold, and the only way to have long-range connections along the surface is to have a path that goes from the surface to the bulk, conduction through the fractal percolation network, and then a path back to the surface again. This occurs with a different critical behavior as in the bulk, and is different from the critical behavior of a two-dimensional surface at its threshold. In the most common model for surface critical behavior in percolation, all bonds are assigned with the same probability p, and the behavior is studied at the bulk p_c, with a value of 0.311608 in this case. In an other model for surface behavior, the surface bonds are made occupied with a different probability p_s, while the bulk is kept at the normal bulk value. When p^{(s)} is increased to a higher value, a new "special" critical point is reached p^{(s)}_c, which has a different set of critical exponents. ==Surface phase transitions==