with other winners, from left C. V. Raman (physics),
Hans Fischer (chemistry),
Karl Landsteiner (medicine) and
Sinclair Lewis (literature)
Musical sound One of Raman's interests was on the scientific basis of musical sounds. He was inspired by
Hermann von Helmholtz's
The Sensations of Tone, the book he came across when he joined IACS. He studied the
acoustics of various violin and related instruments, including Indian stringed instruments, and water splashes. He even performed what he called "Experiments with mechanically-played violins." Raman also studied the uniqueness of Indian drums. His analyses of the
harmonic nature of the sounds of
tabla and
mridangam were the first scientific studies on Indian percussions. He wrote a critical research on vibrations of the
pianoforte string that was known as Kaufmann's theory (the first scientific description of vibration of musical strings made by German physicist
Walter Kaufmann in 1895). During his brief visit of England in 1921, he managed to study how sound travels in the
Whispring Gallery of the dome of
St Paul's Cathedral in London that produces unusual sound effects. His work on acoustics was an important prelude, both experimentally and conceptually, to his later works on optics and quantum mechanics.
Blue color of the sea Raman, in his broadening venture on optics, started to investigate scattering of light starting in 1919. His first phenomenal discovery of the physics of light was the
blue color of seawater. During a voyage home from England on board the
S.S. Narkunda in September 1921, he contemplated the blue color of the
Mediterranean Sea. Using simple optical equipment, a pocket-sized
spectroscope and a
Nicol prism in hand, he studied the sea water. Of several hypotheses on the colour of the sea propounded at the time, the best explanation had been that of
Lord Rayleigh's in 1910, according to which, "The much admired dark blue of the deep sea has nothing to do with the color of water, but is simply the blue of the sky seen by reflection". Rayleigh had correctly described the nature of the blue sky by a phenomenon now known as
Rayleigh scattering, the scattering of light and refraction by particles in the atmosphere. His explanation of the blue colour of water was instinctively accepted as correct. Raman could view the water using a Nicol prism to avoid the influence of sunlight reflected by the surface. He described how the sea appears even more blue than usual, contradicting Rayleigh. As soon as the
S.S. Narkunda docked in Bombay Harbour (now
Mumbai Harbour), Raman finished an article "The colour of the sea" that was published in the November 1921 issue of
Nature. He noted that Rayleigh's explanation is "questionable by a simple mode of observation" (using Nicol prism). By early 1922, Raman came to a conclusion, as he reported in the
Proceedings of the Royal Society of London:True to his words, Ramanathan published an elaborate experimental finding in 1923. His subsequent study of the
Bay of Bengal in 1924 provided the full evidence. It is now known that the intrinsic
colour of water is mainly attributed to the selective absorption of longer wavelengths of light in the red and orange regions of the
spectrum, owing to overtones of the
infrared absorbing O-H (oxygen and hydrogen combined) stretching modes of water molecules.
Raman effect Background Raman's second important discovery on the scattering of light was a new type of radiation, an eponymous phenomenon called the Raman effect. He referred to the phenomenon as "feeble fluorescence." But the theoretical attempts to justify the phenomenon were quite futile for the next two years. The major impetus was the discovery of
Compton effect.
Arthur Compton at
Washington University in St. Louis had found evidence in 1923 that
electromagnetic waves can also be described as particles. By 1927, the phenomenon was widely accepted by scientists, including Raman. As the news of Compton's
Nobel Prize in Physics was announced in December 1927, Raman ecstatically told Krishnan, saying: But the origin of the inspiration went further. As Compton later recollected "that it was probably the Toronto debate that led him to discover the Raman effect two years later." Raman took Duane's side and said, "Compton, you're a very good debater, but the truth isn't in you."|240x240px Krishnan started the experiment in the beginning of January 1928. On 28 February 1928, they obtained spectra of the modified scattering separate from the
incident light. Due to difficulty in measuring the wavelengths of light, they had been relying on visual observation of the colour produced from sunlight through prism. Raman had invented a type of
spectrograph for detecting and measuring electromagnetic waves. Referring to the invention, Raman later remarked, "When I got my Nobel Prize, I had spent hardly 200
rupees on my equipment," although it was obvious that his total expenditure for the entire experiment was much more than that. From that moment they could employ the instrument using
monochromatic light from a
mercury arc lamp which penetrated transparent material and was allowed to fall on a spectrograph to record its spectrum. The lines of scattering could now be measured and photographed.
Announcement The same day, Raman made the announcement before the press. The
Associated Press of India reported it the next day, on 29 February, as "New theory of radiation: Prof. Raman's Discovery." It ran the story as:The news was reproduced by
The Statesman on 1 March under the headline "Scattering of Light by Atoms – New Phenomenon – Calcutta Professor's Discovery." Raman submitted a three-paragraph report of the discovery on 8 March to
Nature and was published on 21 April. The actual data was sent to the same journal on 22 March and was published on 5 May. Raman presented the formal and detailed description as "A new radiation" at the meeting of the South Indian Science Association in Bangalore on 16 March. His lecture was published in the
Indian Journal of Physics on 31 March. On 20 June 1928, Peter Pringsheim at the
University of Berlin was able to reproduce Raman's results successfully. He was the first to coin the terms
Ramaneffekt and
Linien des Ramaneffekts in his articles published the following months. Use of the English versions, "Raman effect" and "Raman lines" immediately followed. In addition to being a new phenomenon itself, the Raman effect was one of the earliest proofs of the
quantum nature of light.
Robert W. Wood at the
Johns Hopkins University was the first American to confirm the Raman effect in early 1929. He made a series of experimental verification, after which he commented, saying, "It appears to me that this very beautiful discovery which resulted from Raman's long and patient study of the phenomenon of light scattering is one of the most convincing proofs of the quantum theory". The field of
Raman spectroscopy came to be based on this phenomenon, and
Ernest Rutherford, President of the
Royal Society, referred to it in his presentation of the
Hughes Medal to Raman in 1930 as "among the best three or four discoveries in
experimental physics in the last decade". He did eventually win that year.
Later work Raman had association with the
Banaras Hindu University in
Varanasi. He attended the foundation ceremony of BHU and delivered lectures on mathematics and "Some new paths in physics" during the lecture series organised at the university from 5 to 8 February 1916. He also held the position of permanent visiting professor. With
Suri Bhagavantam, he determined the
spin of
photons in 1932, which further confirmed the quantum nature of light. Modulators, and switching systems based on this effect have enabled optical communication components based on
laser systems. Other investigations he carried out included experimental and theoretical studies on the diffraction of light by acoustic waves of
ultrasonic and
hypersonic frequencies, and those on the effects produced by X-rays on infrared vibrations in crystals exposed to ordinary light which were published between 1935 and 1942. In 1948, through studying the
spectroscopic behaviour of crystals, he approached the fundamental problems of crystal dynamics in a new manner. He dealt with the structure and properties of diamond from 1944 to 1968, the structure and optical behaviour of numerous
iridescent substances including
labradorite, pearly
feldspar,
agate,
quartz,
opal, and
pearl in the early 1950s. Among his other interests were the optics of
colloids, and electrical and magnetic
anisotropy. His last interests in the 1960s were on biological properties such as the colours of flowers and the
physiology of human vision. ==Personal life==