Disaccharide

There are two functionally different classes of disaccharides: • Reducing disaccharides, in which one monosaccharide, the reducing sugar of the pair, still has a free hemiacetal unit that can perform as a reducing aldehyde group; lactose, maltose and cellobiose are examples of reducing disaccharides, each with one hemiacetal unit, the other occupied by the glycosidic bond, which prevents it from acting as a reducing agent. They can easily be detected by the Woehlk test or Fearon's test on methylamine. • Non-reducing disaccharides, in which the component monosaccharides bond through an acetal linkage between their anomeric centers. This results in neither monosaccharide being left with a hemiacetal unit that is free to act as a reducing agent. Sucrose and trehalose are examples of non-reducing disaccharides because their glycosidic bond is between their respective hemiacetal carbon atoms. The reduced chemical reactivity of the non-reducing sugars, in comparison to reducing sugars, may be an advantage where stability in storage is important. ==Formation==

The formation of a disaccharide molecule from two monosaccharide molecules proceeds by displacing a hydroxy group from one molecule and a hydrogen nucleus (a proton) from the other, so that the new vacant bonds on the monosaccharides join the two monomers together. Because of the removal of the water molecule from the product, the term of convenience for such a process is "dehydration reaction" (also "condensation reaction" or "dehydration synthesis"). For example, milk sugar (lactose) is a disaccharide made by condensation of one molecule of each of the monosaccharides glucose and galactose, whereas the disaccharide sucrose in sugar cane and sugar beet, is a condensation product of glucose and fructose. Maltose, another common disaccharide, is condensed from two glucose molecules. The dehydration reaction that bonds monosaccharides into disaccharides (and also bonds monosaccharides into more complex polysaccharides) forms what are called glycosidic bonds. ==Characteristic reactions==

is one of several sugar alcohols produced from disaccharides|210px|right|thumb Disaccharides can serve as functional groups by forming glycosidic bonds with other organic compounds, forming glycosides and glycoconjugates. Disaccarides characteristically undergo hydrolysis to give monosaccharides. Some disaccharides can be hydrogenated to give useful disaccharide alcohols with retention of the acetal linkage. Commercial products include lactitol, isomalt, and maltitol. Isomalt production begins with a bacterial promoted conversion of sucrose to isomaltulose. Sucrose undergoes acid catalyzed poly-dehydration to give hydroxymethylfurfural. ==Assimilation==

Digestion of disaccharides involves breakdown into monosaccharides. ==Common disaccharides==

: Maltose, cellobiose, and chitobiose are hydrolysis products of the polysaccharides starch, cellulose, and chitin, respectively. Less common disaccharides include: : ==References==