In most cases this decay mode is masked by other, more probable modes involving fewer particles, such as single
electron capture. When all other modes are forbidden (energetically disallowed, or rarely, strongly suppressed) double electron capture becomes the main mode of decay. There exist 34
naturally occurring nuclei that are able to undergo double electron capture, but the process has been confirmed by observation in the decay of only three nuclides: , , and . One reason is that the probability of double electron capture is exceedingly small; the
half-lives for this mode lie well above 10 years. A second reason is that the only detectable particles created in this process are
X-rays and
Auger electrons that are emitted by the excited atomic shell; as the parent and daughter nuclei (being even-even) are both 0+ states, and a 0+ -> 0+ transition is allowed, no
gamma radiation is expected. The X-rays have energies near the electron binding energies (< 100
keV), where the background is high. Thus, the experimental detection of double electron capture is more difficult than that for negative
double beta decay. == Modes with positron emission ==