In ordinary incandescent lamps, evaporated tungsten mostly deposits onto the inner surface of the bulb, causing the bulb to blacken and the filament to grow increasingly weak until it eventually breaks. The presence of the halogen, however, sets up a reversible chemical reaction cycle with this evaporated tungsten. The halogen cycle keeps the bulb clean and causes the light output to remain almost constant throughout the bulb's life. At moderate temperatures, the halogen reacts with the evaporating tungsten, the
halide formed being moved around in the inert gas filling. At some point, however, it will reach higher temperature regions within the bulb where it then
dissociates, releasing tungsten back onto the filament and freeing the halogen to repeat the process. However, the overall bulb envelope temperature must be significantly higher than in conventional incandescent lamps for this reaction to succeed: it is only at temperatures of above on the inside of the glass envelope that the halogen vapor can combine with the tungsten and return it to the filament rather than the tungsten becoming deposited on the glass. A 300-watt tubular halogen bulb operated at full power quickly reaches a temperature of about , while a 500-watt regular incandescent bulb operates at only and a 75-watt regular incandescent at only . The bulb must be made of
fused silica (quartz) or a high-melting-point glass (such as
aluminosilicate glass). Since quartz is very strong, the gas pressure can be higher which reduces the rate of evaporation of the filament, permitting it to run a higher temperature (and so
luminous efficacy) for the same average life. The tungsten released in hotter regions does not generally redeposit where it came from, so the hotter parts of the filament eventually thin out and fail. Quartz iodine lamps, using elemental iodine, were the first commercial halogen lamps launched by GE in 1959. Quite soon, bromine was found to have advantages, but was not used in elemental form. Certain hydrocarbon bromine compounds gave good results. Regeneration of the filament is also possible with fluorine, but its chemical reactivity is so great that other parts of the lamp are attacked. The halogen is normally mixed with a
noble gas, often
krypton or
xenon. The first lamps used only tungsten for filament supports, but some designs use
molybdenum – an example being the molybdenum shield in the H4 twin filament
headlight for the European Asymmetric Passing Beam. For a fixed power and life, the
luminous efficacy of all incandescent lamps is greatest at a particular design voltage. Halogen lamps made for 12 to 24 volt operation have good light outputs, and the very compact filaments are particularly beneficial for optical control (see picture). The ranges of
multifaceted reflector "MR" lamps of 20–50 watts were originally conceived for the projection of
8 mm film, but are now widely used for display lighting and in the home. More recently, wider beam versions have become available, designed for direct use on supply voltages of 120 or . ==Effect of voltage on performance==