When three frequencies (f1, f2, and f3) interact in a nonlinear medium, they give rise to a fourth frequency (f4) which is formed by the scattering of the incident photons, producing the fourth photon. Given inputs
f1, f2, and
f3, the nonlinear system will produce : \pm f_{1} \pm f_{2} \pm f_{3} From calculations with the three input signals, it is found that 12 interfering frequencies are produced, three of which lie on one of the original incoming frequencies. Note that these three frequencies which lie at the original incoming frequencies are typically attributed to
self-phase modulation and
cross-phase modulation, and are naturally phase-matched unlike FWM.
Sum- and difference-frequency generation Two common forms of four-wave mixing are dubbed
sum-frequency generation and difference-frequency generation. In sum-frequency generation three fields are input and the output is a new high frequency field at the sum of the three input frequencies. In difference-frequency generation, the typical output is the sum of two minus the third. A condition for efficient generation of FWM is phase matching: the associated k-vectors of the four components must add to zero when they are plane waves. This becomes significant since sum- and difference-frequency generation are often enhanced when resonance in the mixing media is exploited. In many configurations the sum of the first two photons will be tuned close to a resonant state. It is often very hard to satisfy this in the sum-frequency configuration but it is more easily satisfied in the difference-frequency configuration (where the pi phase shifts cancel out). As a result, difference-frequency is usually more broadly tunable and easier to set up than sum-frequency generation, making it preferable as a light source even though it's less
quantum efficient than sum-frequency generation. The special case of sum-frequency generation where all the input photons have the same frequency (and wavelength) is
Third-Harmonic Generation (THG).
Degenerate four-wave mixing Four-wave mixing is also present if only two components interact. In this case the term : f_{0} = f_{1} + f_{1} - f_{2} couples three components, thus generating so-called
degenerate four-wave mixing, showing identical properties to the case of three interacting waves. == Adverse effects of FWM in fiber-optic communications ==