Material dispersion can be a desirable or undesirable effect in optical applications. The dispersion of light by glass prisms is used to construct
spectrometers and
spectroradiometers. However, in lenses, dispersion causes
chromatic aberration, an undesired effect that may degrade images in microscopes, telescopes, and photographic objectives. The
phase velocity v of a wave in a given uniform medium is given by : v = \frac{c}{n}, where
c is the
speed of light in vacuum, and
n is the
refractive index of the medium. In general, the refractive index is some function of the frequency
f of the light, thus
n =
n(
f), or alternatively, with respect to the wave's wavelength
n =
n(
λ). The wavelength dependence of a material's refractive index is usually quantified by its
Abbe number or its coefficients in an empirical formula such as the
Cauchy or
Sellmeier equations. Because of the
Kramers–Kronig relations, the wavelength dependence of the real part of the refractive index is related to the material
absorption, described by the imaginary part of the refractive index (also called the
extinction coefficient). In particular, for non-magnetic materials (
μ =
μ0), the
susceptibility χ that appears in the Kramers–Kronig relations is the
electric susceptibility χe =
n2 − 1. The most commonly seen consequence of dispersion in optics is the separation of
white light into a
color spectrum by a
prism. From
Snell's law it can be seen that the angle of
refraction of light in a prism depends on the refractive index of the prism material. Since that refractive index varies with wavelength, it follows that the angle that the light is refracted by will also vary with wavelength, causing an angular separation of the colors known as
angular dispersion. For visible light, the refraction index
n of most transparent materials (e.g., air, glasses) decreases with increasing wavelength
λ: : 1 or generally, : \frac{dn}{d \lambda} In this case, the medium is said to have
normal dispersion. However, if the index increases with increasing wavelength (which is typically the case in the ultraviolet), the medium is said to have
anomalous dispersion. At the interface of such a material with air or vacuum (index of ~1), Snell's law predicts that light incident at an angle
θ to the
normal will be refracted at an angle arcsin(). Thus, in the case of normal dispersion, blue light, with a higher refractive index, will be bent more strongly than red light, resulting in the well-known
rainbow pattern. == Group-velocity dispersion ==