soldier wearing a chemical agent
protective suit (
C-vätskeskydd) and
protection mask (
skyddsmask 90) Although crude chemical warfare has been employed in many parts of the world for thousands of years, "modern" chemical warfare began during World War I – see
Chemical weapons in World War I. Initially, only well-known commercially available chemicals and their variants were used. These included chlorine and phosgene gas. The methods used to disperse these agents during battle were relatively unrefined and inefficient. Even so, casualties could be heavy, due to the mainly static troop positions which were characteristic features of
trench warfare. Germany, the first side to employ chemical warfare on the battlefield, simply opened canisters of chlorine upwind of the opposing side and let the
prevailing winds do the dissemination. Soon after, the French modified
artillery munitions to contain phosgene – a much more effective method that became the principal means of delivery. Since the development of modern chemical warfare in World War I, nations have pursued
research and development on chemical weapons that falls into four major categories: new and more deadly agents; more efficient methods of delivering agents to the target (dissemination); more reliable means of defense against chemical weapons; and more sensitive and accurate means of detecting chemical agents.
Chemical warfare agents The chemical used in warfare is called a
chemical warfare agent (
CWA). About 70 different chemicals have been used or stockpiled as chemical warfare agents during the 20th and 21st centuries. These agents may be in liquid, gas or solid form. Liquid agents that evaporate quickly are said to be
volatile or have a
high vapor pressure. Many chemical agents are
volatile organic compounds so they can be dispersed over a large region quickly. The earliest target of chemical warfare agent research was not toxicity, but development of agents that can affect a target through the skin and clothing, rendering protective
gas masks useless. In July 1917, the Germans employed
sulfur mustard. Mustard agents easily penetrate leather and fabric to inflict painful burns on the skin. Chemical warfare agents are divided into
lethal and
incapacitating categories. A substance is classified as incapacitating if less than 1/100 of the
lethal dose causes incapacitation, e.g., through nausea or visual problems. The distinction between lethal and incapacitating substances is not fixed, but relies on a statistical average called the .
Persistency Chemical warfare agents can be classified according to their
persistency, a measure of the length of time that a chemical agent remains effective after dissemination. Chemical agents are classified as
persistent or
nonpersistent. Agents classified as
nonpersistent lose effectiveness after only a few minutes or hours or even only a few seconds. Purely gaseous agents such as chlorine are nonpersistent, as are highly volatile agents such as sarin. Tactically, nonpersistent agents are very useful against targets that are to be taken over and controlled very quickly. Apart from the agent used, the delivery mode is very important. To achieve a nonpersistent deployment, the agent is dispersed into very small droplets comparable with the mist produced by an aerosol can. In this form not only the gaseous part of the agent (around 50%) but also the fine aerosol can be inhaled or absorbed through pores in the skin. Modern doctrine requires very high concentrations almost instantly in order to be effective (one breath should contain a lethal dose of the agent). To achieve this, the primary weapons used would be rocket artillery or bombs and large ballistic missiles with cluster warheads. The contamination in the target area is only low or not existent and after four hours sarin or similar agents are not detectable anymore. By contrast,
persistent agents tend to remain in the environment for as long as several weeks, complicating decontamination. Defense against persistent agents requires shielding for extended periods of time. Nonvolatile liquid agents, such as
blister agents and the oily
VX nerve agent, do not easily evaporate into a gas, and therefore present primarily a contact hazard. The droplet size used for persistent delivery goes up to 1 mm increasing the falling speed and therefore about 80% of the deployed agent reaches the ground, resulting in heavy contamination. Deployment of persistent agents is intended to constrain enemy operations by denying access to contaminated areas. Possible targets include enemy flank positions (averting possible counterattacks), artillery regiments, command posts or supply lines. Because it is not necessary to deliver large quantities of the agent in a short period of time, a wide variety of weapons systems can be used. A special form of persistent agents are thickened agents. These comprise a common agent mixed with thickeners to provide gelatinous, sticky agents. Primary targets for this kind of use include airfields, due to the increased persistency and difficulty of decontaminating affected areas.
Classes Chemical weapons are agents that come in four categories:
choking,
blister,
blood and
nerve. The agents are organized into several categories according to the manner in which they affect the human body. The names and number of categories varies slightly from source to source, but in general, types of chemical warfare agents are as follows: There are other chemicals used militarily that are not scheduled by the CWC, and thus are not controlled under the CWC treaties. These include: •
Defoliants and
herbicides that destroy vegetation, but are not immediately toxic or poisonous to human beings. Their use is classified as
herbicidal warfare. Some batches of
Agent Orange, for instance, used by the British during the
Malayan Emergency and the United States during the
Vietnam War, contained
dioxins as manufacturing impurities.
Dioxins, rather than Agent Orange itself, have long-term cancer effects and for causing genetic damage leading to serious
birth defects. •
Incendiary or
explosive chemicals (such as
napalm, extensively used by the United States during the
Korean War and the Vietnam War, or
dynamite) because their destructive effects are primarily due to fire or explosive force, and not direct chemical action. Their use is classified as
conventional warfare. •
Viruses,
bacteria, or other organisms. Their use is classified as
biological warfare.
Toxins produced by living organisms are considered chemical weapons, although the boundary is blurry. Toxins are covered by the
Biological Weapons Convention.
Designations Most chemical weapons are assigned a one- to three-letter "
NATO weapon designation" in addition to, or in place of, a common name.
Binary munitions, in which precursors for chemical warfare agents are automatically mixed in shell to produce the agent just prior to its use, are indicated by a "-2" following the agent's designation (for example, GB-2 and VX-2). Some examples are given below:
Delivery The most important factor in the effectiveness of chemical weapons is the efficiency of its delivery, or dissemination, to a target. The most common techniques include munitions (such as bombs, projectiles, warheads) that allow dissemination at a distance and spray tanks which disseminate from low-flying aircraft. Developments in the techniques of filling and storage of munitions have also been important. Although there have been many advances in chemical weapon delivery since World War I, it is still difficult to achieve effective dispersion. The dissemination is highly dependent on atmospheric conditions because many chemical agents act in gaseous form. Thus, weather observations and forecasting are essential to optimize weapon delivery and reduce the risk of injuring friendly forces.
Dispersion in
World War I Dispersion is placing the chemical agent upon or adjacent to a target immediately before dissemination, so that the material is most efficiently used. Dispersion is the simplest technique of delivering an agent to its target. The most common techniques are munitions, bombs, projectiles, spray tanks and warheads. World War I saw the earliest implementation of this technique. The actual first chemical ammunition was the French 26 mm cartouche suffocante
rifle grenade, fired from a
flare carbine. It contained of the
tear-producer ethyl bromoacetate, and was used in autumn 1914 – with little effect on the Germans. The
German military contrarily tried to increase the effect of
shrapnel shells by adding an irritant –
dianisidine chlorosulfonate. Its use against the British at
Neuve Chapelle in October 1914 went unnoticed by them. Hans Tappen, a chemist in the Heavy Artillery Department of the War Ministry, suggested to his brother, the Chief of the Operations Branch at German General Headquarters, the use of the tear-gases
benzyl bromide or
xylyl bromide. Shells were tested successfully at the Wahn artillery range near Cologne on January 9, 1915, and an order was placed for
howitzer shells, designated 'T-shells' after Tappen. A shortage of shells limited the first use against the Russians at the
Battle of Bolimów on January 31, 1915; the liquid failed to vaporize in the cold weather, and again the experiment went unnoticed by the Allies. The first effective use were when the German forces at the
Second Battle of Ypres simply opened cylinders of chlorine and allowed the wind to carry the gas across enemy lines. While simple, this technique had numerous disadvantages. Moving large numbers of heavy gas cylinders to the front-line positions from where the gas would be released was a lengthy and difficult logistical task. n forces Stockpiles of cylinders had to be stored at the front line, posing a great risk if hit by artillery shells. Gas delivery depended greatly on wind speed and direction. If the wind was fickle, as at the
Battle of Loos, the gas could blow back, causing
friendly casualties. Gas clouds gave plenty of warning, allowing the enemy time to protect themselves, though many soldiers found the sight of a creeping gas cloud unnerving. This made the gas doubly effective, as, in addition to damaging the enemy physically, it also had a psychological effect on the intended victims. Another disadvantage was that gas clouds had limited penetration, capable only of affecting the front-line trenches before dissipating. Although it produced limited results in World War I, this technique shows how simple chemical weapon dissemination
can be. Shortly after this "open canister" dissemination, French forces developed a technique for delivery of phosgene in a non-explosive artillery shell. This technique overcame many of the risks of dealing with gas in cylinders. First, gas shells were independent of the wind and increased the effective range of gas, making any target within reach of guns vulnerable. Second, gas shells could be delivered without warning, especially the clear, nearly odorless phosgenethere are numerous accounts of gas shells, landing with a "plop" rather than exploding, being initially dismissed as dud high explosive or shrapnel shells, giving the gas time to work before the soldiers were alerted and took precautions. The major drawback of artillery delivery was the difficulty of achieving a killing concentration. Each shell had a small gas payload and an area would have to be subjected to
saturation bombardment to produce a cloud to match cylinder delivery. A British solution to the problem was the
Livens Projector. This was effectively a large-bore mortar, dug into the ground that used the gas cylinders themselves as projectiles – firing a cylinder up to . This combined the gas volume of cylinders with the range of artillery. Over the years, there were some refinements in this technique. In the 1950s and early 1960s, chemical artillery rockets and cluster bombs contained a multitude of submunitions, so that a large number of small clouds of the chemical agent would form directly on the target.
Thermal dissemination gas bomb Thermal dissemination is the use of explosives or
pyrotechnics to deliver chemical agents. This technique, developed in the 1920s, was a major improvement over earlier dispersal techniques, in that it allowed significant quantities of an agent to be disseminated over a considerable distance. Thermal dissemination remains the principal method of disseminating chemical agents today. Most thermal dissemination devices consist of a bomb or projectile shell that contains a chemical agent and a central "burster" charge; when the burster detonates, the agent is expelled laterally. Thermal dissemination devices, though common, are not particularly efficient. First, a percentage of the agent is lost by incineration in the initial blast and by being forced onto the ground. Second, the sizes of the particles vary greatly because explosive dissemination produces a mixture of liquid droplets of variable and difficult to control sizes. The efficacy of thermal detonation is greatly limited by the flammability of some agents. For flammable aerosols, the cloud is sometimes totally or partially ignited by the disseminating explosion in a phenomenon called
flashing. Explosively disseminated VX will ignite roughly one third of the time. Despite a great deal of study, flashing is still not fully understood, and a solution to the problem would be a major technological advance. Despite the limitations of central bursters, most nations use this method in the early stages of chemical weapon development, in part because standard munitions can be adapted to carry the agents.
Aerodynamic dissemination Aerodynamic dissemination is the non-explosive delivery of a chemical agent from an aircraft, allowing aerodynamic stress to disseminate the agent. This technique is the most recent major development in chemical agent dissemination, originating in the mid-1960s. This technique eliminates many of the limitations of thermal dissemination by eliminating the flashing effect and theoretically allowing precise control of particle size. In actuality, the altitude of dissemination, wind direction and velocity, and the direction and velocity of the aircraft greatly influence particle size. There are other drawbacks as well; ideal deployment requires precise knowledge of
aerodynamics and
fluid dynamics, and because the agent must usually be dispersed within the
boundary layer (less than above the ground), it puts pilots at risk. Significant research is still being applied toward this technique. For example, by modifying the properties of the liquid, its breakup when subjected to aerodynamic stress can be controlled and an idealized particle distribution achieved, even at
supersonic speed. Additionally, advances in
fluid dynamics,
computer modeling, and
weather forecasting allow an ideal direction, speed, and altitude to be calculated, such that warfare agent of a predetermined particle size can predictably and reliably hit a target.
Protection against chemical warfare Ideal protection begins with nonproliferation treaties such as the CWC, and detecting, very early, the
signatures of someone building a chemical weapons capability. These include a wide range of intelligence disciplines, such as economic analysis of exports of
dual-use chemicals and equipment, human intelligence (
HUMINT) such as diplomatic, refugee, and agent reports; photography from satellites, aircraft and drones (
IMINT); examination of captured equipment (
TECHINT); communications intercepts (
COMINT); and detection of chemical manufacturing and chemical agents themselves (
MASINT). If all the preventive measures fail and there is a clear and present danger, then there is a need for detection of chemical attacks, collective protection, and decontamination. Since industrial accidents can cause dangerous chemical releases (e.g., the
Bhopal disaster), these activities are things that civilian, as well as military, organizations must be prepared to carry out. In civilian situations in
developed countries, these are duties of
HAZMAT organizations, which most commonly are part of fire departments. Detection has been referred to above, as a technical MASINT discipline; specific military procedures, which are usually the model for civilian procedures, depend on the equipment, expertise, and personnel available. When chemical agents are detected, an alarm needs to sound, with specific warnings over emergency broadcasts and the like. There may be a warning to expect an attack. If, for example, the captain of a
US Navy ship believes there is a serious threat of chemical, biological, or radiological attack, the crew may be ordered to set Circle William, which means closing all openings to outside air, running breathing air through filters, and possibly starting a system that continually washes down the exterior surfaces. Civilian authorities dealing with an attack or a toxic chemical accident will invoke the
Incident Command System, or local equivalent, to coordinate defensive measures. There may need to be immediate intervention to prevent death, such as injection of
atropine for nerve agents. Decontamination is especially important for people contaminated with persistent agents; many of the fatalities after the
explosion of a WWII US ammunition ship carrying sulfur mustard, in the harbor of Bari, Italy, after a German bombing on December 2, 1943, came when rescue workers, not knowing of the contamination, bundled cold, wet seamen in tight-fitting blankets. For decontaminating equipment and buildings exposed to persistent agents, such as blister agents, VX or other agents made persistent by mixing with a thickener, special equipment and materials might be needed. Some type of neutralizing agent will be needed; e.g. in the form of a spraying device with neutralizing agents such as Chlorine, Fichlor, strong alkaline solutions or enzymes. In other cases, a specific chemical decontaminant will be required. ==Sociopolitical climate==