The presumption that solid and liquid are adjacent states of matter was underscored by
Friedrich Reinitzer in 1888 when he noted a cloudy
mesophase of
cholesteryl benzoate between 145.5 °C and 178.5 °C. The subject was taken up in Germany, and in 1907 also in France by Georges Friedel and
François Grandjean, as they described the "focal conic liquid". Friedel contributed his
Mesomorphic States of Matter to the
Annales des Physiques in 1922. This two-hundred-page work established much of the current terminology in
mesophase physics. First, the
nematic phase he characterized as having microscopic threads (these threads are today interpreted as
disclinations in the director-field in the mesophase). Second, Friedel coined the term
smectic phase for a layered mesophase having the structure of
neat soap. Third, Friedel use the term
cholesteric phase for materials like
cholesteryl benzoate, and noted that such mesophases "involve strong twists around a direction normal to the positive
optical axis". Scientists have followed Friedel's classification and the term
mesophase for the intermediate states has also been adopted from him. He was of the conviction that the term
liquid crystal did not bear scrutiny. Indeed, :The liquid crystals were not crystals at all, but peculiar liquids with some hint of solid properties. == Important publications ==