(an intrusive igneous rock) Igneous rocks are classified according to mode of occurrence, texture, mineralogy, chemical composition, and the geometry of the igneous body. The classification of the many types of igneous rocks can provide important information about the conditions under which they formed. Two important variables used for the classification of igneous rocks are particle size, which largely depends on the cooling history, and the mineral composition of the rock.
Feldspars,
quartz or
feldspathoids,
olivines,
pyroxenes,
amphiboles, and
micas are all important minerals in the formation of almost all igneous rocks, and they are basic to the classification of these rocks. All other minerals present are regarded as nonessential in almost all igneous rocks and are called
accessory minerals. Types of igneous rocks with other essential minerals are very rare, but include
carbonatites, which contain essential
carbonates. In a simplified compositional classification, igneous rock types are categorized into felsic or mafic based on the abundance of silicate minerals in the Bowen's Series. Rocks dominated by quartz, plagioclase, alkali feldspar and muscovite are felsic. Mafic rocks are primarily composed of biotite, hornblende, pyroxene and olivine. Generally, felsic rocks are light colored and mafic rocks are darker colored. An igneous rock with larger, clearly discernible crystals embedded in a finer-grained matrix is termed
porphyry. Porphyritic texture develops when the larger crystals, called phenocrysts, grow to considerable size before the main mass of the magma crystallizes as finer-grained, uniform material called groundmass. Grain size in igneous rocks results from cooling time so porphyritic rocks are created when the magma has two distinct phases of cooling. Mineralogical classification of an intrusive rock begins by determining if the rock is ultramafic, a carbonatite, or a
lamprophyre. An ultramafic rock contains more than 90% of iron- and magnesium-rich minerals such as hornblende, pyroxene, or olivine, and such rocks have their own classification scheme. Likewise, rocks containing more than 50% carbonate minerals are classified as carbonatites, while lamprophyres are rare ultrapotassic rocks. Both are further classified based on detailed mineralogy. In the great majority of cases, the rock has a more typical mineral composition, with significant quartz, feldspars, or feldspathoids. Classification is based on the percentages of quartz, alkali feldspar, plagioclase, and feldspathoid out of the total fraction of the rock composed of these minerals, ignoring all other minerals present. These percentages place the rock somewhere on the
QAPF diagram, which often immediately determines the rock type. In a few cases, such as the diorite-gabbro-anorthite field, additional mineralogical criteria must be applied to determine the final classification. Where the mineralogy of a volcanic rock can be determined, it is classified using the same procedure, but with a modified QAPF diagram whose fields correspond to volcanic rock types.
Chemical classification and petrology When it is impractical to classify a volcanic rock by mineralogy, the rock must be classified chemically. There are relatively few minerals that are important in the formation of common igneous rocks, because the magma from which the minerals crystallize is rich in only certain elements:
silicon,
oxygen, aluminium,
sodium,
potassium,
calcium, iron, and
magnesium. These are the elements that combine to form the
silicate minerals, which account for over ninety percent of all igneous rocks. The chemistry of igneous rocks is expressed differently for major and minor elements and for trace elements. Contents of major and minor elements are conventionally expressed as weight percent oxides (e.g., 51% SiO2, and 1.50% TiO2). Abundances of trace elements are conventionally expressed as parts per million by weight (e.g., 420 ppm Ni, and 5.1 ppm Sm). The term "trace element" is typically used for elements present in most rocks at abundances less than 100 ppm or so, but some trace elements may be present in some rocks at abundances exceeding 1,000 ppm. The diversity of rock compositions has been defined by a huge mass of analytical data—over 230,000 rock analyses can be accessed on the web through a site sponsored by the U. S. National Science Foundation (see the External Link to EarthChem). The single most important component is silica, SiO2, whether occurring as quartz or combined with other oxides as feldspars or other minerals. Both intrusive and volcanic rocks are grouped chemically by total silica content into broad categories. •
Felsic rocks have the highest content of silica, and are predominantly composed of the
felsic minerals quartz and feldspar. These rocks (granite, rhyolite) are usually light coloured, and have a relatively low density. •
Intermediate rocks have a moderate content of silica, and are predominantly composed of feldspars. These rocks (diorite, andesite) are typically darker in colour than felsic rocks and somewhat more dense. •
Mafic rocks have a relatively low silica content and are composed mostly of
pyroxenes,
olivines and calcic
plagioclase. These rocks (basalt, gabbro) are usually dark coloured, and have a higher density than felsic rocks. •
Ultramafic rock is very low in silica, with more than 90% of mafic minerals (komatiite,
dunite). This classification is summarized in the following table: The percentage of
alkali metal oxides (
Na2O plus
K2O) is second only to silica in its importance for chemically classifying volcanic rock. The silica and alkali metal oxide percentages are used to place volcanic rock on the
TAS diagram, which is sufficient to immediately classify most volcanic rocks. Rocks in some fields, such as the trachyandesite field, are further classified by the ratio of potassium to sodium (so that potassic trachyandesites are latites and sodic trachyandesites are benmoreites). Some of the more mafic fields are further subdivided or defined by
normative mineralogy, in which an idealized mineral composition is calculated for the rock based on its chemical composition. For example,
basanite is distinguished from
tephrite by having a high normative olivine content. Other refinements to the basic TAS classification include: •
Ultrapotassic – rocks containing molar K2O/Na2O >3. •
Peralkaline – rocks containing molar (K2O + Na2O)/Al2O3 >1. •
Peraluminous – rocks containing molar (K2O + Na2O + CaO)/Al2O3 <1. All three series are found in relatively close proximity to each other at subduction zones where their distribution is related to depth and the age of the subduction zone. The tholeiitic magma series is well represented above young subduction zones formed by magma from relatively shallow depth. The calc-alkaline and alkaline series are seen in mature subduction zones, and are related to magma of greater depths. Andesite and basaltic andesite are the most abundant volcanic rock in island arc which is indicative of the calc-alkaline magmas. Some
island arcs have distributed volcanic series as can be seen in the Japanese island arc system where the volcanic rocks change from tholeiite—calc-alkaline—alkaline with increasing distance from the trench.
History of classification Some igneous rock names date to before the modern era of geology. For example,
basalt as a description of a particular composition of lava-derived rock dates to
Georgius Agricola in 1546 in his work
De Natura Fossilium. The word
granite goes back at least to the 1640s and is derived either from French
granit or Italian
granito, meaning simply "granulate rock". The term
rhyolite was introduced in 1860 by the German traveler and geologist
Ferdinand von Richthofen The naming of new rock types accelerated in the 19th century and peaked in the early 20th century. Much of the early classification of igneous rocks was based on the geological age and occurrence of the rocks. However, in 1902, the American petrologists
Charles Whitman Cross,
Joseph P. Iddings,
Louis V. Pirsson, and
Henry Stephens Washington proposed that all existing classifications of igneous rocks should be discarded and replaced by a "quantitative" classification based on chemical analysis. They showed how vague, and often unscientific, much of the existing terminology was and argued that as the chemical composition of an igneous rock was its most fundamental characteristic, it should be elevated to prime position. Geological occurrence, structure, mineralogical constitution—the hitherto accepted criteria for the discrimination of rock species—were relegated to the background. The completed rock analysis is first to be interpreted in terms of the rock-forming minerals which might be expected to be formed when the magma crystallizes, e.g., quartz feldspars,
olivine, akermannite,
Feldspathoids,
magnetite,
corundum, and so on, and the rocks are divided into groups strictly according to the relative proportion of these minerals to one another. Among these was the classification scheme of M.A. Peacock, which divided igneous rocks into four series: the alkalic, the alkali-calcic, the calc-alkali, and the calcic series. His definition of the alkali series, and the term calc-alkali, continue in use as part of the widely used Irvine-Barager classification, along with W.Q. Kennedy's tholeiitic series. By 1958, there were some 12 separate classification schemes and at least 1637 rock type names in use. In that year,
Albert Streckeisen wrote a review article on igneous rock classification that ultimately led to the formation of the IUGG Subcommission of the Systematics of Igneous Rocks. By 1989 a single system of classification had been agreed upon, which was further revised in 2005. The number of recommended rock names was reduced to 316. These included a number of new names promulgated by the Subcommission. ==Origin of magmas==