Many columns of
limestone rise above the surface of Mono Lake. These limestone towers consist primarily of
calcium carbonate minerals such as
calcite (CaCO3). This type of limestone rock is called
tufa, a term for limestone that forms at low to moderate temperatures.
Tufa tower formation Mono Lake is a highly alkaline lake, or
soda lake.
Alkalinity is a measure of how many
bases are in a
solution, and how well the solution can neutralize
acids.
Carbonate (CO32-) and
bicarbonate (HCO3−) are both bases. Hence, Mono Lake has a very high content of
dissolved inorganic carbon. Through supply of
calcium ions (Ca2+), the water will precipitate
carbonate-minerals such as
calcite (CaCO3). Subsurface waters enter the bottom of Mono Lake through small springs. High concentrations of dissolved calcium ions in these subsurface waters cause huge amounts of calcite to precipitate around the spring orifices. The tufa originally formed at the bottom of the lake. It took many decades, or even centuries, to form the well-known tufa towers. When lake levels fell, the tufa towers rose above the water surface and stand as the pillars seen today (see Mono lake#Lake Level History for more information).
Tufa morphology Description of the Mono Lake tufa dates back to the 1880s, when
Edward S. Dana and
Israel C. Russell made the first systematic descriptions of the Mono Lake tufa. • Lithoid tufa - massive and porous with a rock-like appearance • Dendritic tufa - branching structures that look similar to small shrubs • Thinolitic tufa - large, well-formed crystals of several centimeters Over time, many hypotheses have been developed regarding the formation of the large
thinolite crystals (also referred to as
glendonite) in thinolitic tufa. It was relatively clear that the thinolites represented a calcite
pseudomorph after some unknown original
crystal. Ikaite, or hexahydrated CaCO3, is
metastable and only crystallizes at near-freezing temperatures. It is also believed that calcite crystallization inhibitors, such as
phosphate,
magnesium, and
organic carbon, may help stabilize ikaite. When heated, ikaite breaks down and becomes replaced by smaller crystals of calcite. In the Ikka Fjord of
Greenland, ikaite was also observed to grow in columns similar to the tufa towers of Mono Lake. This has led scientists to believe that thinolitic tufa is an indicator of
past climates in Mono Lake because they reflect very cold temperatures.
Tufa chemistry Russell (1883) studied the chemical composition of the different tufa types in
Lake Lahontan, a large
Pleistocene system of multiple lakes in California, Nevada, and Oregon. Not surprisingly, it was found that the tufas consisted primarily of
CaO and
CO2. However, they also contain minor constituents of
MgO (~2 wt%),
Fe/Al-oxides (.25-1.29 wt%), and
PO5 (0.3 wt%). ==Climate==