Pesticides are commonly applied by the use of mechanical
sprayers. Sprayers convert a
pesticide formulation, often consisting of a mixture of water, the pesticide, and other components (
adjuvants, for example) into droplets, which are applied to the crop. Ideally, the pesticide droplets attach evenly to the targeted crop. Because components of the mist are highly mobile,
spray drift can occur, especially for smaller droplets. Some pesticides mists are visible, appearing cloud-like, while others can be invisible and odorless. The quality of sprayer equipment affects drift problems. Sprayer tanks contaminated with another herbicide are one source of drift. Conversely, wind drift is also an efficient mechanism for moving droplets of an appropriate size range to their targets over a wide area with
ultra-low volume (ULV) spraying. "Drift retardants" are compounds added to the spray mixture to suppress pesticide drift. A typical retardant is
polyacrylamide. These polymers suppress the formation of tiny droplets. Weather conditions and timing affect the drift problem. The efficiency of the spray and reach of the spray drift can be computed. In addition to weather,
windbreaks can mitigate the effects of drift. Other ways to mitigate spray drift is to apply the pesticide directly to the desired treatment area, as well as paying attention to where surface waters, gutters, drainage ditches, and storm drains are located. This is to make sure that the pesticide is applied in a way that prevents it from getting in to these spaces. Most herbicides are organic compounds of low volatility, unlike
fumigants, which are usually gases. Several are salts and others have
boiling points above 100 °C (
Dicamba is a solid that melts at 114°C). Thus, drift often entails mobilization of droplets, which can be very small. The contribution from their volatility, low as they are, cannot be ignored, either. A distinction has been made between "exo-drift" (the transfer of spray out of the target area) and endo-drift, where the
active ingredient (AI) in droplets falls into the target area, but does not reach the biological target. "Endo-drift" is volumetrically more significant and may therefore cause greater ecological contamination (e.g. where chemical pesticides pollute
ground water).
Dicamba drift Dicamba drift is a particular problem, as has been recognized since at least 1979. The effects have been noted for many crops: grapes, tomatoes, soybeans. In 2017, Dicamba-resistant soybeans and cotton were approved for use in the US. This new technology worsened the drift problem because these farmers could use Dicamba more freely. Although already low in volatility, as discussed above, Dicamba can be made even less volatile by conversion to various salts. The approach entails treatment of Dicamba with
amines, which form ammonium salts. These salts are described by their acronyms BAPMA-Dicamba and DGA-Dicamba. Although these salts are of lower volatility in laboratory tests, in the field the situation is more complicated, and drift remains a problem. ==Safety and society==