"Picking Up the Pieces" has received generally positive reviews from critics. Colin Gentry of
4Music said "Picking Up the Pieces" is "a classy, pacey song of trying to compete with a lover's ex-girlfriend. It's hard to imagine anyone putting our Paloma in the shade, and her pained vocals certainly belt out loud enough for everyone to hear her angst."
Digital Spy's Robert Copsey and Lewis Corner thought the single was "an anthemic trailer of sweeping strings and relentless drums", which felt "as intimate" as Faith's previous work. In his official review, Corner gave "Picking Up the Pieces" five stars and stated Faith "may not think she's able to obtain the prime ideal of perfection, but 'Picking Up The Pieces' skirts dangerously close – and for that alone, it's more than worthy of some global recognition." Tim Ingham of
Music Week branded the track a "thumping thick-skinned anthem". So So Gay's Leo Kristoffersson said the song's lyrics "are delivered with Faith's characteristically affirmative vocals". He added "The smoky, jazz-tinged vocal style we have become accustomed to are slightly sharper on the track, which reflects the angst that inspired the track perfectly. We predict big things for this track." David of
We Love Pop magazines gave the single a mixed review. He said "Picking Up the Pieces" was "predictable but strong". He added "We enjoy pop stars that are both a little bit bonkers and are in charge of their own careers; Paloma is both but this song doesn't fully showcase the brilliant pop star she could be." ==Chart performance==