(bleached, ash-colored) horizon and intensely coloured
illuvial horizons. The photo was taken in the Feldberg area, Southern Black Forest, Germany.
Podzolization (or Podsolization) is a complex
soil formation process by which dissolved
organic matter and ions of
iron and
aluminium, released through weathering of various minerals, form organo-mineral complexes (
chelates) and are moved from the upper parts of the soil profile and deposit in the deeper parts of soil. Through this process, the
eluvial horizon becomes bleached and of ash-grey colour. The complexes move with percolating water further down to
illuviated horizons which are commonly coloured brown, red or black as they accumulate and consist of cemented
sesquioxides and/or organic compounds. The podzolization is a typical soil formation process in Podzols.
Preconditions Podzolization usually occurs under
forest or
heath vegetation and is common in cool and humid climates as these climates inhibit the activity of
soil microbes in the topsoil. Overall, podzolization happens where the
decomposition of organic matter is inhibited and as a result, acidic organic surface (mor) layers build up. Under these typically acidic conditions, nutrient deficiency further hampers the microbial degradation of organic complexing agents.
Key steps The soil-forming process of podzolization can be broken down into two main steps: • Mobilization and translocation of organic matter,
Fe and
Al from the surface horizon, and • Immobilization and stabilization of organic matter, Fe and Al into the subsoil. In the topsoil of acidic soils, organic matter (mostly from
plant litter, the humus layer and
root exudates) together with Al- and Fe-ions, form organo-mineral complexes. These soluble
chelates then relocate with percolating water from the
A (or
E horizon) to the
B horizon. As a result of this, the E horizon (or Ae horizon in the
Canadian system of soil classification) is left bleached and ash-grey in colour, while the B horizon becomes enriched with relocated organo-mineral complexes. The colour of B horizon is consequently red, brown or black, depending on the dominance of metal ions or organic matter. Usually, the boundary between the B and eluvial Ae (or E) horizon is very distinct, and sometimes a
hardpan (or Ortstein) can form, as the relocated Fe and Al and organic matter increase mineral particles, cementing them into this compacted layer. There are several reasons why these organo-mineral complexes immobilize in the B horizon: If during the eluviation process more Al- or Fe-ions bind to the organic compounds, the complex can flocculate as the solubility of it decreases with increasing metal to carbon ratio. Apart from that, a higher
pH (or higher Ca content) in the lower
soil horizons can result in the breakdown of metal-humus complexes. In the lower soil layers, the organic complexing agents can be degraded by functioning
microorganisms. Already established complexes in the
B horizon can act as a filter, as they adsorb the traveling complexes from the upper soil horizons. A decreased water conductivity due to higher clay content can also result in the early flocculation of organo-mineral complexes. The relocated substances can sometimes separate in the illuvial horizons. Then, organic substances are mostly enriched in the uppermost part of the illuvial horizon, whereas Fe- and Al-oxides are mostly found in the lower parts of the illuvial horizon. Podzolization also promotes the relocation of some nutrients (
Cu,
Fe,
Mn,
Mo and
P) that sometimes brings them closer to plant
roots. == In different soil classification systems ==