Materials Concrete is a mixture of coarse (stone or brick chips) and fine (generally sand and/or crushed stone) aggregates with a paste of binder material (usually
Portland cement) and water. When cement is mixed with a small amount of water, it
hydrates to form microscopic opaque crystal lattices encapsulating and locking the aggregate into a rigid shape. The aggregates used for making concrete should be free from harmful substances like organic impurities, silt, clay, lignite, etc. Typical concrete mixes have high resistance to
compressive stresses (about ); however, any appreciable
tension (
e.g., due to
bending) will break the microscopic rigid lattice, resulting in cracking and separation of the concrete. For this reason, typical non-reinforced concrete must be well supported to prevent the development of tension. If a material with high strength in tension, such as
steel, is placed in concrete, then the composite material, reinforced concrete, resists not only compression but also bending and other direct tensile actions. A composite section where the concrete resists compression and reinforcement "
rebar" resists tension can be made into almost any shape and size for the construction industry.
Key characteristics Three physical characteristics give reinforced concrete its special properties: • The
coefficient of thermal expansion of concrete is similar to that of steel, eliminating large internal stresses due to differences in
thermal expansion or contraction. • When the cement paste within the concrete hardens, this conforms to the surface details of the steel, permitting any stress to be transmitted efficiently between the different materials. Usually steel bars are roughened or corrugated to further improve the
bond or cohesion between the concrete and steel. • The
alkaline chemical environment provided by the
alkali reserve (KOH, NaOH) and the
portlandite (
calcium hydroxide) contained in the hardened cement paste causes a
passivating film to form on the surface of the steel, making it much more resistant to
corrosion than it would be in neutral or acidic conditions. When the cement paste is exposed to the air and meteoric water reacts with atmospheric CO2,
carbonic acid is formed. Carbonic acid then reacts with the portlandite and
calcium silicate hydrate (CSH) of the hardened cement paste to progressively carbonate them, gradually reducing the high pH from 13.5 – 12.5 to 8.5, the pH of water in equilibrium with
calcite (
calcium carbonate) and the steel is no longer passivated. As a rule of thumb, only to give an idea on orders of magnitude, steel is protected at pH above ~11 but starts to corrode below ~10 depending on steel characteristics and local physico-chemical conditions when concrete becomes carbonated.
Carbonation of concrete along with
chloride ingress are amongst the chief reasons for the failure of
reinforcement bars in concrete. The relative cross-sectional
area of steel required for typical reinforced concrete is usually quite small and varies from 1% for most beams and slabs to 6% for some columns.
Reinforcing bars are normally round in cross-section and vary in diameter. Reinforced concrete structures sometimes have provisions such as ventilated hollow cores to control their moisture & humidity. Distribution of concrete (in spite of reinforcement) strength characteristics along the cross-section of vertical reinforced concrete elements is inhomogeneous.
Mechanism of composite action of reinforcement and concrete The reinforcement in an RC structure, such as a steel bar, has to undergo the same strain or deformation as the surrounding concrete in order to prevent discontinuity, slip, or separation of the two materials under load. Maintaining composite action requires the transfer of load between the concrete and steel. The direct stress is transferred from the concrete to the bar interface so as to change the tensile stress in the reinforcing bar along its length. This load transfer is achieved by means of bond (anchorage) and is idealized as a continuous stress field that develops in the vicinity of the steel-concrete interface. The reasons that the two different material components, concrete and steel, can work together are as follows: (1) Reinforcement can be well bonded to the concrete, thus they can jointly resist external loads and deform. (2) The thermal expansion coefficients of concrete and steel are so close ( to for concrete and for steel) that the thermal stress-induced damage to the bond between the two components can be prevented. (3) Concrete can protect the embedded steel from corrosion and high-temperature-induced softening.
Anchorage (bond) in concrete: Codes of specifications Because the actual bond stress varies along the length of a bar anchored in a zone of tension, current international codes of specifications use the concept of development length rather than bond stress. The main requirement for safety against bond failure is to provide a sufficient extension of the length of the bar beyond the point where the steel is required to develop its yield stress, and this length must be at least equal to its development length. However, if the actual available length is inadequate for full development, special anchorages must be provided, such as cogs, hooks or mechanical end plates. The same concept applies to lap splice length mentioned in the codes where splices (overlapping) provided between two adjacent bars in order to maintain the required continuity of stress in the splice zone.
Anticorrosion measures In wet and cold climates, reinforced concrete for roads, bridges, parking structures, and other structures that may be exposed to
deicing salt may benefit from the use of corrosion-resistant reinforcement such as uncoated, low carbon/chromium (micro composite), epoxy-coated, hot dip galvanized or
stainless steel rebar. Good design and a well-chosen concrete mix will provide additional protection for many applications. Uncoated, low carbon/chromium rebar looks similar to standard carbon steel rebar due to its lack of a coating; its highly corrosion-resistant features are inherent in the steel microstructure. It can be identified by the unique ASTM specified mill marking on its smooth, dark charcoal finish. Epoxy-coated rebar can easily be identified by the light green color of its epoxy coating. Hot dip galvanized rebar may be bright or dull gray depending on length of exposure, and stainless rebar exhibits a typical white metallic sheen that is readily distinguishable from carbon steel reinforcing bar. Reference ASTM standard specifications
A1035/A1035M Standard Specification for Deformed and Plain Low-carbon, Chromium, Steel Bars for Concrete Reinforcement,
A767 Standard Specification for Hot Dip Galvanized Reinforcing Bars,
A775 Standard Specification for Epoxy Coated Steel Reinforcing Bars and
A955 Standard Specification for Deformed and Plain Stainless Bars for Concrete Reinforcement. Another, cheaper way of protecting rebars is coating them with
zinc phosphate. Zinc phosphate slowly reacts with
calcium cations and the
hydroxyl anions present in the cement pore water and forms a stable
hydroxyapatite layer. Penetrating sealants typically must be applied some time after curing. Sealants include paint, plastic foams, films and
aluminum foil, felts or fabric mats sealed with tar, and layers of
bentonite clay, sometimes used to seal roadbeds.
Corrosion inhibitors, such as
calcium nitrite [Ca(NO2)2], can also be added to the water mix before pouring concrete. Generally, 1–2 wt. % of [Ca(NO2)2] with respect to cement weight is needed to prevent corrosion of the rebars. The nitrite anion is a mild
oxidizer that oxidizes the soluble and mobile
ferrous ions (Fe2+) present at the surface of the corroding steel and causes them to precipitate as an insoluble
ferric hydroxide (Fe(OH)3). This causes the passivation of steel at the
anodic oxidation sites. Nitrite is a much more active corrosion inhibitor than
nitrate, which is a less powerful oxidizer of the divalent iron. ==Reinforcement and terminology of beams==