Main characters ; : :The sole member of a Jersey Club who often helps out other clubs and people in need and is passionate about her home town of Kamogawa. She has a habit of saying and draws a circle in the air when she finishes helping someone. She soon discovers she has the ability to pilot a strange robotic aircraft known as the Vox Aura, which she previously encountered ten years ago when she almost drowned. She names this Vox unit Midori, after its green color. In Season 2, she is in her last year of high school and has not thought what she is going to do for the future. She still helps out with the Jersey Club and her uncle's new beach cafe. ; : :An alien girl from the home planet Le Garite, who was sent to protect Madoka and the aircraft. She is not used to Earth culture and often picks up terms from the strangest sources, often barking like a dog (i.e. saying ) after Asteria tricked her into thinking it was a standard Earth greeting. Not only that, her unfamiliarity with Earth's culture makes her somewhat clumsy as well. She was initially unable to properly utilize her Vox Unit as the knowledge of a supposed fate concerning Vox pilots caused her to become afraid. However, Madoka helps her overcome her fear and she becomes able to use her Vox unit, Vox Rympha, which she names Orca. She is particularly jealous towards Muginami, who shows a lot of interest in Madoka, which leads to her joining the Jersey Club and begin living with Madoka. Due to her luxurious upbringing as princess of the planet Le Garite, Lan has little understanding of the commoners' lifestyle. She returns in Season 2. Though she looks that same, Madoka pointed out she grew up a little bit. ; : :Another Ovid pilot who transfers in Madoka's class and joins the Jersey Club. Although she appears to have a slow-witted personality, she is actually sharp and perceptive. She will occasionally say . Born on a Prison Planet, she views Villagulio as an older brother and by his orders, she infiltrated the Pharos base to steal one of the Ovids, thus she ends up becoming the pilot of Vox Ignis, which she nicknamed Hupo. Other than becoming a pilot, she also shows her professional skills of a lifeguard, a martial artist, and a waitress on occasions. After being betrayed and abandoned by Villagulio, Muginami finds herself a new place among Madoka and her friends. After Villagulio's second skirmish, she and her Vox Unit took him and retreated into space. She returns in Season 2 where, after realizing she doesn't want to fight those she loves, rejoins the Jersey Club. Hupo is now equipped with an energy cape she uses as a shield.
Kamogawa residents ; : :Madoka's cousin who is a researcher on underwater archaeology and tried to prevent Madoka from coming into contact with the Vox Unit. She gives in to Madoka's decision to pilot Vox Aura but only on the condition that Madoka is to continue with her daily life as usual. She is a former member of the Jersey Club who inspired Madoka to be like her. In Season 2, she continues her research on the Vox Units and the Rin-ne. ; : :Madoka's uncle and Youko's father who owns the 'Be With Hiroshi' restaurant, where Madoka lives. In Season 2, he opened a beach cafe which did much better than his restaurant ever did since Le Garite reveal themselves to the public. ; : :A teacher at Madoka's school, who was a member of the Jersey Club along Youko and Madoka's mother. ; : :Youko's assistant. In Season 2, he and Youko are continuing her research on the Vox Units and the Rin-ne.
Novumundus ; : :The commander of the Pharos facility. ; : ; : :The granddaughter of the chairman of Novumundus, who provides most of the orders in the organization. She dresses in
Lolita fashion and wields a great deal of authority. She also has a memoria on her chest. In Season 2, she reveals herself as the reincarnation of Queen Maycun who almost destroyed Earth 20,000 years ago by "opening" the Rin-ne and feeling responsible.
De Metrio ; : :The disowned prince of De Metrio who was thrown into Muginami's home planet and became close to her. Soon after, he formed the rebellious organization "Kiss" and sent Muginami to Kamogawa to investigate about the Vox Units, but apparently gets angry at her for becoming the pilot of Vox Ignis and abandons her, while actually it was part of his plan to have her get close to Madoka and the others. In Season 2, it is revealed that Villagulio reclaimed the throne of De Metrio and is currently at war with Le Garite. ; : :Former antagonist that piloted the Ovid Libertas. He is the oldest of the three and the most experienced. In Season 2, he is now working at Hiroshi's new beach cafe as a waiter (in butler cosplay) after Villagulio's second skirmish. He seems to attract a lot of customers, specifically female customers. He is also the reason why the beach cafe is doing much better than Hiroshi's restaurant. ; : :Former antagonist that piloted the Ovid Voluntas. He tends to be rebellious, but is understanding. In Season 2, he is now working at Hiroshi's new beach cafe as a cook (which he is pretty good) after Villagulio's second skirmish. He really enjoys life on Earth. ; : :Former antagonist that pilots the Ovid Teneritas. He is the youngest of the three and the least experienced. He has a fetish for maid outfits and looks very good in it (even though he looks like a pretty girl). In Season 2, he is now working at Hiroshi's new beach cafe as a waiter (in maid cosplay) after Villagulio's second skirmish. ; : :The princess of De Metrio and Villagulio's sister. She was presumed dead after a failed Vox Particle Control Experiment with disastrous consequences. It is later revealed that she survived the experiment and rescued by Le Garite following the Tradegy of Militia Zodia, since then secretly under Dizelmine's care. ; : :Villagulio's right-hand woman.
Le Garite ; : :The crown prince of Le Garite and Lan's older brother. His true objective is making use of Madoka and the Vox Units to destroy the planet De Metrio, as part of his plan to ensure Le Garite's survival as both planets' respective planetary systems are en route of collision. He ended up becoming a young kid after leaving the Rin-ne due to his wishes to right his wrongs. ; : :Dizelmine's aide who was an observator at Pharos during the first season, and since then returned to assist his master. It is revealed he manipulated Dizelmine into opening the Rin-ne, and is also responsible for Queen Maycun who nearly destroyed the Earth 20,000 years ago.
Mecha ; :17.3 meters tall and piloted by Madoka; is later renamed Midori. Originally devoid of weapons, it is specialized in close quarters combat and later in the series it is equipped with a sword called the Formula 32 and a left wrist energy shield. Also comes with a Velociraptor Attachment. ; :17.3 meters tall and piloted by Lan; is later renamed Orca. Armaments include a right wrist sword-machine gun hybrid armed with 120mm bullets and a left wrist energy shield. ; :17.4 meters tall and piloted by Muginami; is later renamed Hupo. Armaments include a pair of energy guns that can combine into a double sided sword, a beam cannon, and in the second half of the series an energy cape. ; :17.4 meters tall and piloted by Kirius. Armaments include a metal staff, a pair of heat swords that can convert into whips, and a force field. ; :17.9 meters tall and piloted by Izo. Armaments include a pair of heat clubs and a force field. ; :17.4 meters tall and piloted by Array. Armaments include an energy cannon on each shoulder and a force field. ; :19 meters tall and piloted by Villagulio. Armaments include an anchor in each arm, a pair of large swords, and a large mortar gun called the Death Wish. It is upgraded to Avarium Sepera in the second half of the series. ; :Piloted by Dizelmine. Is armed with a sword in the right wrist. Later revealed to be a fourth Vox Unit. ==Media==