The snowball Earth hypothesis was originally devised to explain geological evidence for the apparent presence of glaciers at tropical latitudes. According to modelling, an
ice–albedo feedback would result in glacial ice rapidly advancing to the equator once the glaciers spread to within 25° of the equator. Therefore, the presence of glacial deposits within the tropics suggests global ice cover. Critical to an assessment of the validity of the theory, therefore, is an understanding of the reliability and significance of the evidence that led to the belief that ice ever reached the tropics. This evidence must prove three things: • That a bed contains sedimentary structures that could have been formed only by glacial activity; • That the bed lay within the tropics when it was deposited. • That glaciers were active at different global locations at the same time, and that no other deposits of the same age are in existence. This last point is very difficult to prove. Before the
Ediacaran, the
biostratigraphic markers usually used to correlate rocks are absent; therefore there is no way to prove that rocks in different places across the globe were deposited at the same time. The best that can be done is to estimate the age of the rocks using
radiometric dating, which are rarely accurate to better than a million years or so.
Palaeomagnetism The snowball Earth hypothesis was first posited to explain what were then considered to be glacial deposits near the equator. Since tectonic plates move slowly over time, ascertaining their position at a given point in Earth's long history is not easy. In addition to considerations of how the recognizable landmasses could have fit together, the latitude at which a rock was deposited can be constrained by palaeomagnetism. When
sedimentary rocks form, magnetic minerals within them tend to align with
Earth's magnetic field. Through the precise measurement of this palaeomagnetism, it is possible to estimate the
latitude (but not the
longitude) where the rock matrix was formed. Palaeomagnetic measurements have indicated that some sediments of glacial origin in the Neoproterozoic rock record were deposited within 10 degrees of the equator, although the accuracy of this reconstruction is in question. Another weakness of reliance on palaeomagnetic data is the difficulty in determining whether the magnetic signal recorded is original, or whether it has been reset by later activity. For example, a mountain-building
orogeny releases hot water as a by-product of
metamorphic reactions; this water can circulate to rocks thousands of kilometers away and reset their magnetic signature. This makes the authenticity of rocks older than a few million years difficult to determine without painstaking mineralogical observations. Moreover, further evidence is accumulating that large-scale remagnetization events have taken place which may necessitate revision of the estimated positions of the palaeomagnetic poles. There is currently only one deposit, the Elatina deposit of Australia, that was indubitably deposited at low latitudes; its depositional date is well-constrained, and the signal is demonstrably original.
Low-latitude glacial deposits of the
Neoproterozoic Pocatello Formation, a "snowball Earth"-type deposit below
Ediacaran GSSP site in the
Flinders Ranges NP, South Australia.
A$1 coin is for scale. Sedimentary rocks that are deposited by glaciers have distinctive features that enable their identification. Long before the advent of the snowball Earth hypothesis, many Neoproterozoic sediments had been interpreted as having a glacial origin, including some apparently at tropical latitudes at the time of their deposition. However, many sedimentary features traditionally associated with glaciers can also be formed by other means. Thus the glacial origin of many of the key occurrences for snowball Earth has been contested. Evidence of possible glacial origin of sediment includes: •
Dropstones (stones dropped into marine sediments), which can be deposited by glaciers or other phenomena. •
Varves (annual sediment layers in periglacial lakes), which can form at higher temperatures. •
Diamictites (poorly sorted conglomerates). Originally described as glacial
till, most were in fact formed by
debris flows.
Open-water deposits It appears that some deposits formed during the snowball period could only have formed in the presence of an active
hydrological cycle. Bands of glacial deposits up to 5,500 meters thick, separated by small (meters) bands of non-glacial sediments, demonstrate that glaciers melted and re-formed repeatedly for tens of millions of years; solid oceans would not permit this scale of deposition. It is considered possible that
ice streams such as seen in
Antarctica today could have caused these sequences. Further, sedimentary features that could only form in open water (for example:
wave-formed ripples, far-traveled
ice-rafted debris and indicators of
photosynthetic activity) can be found throughout sediments dating from the snowball-Earth periods. While these may represent "
oases" of
meltwater on a completely frozen Earth,
Carbon isotope ratios There are two stable
isotopes of carbon in sea water:
carbon-12 (12C) and the rare
carbon-13 (13C), which makes up about 1.109 percent of carbon atoms.
Biochemical processes, of which
photosynthesis is one, tend to preferentially incorporate the lighter 12C isotope. Thus ocean-dwelling photosynthesizers, both
protists and
algae, tend to be very slightly depleted in 13C, relative to the abundance found in the primary volcanic sources of Earth's carbon. Therefore, an ocean with photosynthetic life will have a lower 13C/12C ratio within organic remains and a higher ratio in corresponding ocean water. The organic component of the lithified sediments will remain very slightly, but measurably, depleted in 13C.
Silicate weathering, an inorganic process by which carbon dioxide is drawn out of the atmosphere and deposited in rock, also fractionates carbon. The emplacement of several
large igneous provinces shortly before the Cryogenian and the subsequent chemical
weathering of the enormous continental
flood basalts produced by them, aided by the breakup of Rodinia that exposed many of these flood basalts to warmer, moister conditions closer to the coast and accelerated chemical weathering, is also believed to have caused a major positive shift in carbon isotopic ratios and contributed to the beginning of the Sturtian glaciation. During the proposed episode of snowball Earth, there are rapid and extreme negative excursions in the ratio of 13C to 12C. Close analysis of the timing of 13C 'spikes' in deposits across the globe allows the recognition of four, possibly five, glacial events in the late Neoproterozoic.
Cap carbonate rocks in the Swiss Alps, photographed in 2005 Around the top of Neoproterozoic glacial deposits there is commonly a sharp transition into a chemically precipitated sedimentary
limestone or
dolomite metres to tens of metres thick. Period. These cap carbonates have unusual chemical composition as well as strange sedimentary structures that are often interpreted as large ripples. The formation of such sedimentary rocks could be caused by a large influx of positively charged
ions, as would be produced by rapid weathering during the extreme greenhouse following a snowball Earth event. The isotopic signature of the cap carbonates is near −5‰, consistent with the value of the mantle—such a low value could be taken to signify an absence of life, since photosynthesis usually acts to raise the value; alternatively the release of methane deposits could have lowered it from a higher value and counterbalance the effects of photosynthesis. The mechanism involved in the formation of cap carbonates is not clear, but the most cited explanation suggests that at the melting of a snowball Earth, water would dissolve the abundant from the atmosphere to form
carbonic acid, which would fall as
acid rain. This would weather exposed
silicate and
carbonate rock (including readily attacked glacial debris), releasing large amounts of calcium, which when washed into the ocean would form distinctively textured layers of carbonate sedimentary rock. Such an abiotic "cap carbonate" sediment can be found on top of the glacial till that gave rise to the snowball Earth hypothesis. However, there are some problems with the designation of a glacial origin to cap carbonates. The high carbon dioxide concentration in the atmosphere would cause the oceans to become acidic and dissolve any carbonates contained within—starkly at odds with the deposition of cap carbonates. The thickness of some cap carbonates is far above what could reasonably be produced in the relatively quick deglaciations. The cause is further weakened by the lack of cap carbonates above many sequences of clear glacial origin at a similar time and the occurrence of similar carbonates within the sequences of proposed glacial origin.
Changing acidity Isotopes of
boron suggest that the
pH of the oceans dropped dramatically before and after the
Marinoan glaciation. This may indicate a buildup of carbon dioxide in the atmosphere, some of which would dissolve into the oceans to form carbonic acid. Although the boron variations may be evidence of extreme climate change, they need not imply a global glaciation.
Space dust Earth's surface is very depleted in
iridium, which primarily resides in Earth's core. The only significant source of the element at the surface is cosmic particles that reach Earth. During a snowball Earth, iridium would accumulate on the ice sheets, and when the ice melted the resulting layer of sediment would be rich in iridium. An
iridium anomaly has been discovered at the base of the cap carbonate formations and has been used to suggest that the glacial episode lasted for at least 3 million years,
Cyclic climate fluctuations Using the ratio of mobile
cations to those that remain in soils during chemical weathering (the chemical index of alteration), it has been shown that chemical weathering varied in a cyclic fashion within a glacial succession, increasing during interglacial periods and decreasing during cold and arid glacial periods. The significance of these deposits is highly reliant upon their dating. Glacial sediments are difficult to date, and the closest dated bed to the Port Askaig group is 8 km stratigraphically above the beds of interest. Its dating to 600 Ma means the beds can be tentatively correlated to the Sturtian glaciation, but they may represent the advance or retreat of a snowball Earth. ==Mechanisms==