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Stefan–Boltzmann law

The Stefan–Boltzmann law, also known as Stefan's law, describes the intensity of the thermal radiation emitted by matter in terms of that matter's temperature. It is named for Josef Stefan, who empirically derived the relationship, and Ludwig Boltzmann who derived the law theoretically.

Detailed explanation
The radiant exitance (previously called radiant emittance), M, has dimensions of energy flux (energy per unit time per unit area), and the SI units of measure are joules per second per square metre (J⋅s⋅m), or equivalently, watts per square metre (W⋅m).) A so-called grey body is a body for which the spectral emissivity is independent of wavelength, so that the total emissivity, \varepsilon, is a constant. In the more general (and realistic) case, the spectral emissivity depends on wavelength. The total emissivity, as applicable to the Stefan–Boltzmann law, may be calculated as a weighted average of the spectral emissivity, with the blackbody emission spectrum serving as the weighting function. It follows that if the spectral emissivity depends on wavelength then the total emissivity depends on the temperature, i.e., \varepsilon = \varepsilon(T). metamaterials, and other nanostructures are not subject to ray-optical limits and may be designed to have an emissivity greater than 1. In national and international standards documents, the symbol M is recommended to denote radiant exitance; a superscript circle (°) indicates a term relative to a black body. (A subscript "e" is added when it is important to distinguish the energetic (radiometric) quantity radiant exitance, M_\mathrm{e}, from the analogous human vision (photometric) quantity, luminous exitance, denoted M_\mathrm{v}.) In common usage, the symbol used for radiant exitance (often called radiant emittance) varies among different texts and in different fields. The Stefan–Boltzmann law may be expressed as a formula for radiance as a function of temperature. Radiance is measured in watts per square metre per steradian (W⋅m⋅sr). The Stefan–Boltzmann law for the radiance of a black body is: L^\circ_\Omega = \frac{M^{\circ}}\pi = \frac\sigma\pi\, T^{4}. The Stefan–Boltzmann law expressed as a formula for radiation energy density is: w^\circ_\mathrm{e} = \frac{4}{c} \, M^\circ = \frac{4}{c} \, \sigma\, T^{4} , where c is the speed of light. == History ==
History
In 1864, John Tyndall presented measurements of the infrared emission by a platinum filament and the corresponding color of the filament. The proportionality to the fourth power of the absolute temperature was deduced by Josef Stefan (1835–1893) in 1877 on the basis of Tyndall's experimental measurements, in the article Über die Beziehung zwischen der Wärmestrahlung und der Temperatur (On the relationship between thermal radiation and temperature) in the Bulletins from the sessions of the Vienna Academy of Sciences. A derivation of the law from theoretical considerations was presented by Ludwig Boltzmann (1844–1906) in 1884, drawing upon the work of Adolfo Bartoli. Bartoli in 1876 had derived the existence of radiation pressure from the principles of thermodynamics. Following Bartoli, Boltzmann considered an ideal heat engine using electromagnetic radiation instead of an ideal gas as working matter. The law was almost immediately experimentally verified. Heinrich Weber in 1888 pointed out deviations at higher temperatures, but perfect accuracy within measurement uncertainties was confirmed up to temperatures of 1535 K by 1897. The law, including the theoretical prediction of the Stefan–Boltzmann constant as a function of the speed of light, the Boltzmann constant and the Planck constant, is a direct consequence of Planck's law as formulated in 1900. == Stefan–Boltzmann constant ==
Stefan–Boltzmann constant
The Stefan–Boltzmann constant, , is derived from other known physical constants: \sigma = \frac{2 \pi^5 k^4}{15 c^2 h^3} = \frac{\pi^2 k^4}{60 c^2 \hbar^3} where is the Boltzmann constant, the is the Planck constant (with \hbar = h/2\pi the reduced Planck constant), and is the speed of light in vacuum. The numerical value of the Stefan–Boltzmann constant is different in other systems of units, as shown in the table below. == Examples ==
Examples
Temperature of the Sun and radiant exitance vs. black-body temperature. Red arrows show that 5780 K black bodies have 501 nm peak and 63.3 MW/m2 radiant exitance. With his law, Stefan also determined the temperature of the Sun's surface. He inferred from the data of Jacques-Louis Soret (1827–1890) that the energy flux density from the Sun is 29 times greater than the energy flux density of a certain warmed metal lamella (a thin plate). A round lamella was placed at such a distance from the measuring device that it would be seen at the same angular diameter as the Sun. Soret estimated the temperature of the lamella to be approximately 1900 °C to 2000 °C. Stefan surmised that 1/3 of the energy flux from the Sun is absorbed by the Earth's atmosphere, so he took for the correct Sun's energy flux a value 3/2 times greater than Soret's value, namely 29 × 3/2 = 43.5. Precise measurements of atmospheric absorption were not made until 1888 and 1904. The temperature Stefan obtained was a median value of previous ones, 1950 °C and the absolute thermodynamic one 2200 K. As 2.574 = 43.5, it follows from the law that the temperature of the Sun is 2.57 times greater than the temperature of the lamella, so Stefan got a value of 5430 °C or 5700 K. This was the first sensible value for the temperature of the Sun. Before this, values ranging from as low as 1800 °C to as high as were claimed. The lower value of 1800 °C was determined by Claude Pouillet (1790–1868) in 1838 using the Dulong–Petit law. Pouillet also took just half the value of the Sun's correct energy flux. Temperature of stars The temperature of stars other than the Sun can be approximated using a similar means by treating the emitted energy as a black body radiation. So: L = 4 \pi R^2 \sigma T^4 where is the luminosity, is the Stefan–Boltzmann constant, is the stellar radius and is the effective temperature. This formula can then be rearranged to calculate the temperature: T = \sqrt[4]{\frac{L}{4 \pi R^2 \sigma}} or alternatively the radius: R = \sqrt{\frac{L}{4 \pi \sigma T^4}} The same formulae can also be simplified to compute the parameters relative to the Sun: \begin{align} \frac{L}{L_\odot} &= \left(\frac{R}{R_\odot}\right)^2 \left(\frac{T}{T_\odot}\right)^4 \\[1ex] \frac{T}{T_\odot} &= \left(\frac{L}{L_\odot}\right)^{1/4} \left(\frac{R_\odot}{R}\right)^{1/2} \\[1ex] \frac{R}{R_\odot} &= \left(\frac{T_\odot}{T}\right)^2 \left(\frac{L}{L_\odot}\right)^{1/2} \end{align} where R_\odot is the solar radius, and so forth. They can also be rewritten in terms of the surface area A and radiant exitance M^{\circ}: \begin{align} L &= A M^{\circ} \\[1ex] M^{\circ} &= \frac{L}{A} \\[1ex] A &= \frac{L}{M^{\circ}} \end{align} where A = 4 \pi R^2 and M^{\circ} = \sigma T^{4}. With the Stefan–Boltzmann law, astronomers can easily infer the radii of stars. The law is also met in the thermodynamics of black holes in so-called Hawking radiation. Effective temperature of the Earth Similarly we can calculate the effective temperature of the Earth T⊕ by equating the energy received from the Sun and the energy radiated by the Earth, under the black-body approximation (Earth's own production of energy being small enough to be negligible). The luminosity of the Sun, L☉, is given by: L_\odot = 4\pi R_\odot^2 \sigma T_\odot^4 At Earth, this energy is passing through a sphere with a radius of a0, the distance between the Earth and the Sun, and the irradiance (received power per unit area) is given by E_\oplus = \frac{L_\odot}{4\pi a_0^2} The Earth has a radius of R⊕, and therefore has a cross-section of \pi R_\oplus^2. The radiant flux (i.e. solar power) absorbed by the Earth is thus given by: \Phi_\text{abs} = \pi R_\oplus^2 \times E_\oplus Because the Stefan–Boltzmann law uses a fourth power, it has a stabilizing effect on the exchange and the flux emitted by Earth tends to be equal to the flux absorbed, close to the steady state where: \begin{align} 4\pi R_\oplus^2 \sigma T_\oplus^4 &= \pi R_\oplus^2 \times E_\oplus \\ &= \pi R_\oplus^2 \times \frac{4\pi R_\odot^2\sigma T_\odot^4}{4\pi a_0^2} \\ \end{align} T⊕ can then be found: \begin{align} T_\oplus^4 &= \frac{R_\odot^2 T_\odot^4}{4 a_0^2} \\ T_\oplus &= T_\odot \times \sqrt\frac{R_\odot}{2 a_0} \\ & = 5780 \; {\rm K} \times \sqrt{6.957 \times 10^{8} \; {\rm m} \over 2 \times 1.495\ 978\ 707 \times 10^{11} \; {\rm m} } \\ & \approx 279 \; {\rm K} \end{align} where T☉ is the temperature of the Sun, R☉ the radius of the Sun, and a0 is the distance between the Earth and the Sun. This gives an effective temperature of 6 °C on the surface of the Earth, assuming that it perfectly absorbs all emission falling on it and has no atmosphere. The Earth has an albedo of 0.3, meaning that 30% of the solar radiation that hits the planet gets scattered back into space without absorption. The effect of albedo on temperature can be approximated by assuming that the energy absorbed is multiplied by 0.7, but that the planet still radiates as a black body (the latter by definition of effective temperature, which is what we are calculating). This approximation reduces the temperature by a factor of 0.71/4, giving . The above temperature is Earth's as seen from space, not ground temperature but an average over all emitting bodies of Earth from surface to high altitude. Because of the greenhouse effect, the Earth's actual average surface temperature is about , which is higher than the effective temperature, and even higher than the temperature that a black body would have. In the above discussion, we have assumed that the whole surface of the earth is at one temperature. Another interesting question is to ask what the temperature of a blackbody surface on the earth would be assuming that it reaches equilibrium with the sunlight falling on it. This of course depends on the angle of the sun on the surface and on how much air the sunlight has gone through. When the sun is at the zenith and the surface is horizontal, the irradiance can be as high as 1120 W/m2. The Stefan–Boltzmann law then gives a temperature of T=\left(\frac{1120\text{ W/m}^2}\sigma\right)^{1/4}\approx 375\text{ K} or . (Above the atmosphere, the result is even higher: .) We can think of the earth's surface as "trying" to reach equilibrium temperature during the day, but being cooled by the atmosphere, and "trying" to reach equilibrium with starlight and possibly moonlight at night, but being warmed by the atmosphere. == Origination ==
Origination
Thermodynamic derivation of the energy density The fact that the energy density of the box containing radiation is proportional to T^{4} can be derived using thermodynamics. == Decomposition in terms of photons ==
Decomposition in terms of photons
The Stefan–Boltzmann law can be expressed as M^{\circ} = \sigma\, T^4 = N_\mathrm{phot} \, \langle E_\mathrm{phot} \rangle where the flux of photons, N_\mathrm{phot}, is given by N_\mathrm{phot} = \pi \int_0^\infty \frac{B_\nu}{h\nu}\,\mathrm{d}\nu N_\mathrm{phot} = \left({ 1.5205\times10^{15}} \; \textrm{photons}{\cdot}\textrm{s}^{-1}{\cdot}\textrm{m}^{-2}{\cdot}\mathrm{K}^{-3}\right)\cdot T^3 and the average energy per photon,\langle E_\textrm{phot}\rangle, is given by \langle E_\textrm{phot}\rangle = \frac{\pi^4}{30\,\zeta(3)} k\,T= \left({3.7294 \times 10^{-23}} \mathrm{J}{\cdot}\mathrm{K}^{-1}\right) \cdot T\,. Marr and Wilkin (2012) recommend that students be taught about \langle E_\textrm{phot}\rangle instead of being taught Wien's displacement law, and that the above decomposition be taught when the Stefan–Boltzmann law is taught. == See also ==
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