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Pine tar

Pine tar is a form of wood tar produced by the high temperature carbonization of pine wood in anoxic conditions. The wood is rapidly decomposed by applying heat and pressure in a closed container; the primary resulting products are charcoal and pine tar.

History
Nordic Iron Age Based on chemical analysis of organic residues, there are strong indications that cone-shaped pits discovered north of Uppsala, Sweden, have been used for pine tar production. Three of the pits have been radiocarbon dated. The oldest dates back to 540–380 BCE, which would make it the world's oldest known, still existing tar production facility. The other dates from 230–390 CE. Classical antiquity In his encyclopedic work Natural History () the Roman naturalist and author Pliny the Elder (23/24–79 CE) describes how, in Europe, tar is produced through the destructive distillation of pine wood. The wood was chopped into small pieces (billets) and heated in a furnace. The tar was used "for coating ships and for many other useful purposes." 17th century Finland Pine tar has long been used in Nordic nations as a preservative for wood which may be exposed to harsh conditions, including outdoor furniture and ship decking and rigging. Tar demand surged in the 17th century as European nations began constructing naval and merchant fleets that required tar and pitch for ship waterproofing and caulking. In Finland, then a part of Sweden, large-scale tar production began in the early 17th century. By the late 17th century, tar was Sweden's third most valuable export commodity. North American colonies Tar and pitch for maritime use was in such demand that it became an important export for the American colonies, which had extensive pine forests. North Carolinians became known as "Tar Heels." 18th–19th century Sweden In present-day Sweden, large-scale tar production started around 1700. Swedish pine tar was often called "Stockholm tar" since, for many years, a single company held a royal monopoly on its export out of Stockholm, Sweden. It was also known as "Archangel Tar". Stockholm tar became synonymous with top-quality tar. Tar production peaked around the mid-1850s and gradually declined thereafter, largely due to new shipbuilding materials reducing the need for tar as a waterproofing agent, and to the decreasing use of hemp rope as sailing ships were phased out. ==Chemical composition==
Chemical composition
32 compounds have been identified in pine tar derived from Pinus nigra , accounting for 95.5% of the total composition. Their respective percentages are: • Methyl dehydroabietate: 22.44% • Dehydroabietic acid: 14.59% • Retene (7-isopropyl-1-methylphenanthrene): 10.08% • Isopimaral: 6.18% • Pimaral: 4.71% • Abietic acid: 4.23% • Pimaric acid: 3.59% • 18-Norabieta-8,11,13-triene: 3.50% • 2,3,5-Trimethylphenanthrene: 1.72% • Levoglucosan: 1.44% These compounds primarily consist of resin acids and their derivatives, along with phenanthrene-based hydrocarbons. Such constituents contribute to pine tar's characteristic properties, including its antiseptic and preservative qualities. == Uses ==
Uses
Pine tar was used as a preservative on the bottoms of traditional Nordic-style skis until modern synthetic materials replaced wood in their construction. It also helped waxes adhere, which aided such skis’ grip and glide. Pine tar is widely used as a veterinary care product, particularly as an antiseptic and hoof care treatment for horses and cattle. Applying a smear of pine tar on the hens' wound acts as a natural germicidal/antibacterial agent that discourages continued attacks on the affected hen due to its foreign texture. Due to the high presence of phenol in the early manufacturing of pine tar, it was deemed carcinogenic. However, now much of the phenol has been removed. Pine tar was banned by the FDA along with many other ingredients categorized as over the counter drugs, due to a lack of evidence of safety and effectiveness for the specific uses named. However, clinical tests in Australia in 2017 demonstrated that the greatest risk comes from acute sensitivity for those with severe dermatological conditions, and if it comes in contact with the eyes. Pine tar is also used in veterinary medicine as an expectorant and an antiseptic in chronic skin conditions. ==In popular culture==
In popular culture
In the television series Ten Pound Poms, depicting immigration from Britain to Australia in the 1950's, a newly betrothed young British man uses pine tar to lighten the skin of his British fiancee's illegitimate mixed-race baby, so that he may pass off the baby as his own (series 2, episode 2). ==See also==
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