Natural asphalt () has been known of and used since antiquity, in
Mesopotamia,
Phoenicia,
Egypt,
Babylon,
Greece,
Carthage, and
Rome, to waterproof temple baths, reservoirs, aqueducts, tunnels, and moats, as a masonry mortar, to cork vessels, and surface roads. The Procession Street of Babylonian King
Nabopolassar, , leading north from his palace through the city's wall, was described as being constructed from burnt brick and asphalt. In 1829 natural
Seyssel asphalt mixed with 7% aggregate, to create an asphat-mastic surface, was used for a footpath at Pont Morand,
Lyon, France, the technique spreading to Paris in 1835, London, England, in 1836, and Philadelphia, United States, in 1838. In 1834, John Henry Cassell & Company of Poplar, London, a pitch and varnish supplier, obtained an English patent for a method to surface roads with a layer of tar, covered by a layer of macadam, and sealed with a layer of tar and sand, and marketed the surface "lava stone for paving and waterproofing"; soon after being contracted to surface the approach road to
Vauxhall bridge, and a road in
Millwall, London. In 1837,
R. T. Claridge obtained a similar English patent (GB patent 1837 #7849), substituting Seyssel asphalt as the binder, having seen it employed in France and Belgium; he would subsequently form the Claridge's Patent Asphalte Company, in 1838. , England A
macadam road surfaced with asphalt was constructed in 1852, between Paris and
Perpignan, France, using Swiss Val de Travers rock asphalt (natural asphalt-covered limestone aggregate). Civil engineer, surveyor, and an English county highway board member,
Edgar Purnell Hooley, created a process and engine to combine petroleum
bitumen with
macadam aggregates (gravel,
Portland cement, crushed rocks, and
blast furnace slag) in a steam heated mixer, at , and through a heated reservoir, conduits, and meshes, create a machine and material that can be applied to form a road surface. He filed a UK patent, in 1902, for his improvement. Hooley founding a UK company to market the technology, where the term
tar macadam, shortened to
tarmac, was coined, after the name of his company ''
Tar Macadam (Purnell Hooley's Patent) Syndicate Limited'', derived from the combination of tar and macadam gravel composite mixtures. == Mixture formulations == , creating a
composite pavement. Mixing of asphalt and aggregate is accomplished in one of several ways: ; Hot-mix asphalt concrete (commonly abbreviated as HMA): This is produced by heating the bitumen binder to decrease its
viscosity and drying the aggregate to remove moisture from it prior to mixing. Mixing is generally performed with the aggregate at about for virgin asphalt and for polymer modified asphalt, and the asphalt cement at . Paving and compaction must be performed while the asphalt is sufficiently hot. In many locales paving is restricted to summer months because in winter the base will cool the asphalt too quickly before it can be packed to the required density. HMA is the form of asphalt concrete most commonly used on high traffic
pavements such as those on major
highways,
racetracks and
airfields. It is also used as an environmental liner for landfills, reservoirs, and fish hatchery ponds. ; Warm-mix asphalt concrete (commonly abbreviated as WMA): This is produced by adding either
zeolites,
waxes, asphalt
emulsions or sometimes water to the asphalt binder prior to mixing. This allows significantly lower mixing and laying temperatures and results in lower consumption of
fossil fuels, thus releasing less
carbon dioxide,
aerosols and vapors. This improves working conditions, and lowers laying-temperature, which leads to more rapid availability of the surface for use, which is important for construction sites with critical time schedules. The usage of these additives in hot-mixed asphalt (above) may afford easier compaction and allow cold-weather paving or longer hauls. Use of warm mix is rapidly expanding. A survey of US asphalt producers found that nearly 25% of asphalt produced in 2012 was warm mix, a 416% increase since 2009. Cleaner road pavements can be potentially developed by combining WMA and material recycling. Warm Mix Asphalt (WMA) technology has environmental, production, and economic benefits. ; Cold-mix asphalt concrete: This is produced by emulsifying the bitumen in water with an
emulsifying agent before mixing with the aggregate. While in its emulsified state, the bitumen is less viscous and the mixture is easy to work and compact. The emulsion will break after enough water evaporates and the cold mix will, ideally, take on the properties of an HMA pavement. Cold mix is commonly used as a patching material and on lesser-trafficked service roads. ; Cut-back asphalt concrete: Is a form of
cold mix asphalt produced by dissolving the binder in
kerosene or another lighter fraction of
petroleum before mixing with the aggregate. While in its dissolved state, the bitumen is less viscous and the mix is easy to work and compact. After the mix is laid down the lighter fraction evaporates. Because of concerns with pollution from the
volatile organic compounds in the lighter fraction, cut-back asphalt has been largely replaced by asphalt emulsion. ; Mastic asphalt concrete, or sheet asphalt: This is produced by heating hard grade blown bitumen (i.e., partly oxidised) in a green cooker (mixer) until it has become a viscous liquid after which the aggregate mix is then added. The bitumen aggregate mixture is cooked (matured) for around 6–8 hours and once it is ready, the mastic asphalt mixer is transported to the work site where experienced layers empty the mixer and either machine or hand lay the mastic asphalt contents on to the road. Mastic asphalt concrete is generally laid to a thickness of around for footpath and road applications and around for flooring or roof applications. ; High-modulus asphalt concrete, sometimes referred to by the French-language acronym EMÉ (enrobé à module élevé): This uses a very hard bituminous formulation (penetration 10/20), sometimes modified, in proportions close to 6% by weight of the aggregates, as well as a high proportion of mineral powder (between 8–10%) to create an asphalt concrete layer with a high modulus of elasticity (of the order of 13000MPa). This makes it possible to reduce the thickness of the base layer up to 25% (depending on the temperature) in relation to conventional bitumen, while offering as very high fatigue strengths. High-modulus asphalt layers are used both in reinforcement operations and in the construction of new reinforcements for medium and heavy traffic. In base layers, they tend to exhibit a greater capacity of absorbing tensions and, in general, better fatigue resistance. In addition to the asphalt and aggregate, additives, such as
polymers, and
antistripping agents may be added to improve the properties of the final product. Areas paved with asphalt concrete—especially
airport aprons—have been called "the tarmac" at times, despite not being constructed using the
tarmacadam process. A variety of specialty asphalt concrete mixtures have been developed to meet specific needs, such as
stone-matrix asphalt, which is designed to ensure a strong wearing surface, or
porous asphalt pavements, which are permeable and allow water to drain through the pavement for controlling storm water. == Roadway performance characteristics ==