The unit processes involved in wastewater treatment include physical processes such as settlement or flotation and biological processes such as oxidation or anaerobic treatment. Some wastewaters require specialized treatment methods. At the simplest level, treatment of most wastewaters is carried out through separation of
solids from
liquids, usually by
sedimentation. By progressively converting dissolved material into solids, usually a biological floc or
biofilm, which is then settled out or separated, an effluent stream of increasing purity is produced.
Phase separation s are widely used for wastewater treatment. Phase separation transfers impurities into a
non-aqueous phase. Phase separation may occur at intermediate points in a treatment sequence to remove solids generated during
oxidation or polishing. Grease and oil may be recovered for fuel or
saponification. Solids often require
dewatering of sludge in a
wastewater treatment plant. Disposal options for dried solids vary with the type and concentration of impurities removed from water.
Sedimentation Solids such as
stones, grit, and sand may be removed from wastewater by
gravity when
density differences are sufficient to overcome dispersion by
turbulence. This is typically achieved using a grit channel designed to produce an optimum flow rate that allows grit to settle and other less-dense solids to be carried forward to the next treatment stage.
Gravity separation of solids is the primary treatment of
sewage, where the unit process is called "primary settling tanks" or "primary sedimentation tanks". It is also widely used for the treatment of other types of wastewater. Solids that are denser than water will accumulate at the bottom of quiescent
settling basins. More complex
clarifiers also have skimmers to simultaneously remove floating grease such as soap scum and solids such as feathers, wood chips, or
condoms. Containers like the
API oil-water separator are specifically designed to separate non-polar liquids.
Biological and chemical processes Oxidation Oxidation lowers the
biochemical oxygen demand of wastewater, and may detoxify some impurities.
Secondary treatment converts organic compounds into
carbon dioxide,
water, and
biosolids through oxidation and reduction reactions. Chemical oxidation is widely used for disinfection.
Biochemical oxidation (secondary treatment) Chemical oxidation Advanced oxidation processes are used to remove some
persistent organic pollutants and concentrations remaining after biochemical oxidation.
Anaerobic treatment Anaerobic wastewater treatment processes are also widely applied in the treatment of industrial wastewaters and biological sludge. Anaerobic treatment occurs in a rectangular or cylindrical reactor, containing a porous packing medium lined with biofilm or biomass, that filters the solids out of the wastewater that enters it. The biomass interacts with the wastewater's organic compounds and turns them into methane and then into carbon dioxide.
Upflow anaerobic sludge blanket digestion (UASB) submerges the packing medium, whereas downflow digestion may or may not. There is a variant of the UASB process called
expanded granular sludge bed digestion (EGSB) that moves the wastewater faster through the reactor. Anaerobic processes produce biogas from 70-90%, and microbial biomass from 5-15%, of the wastewater's organic matter; the remainder does not decompose. Anaerobic processes are cheaper to set up; require less energy, nutrients and land; create methane gas; and produce only a fifth to a third of the solid byproducts that aerobic processes do. Anaerobic processes, however, do not do well at removing pathogens, nitrogen and phosphorus. They also produce foul odours, require post-treatment and can be slow to start up. Many compounds, like
ammonia and
sulfide, can disrupt anaerobic processes.
Polishing Polishing refers to treatments made in further advanced treatment steps after the above methods (also called "fourth stage" treatment). These treatments may also be used independently for some industrial wastewater.
Chemical reduction or
pH adjustment minimizes chemical reactivity of wastewater following chemical oxidation.
Carbon filtering removes remaining contaminants and impurities by chemical adsorption onto
activated carbon. Filtration through sand (calcium carbonate) or fabric filters is the most common method used in municipal wastewater treatment. ==See also==