Early yellowcake compositions were not well characterized. As late as 1970, the
U.S. Bureau of Mines defined yellowcake simply as the final precipitate from the milling process, presumed to be
ammonium diuranate or
sodium diuranate. The actual composition varies significantly based on leaching agents and precipitation conditions. Identified compounds in yellowcake include
uranyl hydroxide,
uranyl sulfate,
sodium para-uranate, and
uranyl peroxide, along with various
uranium oxides. Contemporary yellowcake typically consists of 70% to 90%
triuranium octoxide (U3O8) by weight, with other oxides such as
uranium dioxide (UO2) and
uranium trioxide (UO3) also present. Yellowcake production occurs in all countries where uranium ore is mined.
Further processing Yellowcake serves as feedstock for nuclear fuel production. For use in reactors, it is smelted into purified UO2 for fabrication into
fuel rods, particularly for
pressurized heavy-water reactors and other systems utilizing natural
unenriched uranium. For enrichment purposes, uranium oxides are converted to
uranium hexafluoride gas (UF6) through fluorination. This gas then undergoes
isotope separation via
gaseous diffusion or
gas centrifuge processes. These methods can produce
low-enriched uranium (up to 20% U-235) suitable for most commercial power reactors. Additional processing yields
highly enriched uranium (20% or more U-235) for naval propulsion systems. Further refinement can produce
weapons-grade uranium (typically >90% U-235) for
nuclear weapons. == Radioactivity and safety ==