es, (2)
particulate pollution, (3)
ozone-depleting gases, (4)
acid rain, (5)
ground-level ozone, (6)
nitrogen oxides|alt=Schematic showing (1) CO2 and CH4 from heating, driving and livestock causing warming (2) PM pollution from driving (3) CFCs from buildings depleting ozone, causing UV to come through (4) SO2 from combustion causing acid rain and (5) ground-level ozone from nitrous oxides and (6) nitrous oxides from car exhausts. Air pollutants can be tiny solid or liquid particles dispersed in the air (called
aerosols), or gases. Pollutants are classified as primary or secondary. Primary pollutants are produced directly by a source and remain in the same chemical form after they have been emitted into the atmosphere. Examples include
carbon monoxide gas from car exhausts and sulfur dioxide from factories. Secondary pollutants are not emitted directly. Rather, they form in the air when primary pollutants react with each other or with other parts of the atmosphere.
Ground-level ozone is one example of a secondary pollutant. Some pollutants may be both primary and secondary — both are emitted directly and formed from other primary pollutants.
Ammonia Ammonia () is emitted mainly by overuse of synthetic nitrogen
fertilizers on farmland, and from
manure and urine from
livestock. At typical concentrations in the air, it is not harmful to health directly. However, ammonia can react with other pollutants in the air to form
ammonium sulfate or
nitrate salts, contributing to particulate matter pollution. Furthermore, when ammonia is
deposited onto the soil, it can harm ecosystems via
eutrophication.
Carbon dioxide Carbon dioxide () is mainly emitted by the burning of fossil fuels. is sometimes called an air pollutant, because it is the main
greenhouse gas responsible for
climate change. Although the
World Health Organization recognizes as a climate pollutant, it does not include the gas in its
Air Quality Guidelines or set recommended targets for it. This question of terminology has practical consequences, for example, in determining whether the U.S.
Clean Air Act (which is designed to improve air quality) is deemed to regulate emissions. The
Inflation Reduction Act of 2022 amended the Clean Air Act to define from fossil fuel burning explicitly as an air pollutant.
Carbon monoxide Carbon monoxide (CO) is a colorless, odorless, and toxic gas. It is a product of
combustion of fuel such as natural gas, coal, or wood. In the past, emissions from vehicles were the main source of CO, but modern vehicles do not emit much of it. Now, wildfires and
bonfires are the main source of outdoors CO. Indoors, CO is a larger problem and mainly comes from cooking and heating. In poorly ventilated spaces, CO can
accumulate to dangerous levels, and exposure may cause people to lose consciousness and die. When CO is destroyed in the atmosphere, it can raise levels of and .
Ground-level ozone Ground-level ozone () is mostly created when and volatile organic compounds mix in the presence of sunlight. It can also form from carbon monoxide or methane. Due to the influence of temperature and sunlight on this reaction, high ozone levels are most common on hot summer afternoons. It is the main gas in
photochemical smog. can be harmful to human health, but also to some materials, forests, plants, and crops. Smog is a particular problem in big cities where it cannot easily be transported away by wind (e.g. cities built in valleys surrounded by mountains). When ground-level ozone is produced, it can linger in the air for days or weeks, and therefore be transported far from where it was first formed. and can form acid rain, can form into a
haze, and can cause
nutrient pollution in water. is a reddish-brown toxic gas with a strong odor, whereas is odorless and colorless.
Particulate matter Particulate matter (PM), also known as particle pollution, includes all airborne substances that are not gases. It is a mix of microscopic solid particles or droplets suspended in a gas. Particulate matter can contain a large variety of materials and chemical compounds including toxic substances, which can vary strongly in size. Smaller particles pose more risk to health, as they can reach the bloodstream.
Sea spray, wildfires, volcanoes and
dust storms are the main natural sources of PM. Meanwhile, human sources include the burning of biomass and fossil fuels, as well as road emissions and dust resuspension. Human PM is usually finer than natural PM. Most particulate matter is formed in the atmosphere from precursor gases. For instance,
sulfate comes from ,
nitrate from , and
ammonium is formed from ammonia.
Soot on the other hand is directly emitted from combustion, and consists of black carbon and organic compounds.
Particulate matter can have a cooling effect locally on the climate, as it reflects sunlight away from Earth's surface.
Sulfur dioxide Sulfur dioxide (SO2), an acidic and corrosive gas, is produced mostly by burning
crude oil and coal. These fossil fuels often contain sulfur compounds, and their combustion generates sulfur dioxide. In Europe and North America, SO2 is mostly found in areas with significant shipping and industry, as road traffic fuels are regulated. Smaller amounts of SO2 are released from
smelting and volcanoes. Further oxidation of SO2, mostly taking place in cloud droplets, forms
sulfuric acid (H2SO4), which is one of the components of
acid rain. polluting the air.
Volatile organic compounds Volatile organic compounds (VOCs) are a class of carbon-based chemicals that exist as gases at room temperature, found both indoors and outdoors. They can cause
photochemical smog and form aerosols impacting climate. The group includes methane,
acetone, and
toluene. Some can
cause cancer, such as
butadiene and
benzene, with benzene being released from
cigarette smoking. Methane is a greenhouse gas and the second-largest driver of
global warming. Other VOCs contribute to climate warming because they help form ground-level ozone, a greenhouse gas.
Other pollutants Some
heavy metals can be bad for health. For instance,
lead exposure can lead to
learning disabilities in children. In the atmosphere, heavy metals can exist in different states, such as particles or gases.
One of the forms of
chromium can cause
cancer.
Mercury is harmful both as an element and in an organic compound. In the atmosphere, it comes mostly from
cement production, coal burning, and incinerators.
Persistent organic pollutants (POPs) are organic compounds that are resistant to
environmental degradation. They persist in the environment, are
capable of long-range transmission,
bioaccumulate in humans and animals, and
biomagnify in food chains. The
Stockholm Convention on Persistent Organic Pollutants identified
pesticides and other POPs of concern. These include
dioxins and
furans which are created by waste combustion. POPs are usually either semi-volatile (gaseous only at higher temperatures) or non-volatile (emitted as particles). The harmful effects of the pesticide
DDT, a POP, were popularized by Rachel Carson's 1962 book
Silent Spring.
PFASs and
polycyclic aromatic hydrocarbons (PAHs) are other examples of POPs.
Chlorofluorocarbons (CFCs) are a group of compounds which harm the
ozone layer. They were widely used in
aerosol sprays, refrigerants, and
fire suppression. Due to their chemical stability, CFCs persist in the atmosphere and eventually reach the
stratosphere (the upper atmosphere). There, they break down under the impact of
UV light, which releases
chlorine. This in turn reacts with ozone, destroying it. As the ozone layer blocks harmful UV radiation from reaching the Earth's surface, its depletion leads to health risks such as
skin ageing and
skin cancer. == Exposure ==