On 24 April 1645 in Paris, Anne was married, without much enthusiasm, to
Edward, Count Palatine of Simmern, a landless and penniless German nobleman who was nineteen years old - nine years her junior. She became
Countess Palatine of Simmern, and was known in German as
Pfalzgräfin Anne and in English as
Anne, Princess Palatine. With Edward, she had three daughters: •
Louise Marie • 23 July 1647 – 11 March 1679 • married
Charles Theodore, Prince of Salm •
Anne Henriette Julie • 13 March 1648 – 23 February 1723 • married
Henri Jules, Prince of Condé •
Bénédicte Henriette • 14 March 1652 – 12 August 1730 • married
John Frederick, Duke of Brunswick-Lüneburg • From her, such prominent figures as the doomed King
Louis XVI are descended. According to the Italian historian
Signor G. B. Intra, Anne "held one of the most brilliant
salons during the early years of the reign of Louis XIV." Her second daughter's marriage to Henri Jules de Bourbon, ''duc d'Enghien
, came to restore her position; Henri Jules, son of le Grand Condé'', was a cousin of
Louis XIV and one of the highest-ranking males at court. Her sister, Queen
Ludwika Maria of Poland, had designated Anne Henriette as her heir and was committed to supporting Enghien for the Polish throne. Princess Anne managed to marry her youngest daughter, Bénédicte (sometimes Benedicta or Benedictine), to the
Duke of Brunswick and Hanover. The Princess Palatine was a confidante of
Philippe d'Orléans, and helped arrange his second marriage (to her husband's nineteen-year-old niece
Liselotte, Princess Palatine). ==Later life and religion==