Dishwasher detergent Dishwashers are designed to work using specially formulated
dishwasher detergent. Over time, many regions have banned the use of
phosphates in detergent and phosphorus-based compounds. They were previously used because they have properties that aid in effective cleaning. The concern was the increase in
algal blooms in waterways caused by increasing phosphate levels (see
eutrophication). Seventeen US states have partial or full bans on the use of phosphates in dish detergent, and two US states (
Maryland and
New York) ban phosphates in commercial dishwashing. Detergent companies claimed it is not cost effective to make separate batches of detergent for the states with phosphate bans, and so most have voluntarily removed phosphates from all dishwasher detergents. In addition,
rinse aids have contained
nonylphenol and nonylphenol ethoxylates. These have been banned in the European Union by EU Directive 76/769/EEC. In some regions, depending on water hardness, a dishwasher might function better with the use of a
dishwasher salt.
Glassware Glassware washed by dishwashing machines can develop a white
haze on the surface over time. This may be caused by any or all of the below processes, of which only the first is reversible: ; Deposition of minerals: Calcium carbonate (
limescale) in hard water can deposit and build up on surfaces when water dries. The deposits can be dissolved by vinegar or another acid. Dishwashers often include
ion exchange device to remove calcium and magnesium ions and replace them with sodium. The resultant sodium salts are water-soluble and don't tend to build up. ; Silicate filming, etching, and accelerated crack corrosion: This film starts as an iridescence or "oil-film" effect on glassware, and progresses into a "milky" or "cloudy" appearance (which is not a deposit) that cannot be polished off or removed like limescale. It is formed because the detergent is strongly alkaline (basic) and
glass dissolves slowly in alkaline aqueous solution. It becomes less soluble in the presence of silicates in the water (added as anti-metal-corrosion agents in the dishwasher detergent). Since the cloudy appearance is due to nonuniform glass dissolution, it is (somewhat paradoxically)
less marked if dissolution is higher, i.e. if a silicate-free detergent is used; also, in certain cases, the etching will primarily be seen in areas that have microscopic surface cracks as a result of the items' manufacturing. Limitation of this undesirable reaction is possible by controlling water hardness, detergent load and temperature. The type of glass is an important factor in determining if this effect is a problem. Some dishwashers can reduce this etching effect by automatically dispensing the correct amount of detergent throughout the wash cycle based on the level of water hardness programmed. ; Dissolution of lead: Lead in
lead crystal can be converted into a soluble form by the high temperatures and strong alkali detergents of dishwashers, which could endanger the health of subsequent users.
Other materials Other materials besides glass are also harmed by the strong detergents, strong agitation, and high temperatures of dishwashers, especially on a hot wash cycle when temperatures can reach . Aluminium, brass, and copper items will discolor, and light aluminum containers will mark other items they knock into. Nonstick pan coatings will deteriorate. Glossy, gold-colored, and hand-painted items will be dulled or fade. Fragile items and sharp edges will be dulled or damaged from colliding with other items or thermal stress. Sterling silver and pewter will oxidize and discolour from the heat and from contact with metals lower on the
galvanic series such as stainless steel. Pewter has a low melting point and may warp in some dishwashers. Glued items, such as hollow-handle knives or wooden
cutting boards, will melt or soften in a dishwasher; high temperatures and moisture damage wood. High temperatures damage many plastics, especially in the bottom rack close to an exposed
heating element (many newer dishwashers have a concealed heating element away from the bottom rack entirely). Squeezing plastic items into small spaces may cause the plastic to distort in shape.
Cast iron cookware is normally seasoned with oil or grease and heat, which causes the oil or grease to be absorbed into the pores of the cookware, thereby giving a smooth relatively non-stick cooking surface which is stripped off by the combination of alkali based detergent and hot water in a dishwasher. Knives and other cooking tools that are made of
carbon steel, semi-stainless steels like D2, or specialized, highly hardened cutlery steels like ZDP189 corrode in the extended moisture bath of dishwashers, compared to briefer baths of hand washing. Cookware is made of
austenitic stainless steels, which are more stable. Items contaminated by chemicals such as wax, cigarette ash, poisons, mineral oils, wet paints, oiled tools, furnace filters, etc. can contaminate a dishwasher, since the surfaces inside small water passages cannot be wiped clean as surfaces are in hand-washing, so contaminants remain to affect future loads. Objects contaminated by
solvents may explode in a dishwasher.
Environmental comparison Dishwashers use less water, and therefore less fuel to heat the water, than hand washing, except for small quantities washed in wash bowls without running water. Hand-washing techniques vary by individual. According to a peer-reviewed study in 2003, hand washing and drying of an amount of dishes equivalent to a fully loaded automatic dishwasher (no
cookware or bakeware) could use between of water and between 0.1 and 8 kWh of energy, while the numbers for energy-efficient automatic dishwashers were and 1 to 2 kWh, respectively. The study concluded that fully loaded dishwashers use less energy, water, and detergent than the average European hand-washer. For the automatic dishwasher results, the dishes were not rinsed before being loaded. The study does not address costs associated with the manufacture and disposal of dishwashers, the cost of possible accelerated wear of dishes from the chemical harshness of dishwasher detergent, the comparison for cleaning cookware, or the value of labour saved; hand washers needed between 65 and 106 minutes. Several points of criticism on this study have been raised. For example,
kilowatt hours of electricity were compared against energy used for heating hot water without taking into account possible inefficiencies. Also, inefficient handwashings were compared against optimal usage of a fully loaded dishwasher without manual pre-rinsing that can take up to of water. A 2009 study showed that the microwave and the dishwasher were both more effective ways to clean
domestic sponges than handwashing. ==Adoption==