In 1880, Planck became a
Privatdozent (unsalaried lecturer) at Munich, waiting until he was offered an academic position. Although he was initially ignored by the academic community, he furthered his work on the field of
heat theory and discovered one after another the same
thermodynamical formalism as
Gibbs without realizing it. Clausius' ideas on
entropy occupied a central role in his work. In April 1885, Planck was appointed associate professor of Theoretical Physics at the
University of Kiel. Further work on entropy and its treatment, especially as applied in
physical chemistry, followed. He published his
Treatise on Thermodynamics in 1897. He proposed a thermodynamic basis for
Svante Arrhenius's theory of
electrolytic dissociation. In 1889, Planck was named the successor to Kirchhoff's position at the
University of Berlin – presumably thanks to Helmholtz's intercession – and by 1892 became Full Professor. In 1907, he was offered
Ludwig Boltzmann's position in
Vienna, but turned it down to stay in Berlin. During 1909, as a University of Berlin professor, he was invited to become the
Ernest Kempton Adams Lecturer in Theoretical Physics at
Columbia University in New York City. A series of his lectures were translated and co-published by Columbia University professor
A. P. Wills. He retired from Berlin on 10 January 1926, and was succeeded by
Erwin Schrödinger.
Professor at Berlin University As a professor at the University of Berlin, Planck joined the local Physical Society. He later wrote about this time: "In those days I was essentially the only theoretical physicist there, whence things were not so easy for me, because I started mentioning entropy, but this was not quite fashionable, since it was regarded as a mathematical spook". Thanks to his initiative, the various local Physical Societies of Germany merged in 1898 to form the German Physical Society (
Deutsche Physikalische Gesellschaft, DPG); from 1905 to 1909 Planck was the president. : "Max Planck, discoverer of the elementary quantum of action
h, taught in this building from 1889 to 1928." Planck started a six-semester course of lectures on theoretical physics, "dry, somewhat impersonal" according to
Lise Meitner, "using no notes, never making mistakes, never faltering; the best lecturer I ever heard" according to an English participant,
James R. Partington, who continues: "There were always many standing around the room. As the lecture-room was well heated and rather close, some of the listeners would from time to time drop to the floor, but this did not disturb the lecture." Planck did not establish an actual "school"; the number of his graduate students was only about 20, among them: • 1897
Max Abraham (1875–1922) • 1903
Max von Laue (1879–1960) • 1904
Moritz Schlick (1882–1936) • 1906
Walther Meissner (1882–1974) • 1907
Fritz Reiche (1883–1960) • 1912
Walter Schottky (1886–1976) • 1914
Walther Bothe (1891–1957)
Entropy Thermodynamics, also known as the "mechanical theory of heat" at the end of the 19th century, had emerged at the beginning of this century from an attempt to understand the functioning of steam engines and to improve their efficiency. In the 1840s, several researchers independently discovered and formulated the law of conservation of energy, which is now also known as the
first law of thermodynamics. In 1850,
Rudolf Clausius formulated the so-called
second law of thermodynamics, which states that a voluntary (or spontaneous) transfer of energy is only possible from a warmer to a colder body, but not vice versa. In England at this time
William Thomson came to the same conclusion. Clausius generalized his formulation further and further and came up with a new formulation in 1865. To this end, he introduced the concept of
entropy, which he defined as a measure of the reversible supply of heat in relation to the absolute temperature. The new formulation of the second law, which is still valid today, was: "Entropy can be created, but never destroyed". Clausius, whose work Planck read as a young student during his stay in Berlin, successfully applied this new law of nature to mechanical, thermoelectric and chemical processes. In his thesis in 1879, Planck summarized Clausius' writings, pointing out contradictions and inaccuracies in their formulation and then clarifying them. In addition, he generalized the validity of the second law to all processes in nature; Clausius had limited its application to reversible processes and thermal processes. Furthermore, Planck dealt intensively with the new concept of entropy and emphasized that entropy is not only a property of a physical system, but at the same time a measure of the irreversibility of a process: If entropy is generated in a process, it is irreversible, since entropy cannot be destroyed according to the second law. In reversible processes, the entropy remains constant. He presented this fact in detail in 1887 in a series of treatises entitled "On the Principle of the Increase of Entropy". In his study of the concept of entropy, Planck did not follow the molecular, probabilistic interpretation that prevailed at the time, as these do not provide absolute proof of universality. Instead, he pursued a phenomenological approach and was also skeptical of atomism. Even though he later abandoned this attitude in the course of his work on the law of radiation, his early work impressively shows the possibilities of thermodynamics in solving concrete physicochemical problems. Planck's understanding of entropy included the realization that the maximum of entropy corresponds to the equilibrium state. The accompanying conclusion that knowledge of the Entropy allows all laws of thermodynamic equilibrium states to be derived corresponds to the modern understanding of such states. Planck therefore chose equilibrium processes as his research focus and, based on his habilitation thesis, researched the coexistence of aggregate states and the equilibrium of gas reactions, for example. This work on the frontier of chemical thermodynamics also received great attention due to the rapidly expanding chemical work at that time. Independently of Planck,
Josiah Willard Gibbs had also discovered almost all the knowledge Planck gained about the properties of physicochemical equilibria and published them from 1876 onwards. Planck was unaware of these essays, and they did not appear in German until 1892. However, both scientists approached the topic in different ways, while Planck dealt with irreversible processes, Gibbs looked at equilibria. This approach was finally able to prevail because of its simplicity, but Planck's approach is attributed the greater universality.
Electrolytes and Solutions In addition to his research on entropy, Planck dedicated the first decade of his scientific career to the study of electrical processes in solutions. During this period, he succeeded in theoretically deriving the relationship between the conductivity and dilution of a solution, thereby establishing the foundations of modern electrolyte theory. He was also able to provide a theoretical derivation for the conditions governing the changes in freezing and boiling points of dilute solutions, phenomena which had been empirically discovered by François-Marie Raoult and Jacobus Henricus van ’t Hoff in 1886.
Black-body radiation In 1894, Planck turned his attention to the problem of
black-body radiation. The problem had been stated by Kirchhoff in 1859: "how does the intensity of the electromagnetic radiation emitted by a
black body (a perfect absorber, also known as a cavity radiator) depend on the
frequency of the radiation (i.e., the color of the light) and the temperature of the body?". The question had been explored experimentally, but no theoretical treatment had agreed with the experimentally observed evidence.
Wilhelm Wien proposed
Wien's law, which correctly predicted the behaviour at high frequencies, but failed at low frequencies. The
Rayleigh–Jeans law, another approach to the problem, agreed with experimental results at low frequencies, but created what was later known as the "
ultraviolet catastrophe" at high frequencies, as predicted by
classical physics. However, contrary to many textbooks, this was not a motivation for Planck. Planck's first proposed solution to the problem in 1899 followed from what he called the "principle of elementary disorder", which allowed him to derive Wien's law from a number of assumptions about the
entropy of an ideal oscillator, creating what was referred to as the Wien–Planck law. Soon, however, it was found that experimental evidence did not confirm the new law at all, to Planck's frustration. He revised his approach and now derived the first version of the famous
Planck black-body radiation law, which described clearly the experimentally observed black-body spectrum. It was first proposed in a meeting of the DPG on 19 October 1900 and published in 1901. (This first derivation did not include energy quantisation, and did not use
statistical mechanics, to which he held an aversion.) In November 1900 Planck revised this first version, now relying on
Boltzmann's statistical interpretation of the
second law of thermodynamics as a way of gaining a more fundamental understanding of the principles behind his radiation law. Planck was deeply suspicious of the philosophical and physical implications of such an interpretation of Boltzmann's approach; thus his recourse to them was, as he later put it, "an act of despair ... I was ready to sacrifice any of my previous convictions about physics". In recognition of Planck's fundamental contribution to a new branch of physics, he was awarded the Nobel Prize in Physics for 1918; (he received the award in 1919). Subsequently, Planck tried to grasp the meaning of energy quanta, but to no avail. "My unavailing attempts to somehow reintegrate the action quantum into classical theory extended over several years and caused me much trouble." Even several years later, other physicists such as
Rayleigh,
Jeans, and
Lorentz set the Planck constant to zero in order to align with classical physics, but Planck knew well that this constant had a precise nonzero value. "I am unable to understand Jeans' stubbornness – he is an example of a theoretician as should never be existing, the same as
Hegel was for philosophy. So much the worse for the facts if they don't fit."
Max Born wrote about Planck: "He was, by nature, a conservative mind; he had nothing of the revolutionary and was thoroughly skeptical about speculations. Yet his belief in the compelling force of logical reasoning from facts was so strong that he did not flinch from announcing the most revolutionary idea which ever has shaken physics."
Einstein and the theory of relativity In 1905,
Albert Einstein published
three papers in the journal
Annalen der Physik. Planck was among the few who immediately recognized the significance of the
special theory of relativity. Thanks to his influence, this theory was soon widely accepted in Germany. Planck also contributed considerably to extend the special theory of relativity. For example, he recast the theory in terms of classical
action. Einstein's hypothesis of light
quanta (
photons), based on
Heinrich Hertz's 1887 discovery (and further investigation by
Philipp Lenard) of the
photoelectric effect, was initially rejected by Planck. He was unwilling to discard completely
Maxwell's theory of
electrodynamics. "The theory of light would be thrown back not by decades, but by centuries, into the age when
Christiaan Huygens dared to fight against the mighty emission theory of
Isaac Newton ..." In 1910, Einstein pointed out the anomalous behavior of
specific heat at low temperatures as another example of a phenomenon which defies explanation by classical physics. Planck and
Walther Nernst, seeking to clarify the increasing number of contradictions, organized the First
Solvay Conference (Brussels 1911). At this meeting Einstein was able to convince Planck. Meanwhile, Planck had been appointed dean of Berlin University, whereby it was possible for him to call Einstein to Berlin and establish a new professorship for him (1914). Soon the two scientists became close friends and met frequently to play music together.
First World War At the onset of the
First World War Planck endorsed the general excitement of the public, writing that, "Besides much that is horrible, there is also much that is unexpectedly great and beautiful: the smooth solution of the most difficult domestic political problems by the unification of all parties (and) ... the extolling of everything good and noble." Planck also signed the infamous "
Manifesto of the 93 intellectuals", a pamphlet of polemic war propaganda (while Einstein retained a strictly pacifistic attitude which almost led to his imprisonment, only being spared thanks to his
Swiss citizenship). In 1915, when Italy was still a neutral power, Planck voted successfully for a scientific paper from Italy, which received a prize from the
Prussian Academy of Sciences, where Planck was one of four permanent presidents.
Post-war and the Weimar Republic In the turbulent post-war years, Planck, now the highest authority of German physics, issued the slogan "persevere and continue working" to his colleagues. In October 1920, he and
Fritz Haber established the
Notgemeinschaft der Deutschen Wissenschaft, aimed at providing financial support for scientific research. A considerable portion of the money the organization would distribute was raised abroad. Planck held leading positions at Berlin University, the Prussian Academy of Sciences, the German Physical Society, and the
Kaiser Wilhelm Society (which became the
Max Planck Society in 1948). During this time economic conditions in Germany were such that he was hardly able to conduct research. During the interwar period, Planck became a member of the
German People's Party, the party of Nobel Peace Prize laureate
Gustav Stresemann, which aspired to liberal aims for domestic policy and rather revisionistic aims for politics around the world. Planck disagreed with the introduction of
universal suffrage and later expressed the view that the Nazi dictatorship resulted from "the ascent of the rule of the crowds."
Quantum mechanics ,
Einstein, Planck,
Millikan, and
Laue at a dinner given by Laue in Berlin on 11 November 1931. At the end of the 1920s,
Niels Bohr,
Werner Heisenberg, and
Wolfgang Pauli had worked out the
Copenhagen interpretation of quantum mechanics, but it was rejected by Planck, and by Schrödinger, Laue, and Einstein as well. Planck expected that
wave mechanics would soon render quantum theoryhis own childunnecessary. This was not to be the case, however. Further work only served to underscore the enduring central importance of quantum theory, even against his and Einstein's philosophical revulsions. Here Planck experienced the truth of his own earlier observation from his struggle with the older views during his younger years: "A new scientific truth does not triumph by convincing its opponents and making them see the light, but rather because its opponents eventually die, and a new generation grows up that is familiar with it." The quote, while often cited, had multiple counter examples by Planck's own time. It took only 10 years for 75% of British scientists to generally accept
Charles Darwin's ideas from
On the Origin of Species and science historian
I. Bernard Cohen noted that, to the contrary, Planck's own ideas were generally accepted by his peers.
Plate tectonics also took only a decade to be adopted by geologists evidenced by its use in textbooks. K. Brad Wray's research into the history of scientific ideas showed that older scientists are only marginally less inclined to accept new conceptualizations.
Nazi dictatorship and the Second World War When the Nazis came to power in 1933, Planck was 74 years old. He witnessed many Jewish friends and colleagues expelled from their positions and humiliated, and hundreds of scientists emigrate from
Nazi Germany. He again tried to "persevere and continue working" and asked scientists who were considering emigration to remain in Germany. Nevertheless, he helped his nephew, the economist
Hermann Kranold, to emigrate to
London after his arrest. He hoped the crisis would abate soon and the political situation would improve.
Otto Hahn asked Planck to gather well-known German professors in order to issue a public proclamation against the treatment of Jewish professors, but Planck replied, "If you are able to gather today 30 such gentlemen, then tomorrow 150 others will come and speak against it, because they are eager to take over the positions of the others." Under Planck's leadership, the
Kaiser Wilhelm Society (KWG) avoided open conflict with the Nazi regime, except concerning the Jewish Fritz Haber. In May 1933, Planck requested and received an interview with the recently appointed Chancellor of Germany
Adolf Hitler to discuss the issue, telling him that the "forced emigration of Jews would kill German science and Jews could be good Germans", to which the chancellor replied "but we don't have anything against the Jews, only against communists". Planck was therefore unsuccessful, since this reply "took from him every basis for further negotiation", as to Hitler "the Jews are all Communists, and these are my enemies." In the following year, 1934, Haber died in exile. One year later, Planck, having been the president of the KWG since 1930, organized in a somewhat provocative style an official commemorative meeting for Haber. He also succeeded in secretly enabling a number of Jewish scientists to continue working in institutes of the KWG for several years. In 1936, his term as president of the KWG ended, and the Nazi government pressured him to refrain from seeking another term. As the political climate in Germany gradually became more hostile,
Johannes Stark, prominent exponent of the
Deutsche Physik ("German Physics", also called "Aryan Physics") attacked Planck,
Arnold Sommerfeld, and Heisenberg for continuing to teach the theories of Einstein, calling them "white Jews". The "Hauptamt Wissenschaft" (Nazi government office for science) started an investigation of Planck's ancestry, claiming that he was "1/16 Jewish", but Planck denied it. In 1938, Planck celebrated his 80th birthday. The DPG held a celebration, during which the Max-Planck medal (founded as the highest medal by the DPG in 1928) was awarded to French physicist
Louis de Broglie. At the end of 1938, the Prussian Academy lost its remaining independence and was taken over by Nazis, as part of their process of
Gleichschaltung. Planck protested by resigning his presidency. He continued to travel frequently, giving numerous public talks, such as his talk on Religion and Science and, five years later, he was sufficiently fit to climb 3,000-metre peaks in the
Alps. During the
Second World War, the increasing number of Allied bombing missions against Berlin forced Planck and his wife to temporarily leave the city and live in the countryside. In 1942, he wrote: "In me an ardent desire has grown to persevere this crisis and live long enough to be able to witness the turning point, the beginning of a new rise." In February 1944, his home in Berlin was completely destroyed by an air raid, annihilating all his scientific records and correspondence. His rural retreat was threatened by the rapid advance of the Allied armies from both sides. In 1944, Planck's son
Erwin was arrested by the
Gestapo following the attempted assassination of Hitler in the . He was tried and sentenced to death by the
People's Court in October 1944. Erwin was hanged at Berlin's
Plötzensee Prison in January 1945. The death of his son destroyed much of Planck's will to live. == Personal life and death ==