Hexamine is prepared by the reaction of
formaldehyde and
ammonia. In an acidic environment hexamine is converted to toxic formaldehyde, where the main hazard for
toxicity is by
ingestion. As with
trioxane, hexamine has an almost unlimited shelf life if stored properly, in a sealed dry container. However, the heat given off cannot be easily adjusted, so water can be boiled, but cooking requiring
simmering is more difficult. Tablets are a powerful stove fuel (30.0 MJ/kg), but are sensitive to wind and dampness. Esbit's Safety Data Sheet states combustion can create
formaldehyde,
ammonia,
nitrogen oxide,
hydrogen cyanide and ingestion may cause
nausea,
vomiting, gastrointestinal disturbances, and
kidney damage. When burned, the chemical oxidation of the fuel yields noxious fumes, which requires cooking foods in a container, such as a pot or pan, with a tight fitting lid. Burned tablets leave a sticky dark
residue on the bottom of pots. If tablets are stored or used under damp conditions they can break up while burning and shed burning fragments, though this claim is hard to verify or reproduce. As hexamine is a precursor for the simplest synthesis of the chemical explosive
RDX, its possession is tightly regulated in the
United Kingdom. == See also ==