The second line of development pursued by the Manhattan Project used plutonium. Although small amounts of plutonium exist in nature, the best way to obtain large quantities is via a reactor. Natural uranium is bombarded by neutrons and
transmuted into
uranium-239, which rapidly decays, first into
neptunium-239 and then into
plutonium-239.
X-10 Graphite Reactor In March 1943, DuPont began construction of a plutonium plant on a site at Oak Ridge. Intended as a pilot plant for the larger production facilities at Hanford, it included the air-cooled
X-10 Graphite Reactor, a chemical separation plant, and support facilities. Because of the subsequent decision to construct water-cooled reactors at Hanford, only the chemical separation plant operated as a true pilot. The X-10 Graphite Reactor consisted of a huge block of graphite, per side, weighing around , surrounded by of high-density concrete as a radiation shield. The X-10 Graphite Reactor went critical on 4 November 1943 with about of uranium. A week later the load was increased to , raising its power generation to 500 kW, and by the end of the month the first 500 mg of plutonium was created. Gradual modifications raised the power to 4,000 kW in July 1944. X-10 operated as a production plant until January 1945, when it was turned over to research.
Hanford reactors Although an air-cooled design was chosen for the reactor at Oak Ridge to facilitate rapid construction, this was impractical for the much larger production reactors. Initial designs by the Metallurgical Laboratory and DuPont used helium for cooling, before they determined that a water-cooled reactor was simpler, cheaper and quicker to build. The design did not become available until 4 October 1943; in the meantime, Matthias concentrated on improving the Hanford Site by erecting accommodations, improving the roads, building a railway switch line, and upgrading the electricity, water and telephone lines. site, June 1944|alt=An aerial view of the Hanford B-Reactor site from June 1944. At center is the reactor building. Small trucks dot the landscape and give a sense of scale. Two large water towers loom above the plant. As at Oak Ridge, the most difficulty was encountered while canning the uranium slugs, which commenced at Hanford in March 1944. They were
pickled to remove dirt and impurities, dipped in molten bronze, tin, and
aluminum-silicon alloy, canned using hydraulic presses, and then capped using
arc welding under an argon atmosphere. Finally, they were tested to detect holes or faulty welds. Disappointingly, most canned slugs initially failed the tests, resulting in an output of only a handful per day. But steady progress was made and by June 1944 production increased to the point where it appeared that enough canned slugs was available to start
Reactor B on schedule in August 1944. Work began on Reactor B, the first of six planned 250 MW reactors, on 10 October 1943. The reactor complexes were given letter designations A through F, with B, D and F sites developed first, as this maximized the distance between the reactors. They were the only ones constructed during the Manhattan Project. Some of steel, of concrete, 50,000 concrete blocks and 71,000 concrete bricks were used to construct the high building. Construction of the reactor itself commenced in February 1944. Watched by Compton, Matthias, DuPont's
Crawford Greenewalt,
Leona Woods and Fermi, who inserted the first slug, the reactor was powered up beginning on 13 September 1944. Over the next few days, 838 tubes were loaded and the reactor went critical. Shortly after midnight on 27 September, the operators began to withdraw the
control rods to initiate production. At first all appeared well but around 03:00 the power level started to drop and by 06:30 the reactor had shut down completely. The cooling water was investigated to see if there was a leak or contamination. The next day the reactor started up again, only to shut down once more. Fermi contacted
Chien-Shiung Wu, who identified the cause of the problem as
neutron poisoning from
xenon-135, which has a
half-life of 9.2 hours. Fermi, Woods,
Donald J. Hughes and
John Archibald Wheeler then calculated the
nuclear cross section of xenon-135, which turned out to be 30,000 times that of uranium. DuPont engineer George Graves had deviated from the Metallurgical Laboratory's original design in which the reactor had 1,500 tubes arranged in a circle, and had added an additional 504 tubes to fill in the corners. The scientists had originally considered this overengineering a waste of time and money, but Fermi realized that by loading all 2,004 tubes, the reactor could reach the required power level and efficiently produce plutonium. Reactor D was started on 17 December 1944 and Reactor F on 25 February 1945.
Separation process Meanwhile, the chemists considered how plutonium could be separated from uranium when its chemical properties were not known. Working with the minute quantities of plutonium available at the Metallurgical Laboratory in 1942, a team under Charles M. Cooper developed a
lanthanum fluoride process which was chosen for the pilot separation plant. A second separation process, the
bismuth phosphate process, was subsequently developed by Seaborg and Stanly G. Thomson. Greenewalt favored the bismuth phosphate process due to the corrosive nature of lanthanum fluoride, and it was selected for the Hanford separation plants. Once X-10 began producing plutonium, the pilot separation plant was put to the test. The first batch was processed at 40% efficiency but over the next few months this was raised to 90%. Early plans called for the construction of two separation plants in each of the areas known as 200-West and 200-East. This was subsequently reduced to two, the T and U plants, in 200-West and one, the B plant, at 200-East. Each separation plant consisted of four buildings: a process cell building or "canyon" (known as 221), a concentration building (224), a purification building (231) and a magazine store (213). The canyons were each long and wide. Each consisted of forty cells. Work began on 221-T and 221-U in January 1944, with the former completed in September and the latter in December. The 221-B building followed in March 1945. Because of the high levels of radioactivity involved, work in the separation plants had to be conducted by remote control using closed-circuit television, something unheard of in 1943. Maintenance was carried out with the aid of an overhead crane and specially designed tools. The 224 buildings were smaller because they had less material to process, and it was less radioactive. The 224-T and 224-U buildings were completed on 8 October 1944, and 224-B followed on 10 February 1945. The purification methods that were eventually used in 231-W were still unknown when construction commenced on 8 April 1944, but the plant was complete and the methods were selected by the end of the year. On 5 February 1945, Matthias hand-delivered the first shipment of 80 g of 95%-pure plutonium nitrate to a Los Alamos courier in Los Angeles. This rendered it unsuitable for use in a gun-type weapon, for the plutonium-240 would start the chain reaction too soon, causing a
predetonation that would disperse the critical mass after a minimal amount of plutonium had fissioned (a
fizzle). A higher-velocity gun was suggested but found to be impractical. The possibility of separating the isotopes was also considered and rejected, as plutonium-240 is even harder to separate from plutonium-239 than uranium-235 from uranium-238, and attempting it "would postpone the weapon indefinitely". Work on an alternative method of bomb design, known as implosion, had begun earlier under the direction of the physicist
Seth Neddermeyer. Implosion used explosives to crush a subcritical sphere of fissile material into a smaller and denser form. The critical mass is assembled in much less time than with the gun method. When the fissile atoms are packed closer together, the rate of neutron capture increases, so it also makes more efficient use of fissionable material. Neddermeyer's 1943 and early 1944 investigations showed promise, but also made it clear that an implosion weapon was more complex than the gun-type design from both a theoretical and an engineering perspective. In September 1943,
John von Neumann, who had experience with
shaped charges, proposed using a spherical configuration instead of the cylindrical one that Neddermeyer was working on. An accelerated effort on the implosion design, codenamed
Fat Man, began in August 1944 when Oppenheimer implemented a sweeping reorganization of the Los Alamos laboratory to focus on implosion. Two new groups were created at Los Alamos to develop the implosion weapon, X (for explosives) Division headed by explosives expert
George Kistiakowsky and G (for gadget) Division under Robert Bacher. The new design featured
explosive lenses that focused the implosion into a spherical shape. Various explosives were tested before settling on
composition B and
baratol. The final design resembled a soccer ball, with 20 hexagonal and 12 pentagonal lenses, each weighing about . Getting the detonation just right required fast, reliable and safe electrical
detonators, of which there were two for each lens for reliability. To study the behavior of converging
shock waves, Robert Serber devised the
RaLa Experiment, which used the short-lived
radioisotope lanthanum-140, a potent source of
gamma radiation. The gamma ray source was placed in the center of a metal sphere surrounded by the explosive lenses, which in turn were inside in an
ionization chamber. This allowed the taking of an X-ray movie of the implosion. The lenses were designed primarily using this series of tests. In his history of the Los Alamos project,
David Hawkins wrote: "RaLa became the most important single experiment affecting the final bomb design". Within the explosives was an aluminum pusher, which provided a smooth transition from the relatively low-density explosive to the next layer, the
tamper of natural uranium. Its main job was to hold the critical mass together as long as possible, but it would also reflect neutrons into the core and some of its uranium would fission. To prevent predetonation by an external neutron, the tamper was coated in a thin layer of neutron-absorbing boron. was developed to start the chain reaction at precisely the right moment. This work on the chemistry and metallurgy of radioactive polonium was directed by
Charles Allen Thomas of the
Monsanto Company and became known as the
Dayton Project. Testing required up to 500
curies per month of polonium, which Monsanto was able to deliver. The whole assembly was encased in a
duralumin bomb casing to protect it from bullets and flak. at Los Alamos|alt=A shack surrounded by pine trees. There is snow on the ground. A man and a woman in white lab coats are pulling on a rope, which is attached to a small trolley on a wooden platform. On top of the trolley is a large cylindrical object. The ultimate task of the metallurgists was to determine how to cast plutonium into a sphere. The difficulties became apparent when attempts to measure the density of plutonium gave inconsistent results. At first contamination was suspected, but it was soon determined that there were multiple
allotropes of plutonium. The brittle α phase that exists at room temperature changes to the plastic β phase at higher temperatures. Attention then shifted to the even more malleable δ phase that normally exists in the 300 °C to 450 °C range. It was found that this was stable at room temperature when alloyed with aluminum, but aluminum emits neutrons when bombarded with
alpha particles, which would exacerbate the pre-ignition problem. The metallurgists then hit upon using a
plutonium-gallium alloy, which stabilized the δ phase and could be
hot pressed into the desired spherical shape. As plutonium was found to corrode readily, the sphere was coated with nickel. The work proved dangerous. By the end of the war, half the chemists and metallurgists had to be removed from work with plutonium when unacceptably high levels of the element was detected in their urine. A minor fire at Los Alamos in January 1945 led to a fear that a fire in the plutonium laboratory might contaminate the whole town, and Groves authorized the construction of a new facility for plutonium chemistry and metallurgy, which became known as the DP-site. The hemispheres for the first plutonium
pit (or core) were produced and delivered on 2 July 1945. Three more hemispheres followed on 23 July and were delivered three days later. In contrast to the plutonium Fat Man, the uranium gun-type Little Boy weapon was straightforward if not trivial to design. Overall responsibility for it was assigned to Parsons's Ordnance (O) Division, with the design, development, and technical work at Los Alamos consolidated under
Lieutenant Commander Francis Birch's group. The gun-type design now had to work with enriched uranium only, and this allowed the design to be greatly simplified. A high-velocity gun was no longer required, and a simpler weapon was substituted. Research into the Super was also pursued, although it was considered secondary to the development of a fission bomb. The effort was directed by Teller, who was its most enthusiastic proponent. The F-1 (Super) Group calculated that burning of liquid
deuterium would release the energy of , enough to devastate . In a final report on the Super in June 1946, Teller remained upbeat about the prospect of it being successfully developed, although that opinion was not universal.
Trinity Because of the complexity of an implosion-style weapon, it was decided that, despite the waste of fissile material, a full-scale
nuclear test was required. Oppenheimer codenamed it "Trinity". In March 1944, planning for the test was assigned to
Kenneth Bainbridge, who selected the
Alamogordo Bombing Range for the test site. A base camp was constructed with barracks, warehouses, workshops, an explosive magazine and a commissary. A pre-test explosion was conducted on 7 May 1945 to calibrate the instruments. A wooden test platform was erected from future Trinity Ground Zero and piled with about of high explosives spiked with
nuclear fission products. Groves did not relish the prospect of explaining to a Senate committee the loss of a billion dollars' worth of plutonium, so a cylindrical containment vessel codenamed "Jumbo" was constructed to recover the active material in the event of a failure. It was fabricated at great expense from of iron and steel. By the time it arrived, however, confidence in the implosion method was high enough, and the availability of plutonium was sufficient, that Oppenheimer decided not to use it. Instead, it was placed atop a steel tower from the weapon as a rough measure of the explosion's power. Jumbo survived, although its tower did not, adding credence to the belief that Jumbo would have successfully contained a
fizzled explosion. of the Manhattan Project was the first detonation of a
nuclear weapon. For the actual test, the weapon, nicknamed "the gadget", was hoisted to the top of a steel tower, as detonation at that height would give a better indication of how the weapon would behave when dropped from a bomber. Detonation in the air maximized the energy applied directly to the target and generated less
nuclear fallout. The gadget was assembled under the supervision of
Norris Bradbury at the nearby
McDonald Ranch House on 13 July, and precariously winched up the tower the following day. At 05:30 on 16 July 1945 the gadget exploded with an
energy equivalent of around 20 kilotons of TNT, leaving a crater of
trinitite (radioactive glass) in the desert wide. The shock wave was felt over away, and the
mushroom cloud reached in height. It was heard as far away as
El Paso, Texas, so Groves issued a cover story about an ammunition magazine explosion at Alamogordo Field involving gas shells. Oppenheimer later claimed that, while witnessing the explosion, he thought of a verse from the
Hindu holy book, the
Bhagavad Gita (XI,12): {{verse translation|italicsoff=true|lang=sa together with verse (XI,32), which he translated as "Now I am become Death, destroyer of worlds". The test was significantly more successful than had been anticipated; this was immediately cabled to Stimson, who was then at the
Potsdam Conference, and Groves hastily prepared a lengthier report sent via courier. President
Harry S. Truman was powerfully and positively affected by the news. Stimson noted in his diary that when he shared it with Churchill, Churchill remarked: "Now I know what happened to Truman yesterday. I couldn't understand it. When he got to the meeting after having read this report, he was a changed man. He told the Russians just where they got on and off and generally bossed the whole meeting." == Personnel ==