Macroscopic formulation in terms of displacement and magnetizing fields (in matter version)
The above equations are the microscopic version of Maxwell's equations, expressing the electric and the magnetic fields in terms of the (possibly atomic-level) charges and currents present. This is sometimes called the "general" form, but the macroscopic version below is equally general, the difference being one of bookkeeping. The microscopic version is sometimes called "Maxwell's equations in vacuum": this refers to the fact that the material medium is not built into the structure of the equations, but appears only in the charge and current terms. The microscopic version was introduced by Lorentz, who tried to use it to derive the macroscopic properties of bulk matter from its microscopic constituents. "Maxwell's macroscopic equations", also known as '''Maxwell's equations in matter''', are more similar to those that Maxwell introduced himself. In the macroscopic equations, the influence of bound charge and bound current is incorporated into the
displacement field and the
magnetizing field , while the equations depend only on the free charges and free currents . This reflects a splitting of the total electric charge
Q and current
I (and their densities and
J) into free and bound parts: \begin{align} Q &= Q_\text{f} + Q_\text{b} = \iiint_\Omega \left(\rho_\text{f} + \rho_\text{b} \right) \, \mathrm{d}V = \iiint_\Omega \rho \,\mathrm{d}V, \\ I &= I_\text{f} + I_\text{b} = \iint_\Sigma \left(\mathbf{J}_\text{f} + \mathbf{J}_\text{b} \right) \cdot \mathrm{d}\mathbf{S} = \iint_\Sigma \mathbf{J} \cdot \mathrm{d}\mathbf{S}. \end{align} The cost of this splitting is that the additional fields and need to be determined through phenomenological constituent equations relating these fields to the electric field and the magnetic field , together with the bound charge and current. See below for a detailed description of the differences between the microscopic equations, dealing with
total charge and current including material contributions, useful in air/vacuum; and the macroscopic equations, dealing with
free charge and current, practical to use within materials.
Bound charge and current When an electric field is applied to a
dielectric material its molecules respond by forming microscopic
electric dipoles – their
atomic nuclei move a tiny distance in the direction of the field, while their
electrons move a tiny distance in the opposite direction. This produces a
macroscopic bound charge in the material even though all of the charges involved are bound to individual molecules. For example, if every molecule responds the same, similar to that shown in the figure, these tiny movements of charge combine to produce a layer of positive
bound charge on one side of the material and a layer of negative charge on the other side. The bound charge is most conveniently described in terms of the
polarization of the material, its dipole moment per unit volume. If is uniform, a macroscopic separation of charge is produced only at the surfaces where enters and leaves the material. For non-uniform , a charge is also produced in the bulk. Somewhat similarly, in all materials the constituent atoms exhibit
magnetic moments that are intrinsically linked to the
angular momentum of the components of the atoms, most notably their
electrons. The
connection to angular momentum suggests the picture of an assembly of microscopic current loops. Outside the material, an assembly of such microscopic current loops is not different from a macroscopic current circulating around the material's surface, despite the fact that no individual charge is traveling a large distance. These
bound currents can be described using the
magnetization . The very complicated and granular bound charges and bound currents, therefore, can be represented on the macroscopic scale in terms of and , which average these charges and currents on a sufficiently large scale so as not to see the granularity of individual atoms, but also sufficiently small that they vary with location in the material. As such, ''Maxwell's macroscopic equations'' ignore many details on a fine scale that can be unimportant to understanding matters on a gross scale by calculating fields that are averaged over some suitable volume.
Auxiliary fields, polarization and magnetization The
definitions of the auxiliary fields are: \begin{align} \mathbf{D}(\mathbf{r}, t) &= \varepsilon_0 \mathbf{E}(\mathbf{r}, t) + \mathbf{P}(\mathbf{r}, t), \\ \mathbf{H}(\mathbf{r}, t) &= \frac{1}{\mu_0} \mathbf{B}(\mathbf{r}, t) - \mathbf{M}(\mathbf{r}, t), \end{align} where is the
polarization field and is the
magnetization field, which are defined in terms of microscopic bound charges and bound currents respectively. The macroscopic bound charge density and bound current density in terms of
polarization and
magnetization are then defined as \begin{align} \rho_\text{b} &= -\nabla\cdot\mathbf{P}, \\ \mathbf{J}_\text{b} &= \nabla\times\mathbf{M} + \frac{\partial\mathbf{P}}{\partial t}. \end{align} If we define the total, bound, and free charge and current density by \begin{align} \rho &= \rho_\text{b} + \rho_\text{f}, \\ \mathbf{J} &= \mathbf{J}_\text{b} + \mathbf{J}_\text{f}, \end{align} and use the defining relations above to eliminate , and , the "macroscopic" Maxwell's equations reproduce the "microscopic" equations.
Constitutive relations In order to apply 'Maxwell's macroscopic equations', it is necessary to specify the relations between
displacement field and the electric field , as well as the
magnetizing field and the magnetic field . Equivalently, we have to specify the dependence of the polarization (hence the bound charge) and the magnetization (hence the bound current) on the applied electric and magnetic field. The equations specifying this response are called
constitutive relations. For real-world materials, the constitutive relations are rarely simple, except approximately, and usually determined by experiment. See the main article on constitutive relations for a fuller description. For materials without polarization and magnetization, the constitutive relations are (by definition) • For isotropic materials, and are scalars, while for anisotropic materials (e.g. due to crystal structure) they are
tensors. • Materials are generally
dispersive, so and depend on the
frequency of any incident EM waves. Even more generally, in the case of non-linear materials (see for example
nonlinear optics), and are not necessarily proportional to , similarly or is not necessarily proportional to . In general and depend on both and , on location and time, and possibly other physical quantities. In applications one also has to describe how the free currents and charge density behave in terms of and possibly coupled to other physical quantities like pressure, and the mass, number density, and velocity of charge-carrying particles. E.g., the original equations given by Maxwell (see ''
History of Maxwell's equations'') included
Ohm's law in the form \mathbf{J}_\text{f} = \sigma \mathbf{E}. == Alternative formulations ==