The basic requirements for formation of
foam are an abundance of gas, water, a surfactant, and energy. The steam wand of an espresso machine supplies energy, in the form of heat, and gas, in the form of steam. The other two components, water and surfactants, are naturally occurring ingredients of milk. Varying the balance of these factors affects the size of bubbles, the foam dissipation rate, and the volume of foam. Microfoam may be represented simply as a
metastable liquid-gas
colloid of milk and air, consisting of gaseous bubbles suspended in the liquid milk. In reality, the suspension is more complex because milk consists of two different colloids itself - an
emulsion of fat and a
sol of protein. In fact, these two colloids are what enable milk to form such a mechanically strong foam which does not collapse under its own weight. The interaction between fat and air creates a structure of microscopic bubbles strong enough to support itself, and even be submerged (i.e. suspended within the liquid milk). This adsorption causes destabilization of the bubbles, because the fat molecules are
amphiphilic (i.e. they have
polar and non-polar ends), competing with protein molecules which are more conducive to bubbles. The denaturation of milk fat occurs around , so milk at higher temperatures is not significantly affected by this problem. This value is higher for
raw milk - around . The dip in foamability occurs due to fat globules consisting of both solid and liquid phases at this temperature. Solid fat crystals in a globule may penetrate the film which separates them from the surrounding air, causing spreading of the membrane material which is then adsorbed onto air bubbles. If milk is heated above , it becomes
scalded and its texture is compromised. Microfoam cannot exist in overheated milk due to the missing
tertiary structure in the protein. When milk is scalded, the suspended protein
casein becomes
denatured and cannot maintain the intermolecular bonds necessary for microfoam. The stability of milk foam, measured by the
half-life of its volume, is also greatly influenced by temperature. A louder screaming sound may be heard if the steam orifice becomes blocked or the machine cannot pump enough air. == References ==