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Oil shale in Estonia

There are two kinds of oil shale in Estonia, both of which are sedimentary rocks laid down during the Ordovician geologic period. Graptolitic argillite is the larger oil shale resource, but, because its organic matter content is relatively low, it is not used industrially. The other is kukersite, which has been mined for more than a hundred years. Kukersite deposits in Estonia account for 1% of global oil shale deposits.

Resource
Graptolitic argillite (FeS2) from the Türisalu cliff, an outcrop of the Türisalu Formation of the Ordovician graptolitic argillite deposits in northern Estonia, indicating thickness in meters Estonian graptolitic argillite (also known as dictyonema argillite, dictyonema oil shale, dictyonema shale or alum shale) is a marine-type of black shale, belonging to the marinite-type of oil shales. Although the name dictyonema argillite is widely used instead of graptolitic argillite, it is now considered a misnomer as the graptolite fossils in the rock, earlier considered dictyonemids, were reclassified during the 1980s as members of the genus Rhabdinopora. Graptolitic argillite was formed some 480 million years ago during the Early Ordovician under a marine environment. Resources of graptolitic argillite in Estonia have been estimated at 60–70 billion tonnes. Its organic content ranges from 10 to 20% and its sulfur content from 2 to 4%. Correspondingly, its calorific value is only 5–8 megajoules per kilogram (MJ/kg; 1,200–1,900 kcal/kg) and its Fischer Assay oil yield is 3–5%. It was named kuckers by the Baltic German geologist Carl Friedrich Schmidt in the mid-19th century, and kukersite by the Russian paleobotanist Mikhail Zalessky in 1916. The name reflects the German name for Kukruse Manor, where oil shale samples were obtained. Kukersite deposits in Estonia are the world's second highest-grade oil shale deposits after the Australian torbanite. and its Fischer Assay oil yield is 30 to 47%. The principal organic component of kukersite is telalginite, which originated from the fossil green alga Gloeocapsomorpha prisca, deposited in a shallow marine basin. and together with the Leningrad deposit (an extension of the Estonian) form the Baltic Oil Shale Basin. The Estonian deposit, which covers about , is used industrially. It consists of 23 exploration and mining fields. The Tapa deposit is not accounted as a reserve due to its lower calorific value, which makes its extraction economically inexpedient. The total kukersite resources in Estonia are estimated to be about 4.8 billion tonnes, including 1.3 billion tonnes of economically proven and probable reserves. Up to 650 million tonnes of economically proven and probable reserves are designated as recoverable. ==History==
History
Early history It is often reported that 18th-century naturalist and explorer Johann Anton Güldenstädt had mentioned a discovery of a "burning rock" near Jõhvi in 1725, but his published travel notes mention neither oil shale nor Estonia. It is also often reported that the earliest documented record of oil shale in Estonia, authored by the Baltic German publicist and linguist August Wilhelm Hupel, dates to 1777. However, this is based on a misinterpretation of the German word Steinöhl (meaning: stone oil), which was used by Hupel but which most likely did not mean oil shale in the context of his publication. The first scientific research into the rock's oil yield, using samples from the village of Vanamõisa of the Kohala Manor, was published by Georgi at the Russian Academy of Sciences in 1791. In 1838 he made a thorough experiment to distil oil from the Vanamõisa oil shale deposit. During the 1850s, large-scale works were undertaken in Estonia to transform excessively wet land into land suitable for agriculture; this included the digging of drainage ditches. In the process, previously unknown layers of oil shale were discovered in several locations. In the years 1850–1857, the territory of Estonia was explored by the Baltic German geologist Carl Friedrich Schmidt who studied these findings of oil shale. Russian chemist Aleksandr Shamarin, who at the end of the 1860s had studied the composition and properties of oil shale originating from the Kukruse area, concluded it made sense to use oil shale for the production of gas and as a solid fuel. However, he considered shale oil production unprofitable. For example, in the 1870s, Robert von Toll, landlord of the Kukruse Manor, started to use oil shale as a fuel for the manor's distillery. There were failed attempts to use graptolitic argillite as fertilizer in the 19th century. In the beginning of the 20th century, geologist and engineer Carl August von Mickwitz studied self-ignition of graptolitic argillite near Paldiski. At the University of Tartu oil shale geology and chemistry analyses were conducted during the 19th century by Georg Paul Alexander Petzholdt, Alexander Gustav von Schrenk, and Carl Ernst Heinrich Schmidt, among others. These events marking the beginning of the Estonian oil shale industry In February 1918, the area surrounding the oil shale basin in northeast Estonia was occupied by German troops. During this occupation, mining activities were carried out at Pavandu by the German company Internationales Baukonsortium (), including sending oil shale to Germany for research and experimentation. This work used a retort constructed by Julius Pintsch AG, known as a Pintsch generator. In late 1918, German forces left Estonia, by which time no more than a single trainload of oil shale had been mined and sent to Germany. Developments in interwar Estonia , 1937. Photo by Carl Sarap) , 1931) After Estonia gained independence, the state owned oil shale enterprise, Riigi Põlevkivitööstus (), was established as a department of the Ministry for Trade and Industry on 24 November 1918. The enterprise, later named Esimene Eesti Põlevkivitööstus (), was the predecessor of Viru Keemia Grupp, one of the current shale oil producers in Estonia. It took over the existing Pavandu open-pit mine, and opened new mines at Vanamõisa (1919), Kukruse (1920), and Käva (1924). Initially, oil shale was used primarily in the cement industry, but also for firing locomotive furnaces and as a household fuel. The first major industrial consumers of oil shale were cement factories in Kunda and Aseri. By 1925, all locomotives in Estonia were powered by oil shale. Shale oil production started in Estonia in 1921 when Riigi Põlevkivitööstus built 14 experimental oil shale processing retorts in Kohtla-Järve. These vertical retorts used the method developed by Julius Pintsch AG that would later evolve into the current Kiviter processing technology. The German-owned company Eesti Kiviõli (, , predecessor of Kiviõli Keemiatööstus), affiliated with G. Scheel & Co. and Mendelssohn & Co., was established in 1922. By the end of the 1930s, it had become the largest shale oil producer in Estonia. Around the company's mine and oil plant, the Kiviõli settlement (now town) was formed in the same way as the Küttejõu settlement (now district of Kiviõli) formed around the mine owned by Eesti Küttejõud. In 1924, the British investor-owned Estonian Oil Development Syndicate Ltd. (later Vanamõisa Oilfields Ltd.) purchased an open-pit mine in Vanamõisa and opened a shale oil extraction plant that was abandoned in 1931 due to technical problems. The Swedish–Norwegian consortium Eestimaa Õlikonsortsium (, ), controlled by Marcus Wallenberg, was founded in Sillamäe in 1926. New Consolidated Gold Fields Ltd. of the United Kingdom built a shale oil extraction plant at Kohtla-Nõmme in 1931. Since 1935, Estonian shale oil has been supplied to the German Kriegsmarine as a ship fuel. In 1938, 45% of Estonian shale oil was exported, accounting for 8% of Estonia's total exports. In 1937, the Geological Committee under the Ministry of Economic Affairs, and the Institute of Natural Resources, an independent academic institution, were established. A department of mining was established at Tallinn Technical University in 1938. Estonian oil shale industries conducted tests of oil shale samples from Australia, Bulgaria, Germany and South Africa. Developments in German-occupied Estonia Soon after the Soviet occupation in 1940, the entire oil shale industry was nationalised and subordinated to the Mining Office and later to the General Directorate of Mining and Fuel Industry of the Peoples' Commissariat for Light Industry. Germany invaded the Soviet Union in 1941 and the industry's infrastructure was largely destroyed by retreating Soviet forces. This entity was subordinated to Kontinentale Öl, a company that had exclusive rights to oil production in German-occupied territories. On 21 June 1943, Reichsführer Heinrich Himmler issued an order to send as many male Jews as possible to the oil shale mining. Baltische Öl consisted of five units (Kiviõli, Küttejõu, Kohtla-Järve, Sillamäe, and Kohtla), all of which were partially restored, previously existing industries. In addition, Baltische Öl started construction of a new mining and shale oil extraction complex in Ahtme, but it never became operational. Prisoners of war and forced labour made up about two-thirds of the work force in these units. Existing oil shale-fired power stations were also destroyed. Statistical Office of Estonia; Estonian Oil Shale Industry Yearbook 2019) Shale oil extraction, except the Kiviõli and Kohtla-Nõmme plants, was merged into the Kohtla-Järve shale oil combinate (, now Viru Keemia Grupp) under the General Directorate of Synthetic Liquid Fuel and Gas of the USSR (Glavgaztopprom). Both organisations were directed from Moscow. New mines were opened in Ahtme (1948), Jõhvi (No. 2, 1949), Sompa (1949), Tammiku (1951), and in the area between Käva and Sompa (No. 4, 1953). The Ubja mine was closed in 1959. The industry declined during the subsequent two decades. Demand for electric power generated from oil shale decreased following construction of nuclear power stations in the Russian SFSR, particularly the Leningrad Nuclear Power Station. The shale oil industry at Kohtla-Järve and Kiviõli was redeveloped. In 1945, the first tunnel kiln was restored, and by the end of the 1940s four tunnel kilns located in Kiviõli and Kohtla-Nõmme had been restored. German prisoners of war contributed most of the labour. Between 1946 and 1963, 13 Kiviter-type retorts were built in Kohtla-Järve and eight in Kiviõli. The first Galoter-type commercial-scale pilot retorts were built at Kiviõli in 1953 and 1963 with capacities of 200 and 500 tonnes of oil shale per day, respectively. The first of these retorts closed in 1963 and the second in 1981. The Narva Oil Plant, annexed to the Eesti Power Station and operating two Galoter-type 3,000-tonnes-per day retorts, was commissioned in 1980. In 1948 an oil shale gas plant in Kohtla-Järve became operational, and for several decades the oil shale gas was used as a substitute for natural gas in Saint Petersburg (then known as Leningrad) and in northern Estonian cities. It was the first time in history that synthetic gas from oil shale was used in households. To enable delivery of the gas, a pipeline from Kohtla-Järve to Saint Peterburg was built, followed by a pipeline from Kohtla-Järve to Tallinn. In 1962 and 1963, the conversion of oil shale gas into ammonium was tested; however, for industrial production, oil shale gas was replaced with natural gas. Although this gas had become uneconomical by 1958, production continued and was even expanded. After peaking in 1976 at , oil shale gas production ceased in 1987. In 1988 Moscow-based authorities planned a third oil shale-fired power station in Narva with a capacity of 2,500 MW, together with a new mine at Kuremäe. The plan, disclosed at the time of the Phosphorite War and the Singing Revolution, met with strong local opposition and was never implemented. Between 1946 and 1952, uranium compounds were extracted from locally mined graptolitic argillite at the Sillamäe Processing Plant (now: Silmet). More than 60 tonnes of uranium compounds (corresponding to 22.5 tonnes of elemental uranium) were produced. Preliminary research into oil shale-based chemical production began the same year, exploring the potential for the use of oil shale in bitumen, synthetic construction materials, detergents, synthetic leathers, synthetic fibres, plastics, paints, soaps, glues, and pesticides. Between 1959 and 1985, of mineral wool were produced from oil shale coke, a solid residue of oil shale. In 1968, a branch of the Skochinsky Institute of Mining was established in Kohtla-Järve, In 1995, state-owned shale oil producers in Kohtla-Järve and Kiviõli were merged into the single company named RAS Kiviter. In 1997, Kiviter was privatized and a year later it declared insolvency. Its factories in Kohtla-Järve and Kiviõli were sold separately and new oil producers – Viru Keemia Grupp and Kiviõli Keemiatööstus – emerged. The proposed deal with NRG Energy met a strong public and political opposition and was cancelled after NRG Energy failed the deadline to secure financing for the project. Consequently, the Government transferred its remained shares in Eesti Põlevkivi to a state-owned company Eesti Energia, a parent company of the Narva Power Stations, and Eesti Põlevkivi became a fully owned subsidiary of Eesti Energia. Oil shale production started to increase again in the beginning of the 21st century. In 2000, the open-pit mines at Viivikonna, Sirgala and Narva were merged into the single Narva open-pit mine. Since 2003, several new mines were opened: the Põhja-Kiviõli open-pit mine in 2003, the Ubja open-pit mine in 2005, and the Ojamaa underground mine in 2010. The exhausted Aidu open-pit mine was closed in 2012, followed a year later by the Viru underground mine. In 2004, two power units with circulating fluidised bed combustion boilers were put into operation at the Narva Power Stations. Construction of the Auvere Power Station, located next to the existing Eesti Power Station, began in 2012. In the end of 2012, the Ahtme Power Station was closed. In 2008, Eesti Energia established a joint venture, Enefit Outotec Technology, with the Finnish technology company Outotec. The venture sought to develop and commercialise a modified Galoter process–the Enefit process–that would enhance the existing technology by using circulating fluidised beds. In 2013, Enefit Outotec Technology opened an Enefit testing plant in Frankfurt. Kiviõli Keemiatööstus began to test two Galoter-type retorts in 2006. VKG Oil opened three new Galoter-type oil plants called Petroter correspondingly in December 2009, in October 2014, and in November 2015. In 2020, Eesti Energia announced a plan to build additional oil plant by 2023. At the same time, it cancelled a shale oil pre-refinery project developed jointly with Viru Keemia Grupp. In spring 2021, the government coalition of Estonian Reform Party and Estonian Centre Party put a political target in their coalition agreement to stop oil shale power generation by 2035 and using oil shale in the entire energy sector by 2040 at the latest. Shortly after, Eesti Energia announced it will stop burning oil shale for electricity generation by 2025 and burning oil shale gas by 2030. It will close older type shale oil plants by 2040 while in newer generation shale oil plants oil shale will be replaced with waste plastics. Estonia is negotiating with the European Commission to receive €340 million support from the Just Transition Fund to mitigate the impact of the oil shale industry transition. ==Economic impact==
Economic impact
The oil shale industry in Estonia is one of the most developed in the world. Estonia is the only country in the world that uses oil shale as its primary energy source. In 2018, oil shale accounted for 72% of Estonia's total domestic energy production and supplied 73% of Estonia's total primary energy. About 7,300 people (over 1% of the total workforce in Estonia) were employed in the oil shale industry. The state revenue from oil shale production was about €122 million. Mining in the Narva open-pit mine (2005) Estonia has adopted a national development plan that limits the annual mining of oil shale to 20 million tonnes. As of 2021, five oil shale mines are in operation; three are open-pit mines and two are underground mines. The mines are owned by four companies. Several mining companies have applied for permits for opening new mines. Historically, the ratio of underground mining to open-pit mining has been approximately even, but usable deposits close to the surface has become scarcer. The Estonia underground mine at Väike-Pungerja, operated by Enefit Power, a subsidiary of Eesti Energia, is the largest oil shale mine in the world. The other underground mine, operated by privately owned Viru Keemia Grupp, is located at Ojamaa. Both mines use the room and pillar mining method. The Narva open-pit mine is operated by Enefit Power, and the Põhja-Kiviõli open-pit mine is operated by privately owned Kiviõli Keemiatööstus. Both mines use highly selective extraction in three layers of seams. The third open-pit mine, operated by Kunda Nordic Tsement which belongs to German HeidelbergCement group, is located at Ubja. The share of oil shale in Estonia's electricity generation has decreased significantly over the last decade, and it is set to decrease even more due to the European Union's climate policy as well as the country's recognition of the environmental impact of oil shale-fired power stations and need to diversify the national energy balance. According to the International Energy Agency, Estonia should adopt the energy strategy in order to reduce the share of oil shale in the primary energy supply by improving the efficiency of shale-fired power stations and increasing the use of other energy sources such as renewable energy. Eesti Energia owns the largest oil shale-fuelled power stations (Narva Power Stations) in the world. The increased carbon price has made oil-shale electricity less competitive and will affect it even more in the future. In June 2021, Eesti Energia announced it will stop burning oil shale for electricity generation by 2025 and burning oil shale gas by 2030. The government coalition of Estonia has decided that Estonia will stop oil shale power generation by 2035 at the latest. Heat produced by co-generation at the Balti Power Station is used for district heating of Narva, the third largest city in Estonia with 58,700 inhabitants (2013). The co-generation plants in Kohtla-Järve, Sillamäe, and Kiviõli burn oil shale to produce electrical power and supply district heating to nearby towns. In addition to raw oil shale, the Kohtla-Järve Power Station uses oil shale gas, a by-product of shale oil production, for the same purposes. Shale oil extraction In 2008, Estonia was the second largest shale oil producer in the world after China. Production was 1.173 million tonnes of shale oil in 2019. About 99% of shale oil production was exported. The government coalition of Estonia has decided that Estonia will stop shale oil extraction by 2040 at the latest. Estonia aims for climate neutrality by 2050 and 100% renewable electricity by 2030. ==Environmental impact==
Environmental impact
heap in Kohtla-Järve (2005) Wastes and land usage The mining and processing of about one billion tonnes of oil shale in Estonia has created about 360-370 million tonnes of solid waste. Combustion ashes are the largest component (200 million tonnes), followed by mining waste (90 million tonnes) and spent shale (mainly semi-coke, 70–80 million tonnes). As a result of decades of mining activity, the topography of the oil shale region has changed; this includes a greater range of altitudes within the mined area. Former and current oil shale mines occupy about 1% of Estonia's territory. Semi-coke heaps near Kohtla-Järve and Kiviõli cover more than and ash heaps near Narva cover more than . These heaps protruding from the flat landscape are regarded as landmarks and as monuments to the area's industrial heritage. There is less biodiversity within the mined area; in particular, the reclaimed and reforested areas have less biodiversity than the areas which have undergone a natural succession. The release of mine water into the environment has changed the natural movement of surface water. The process of pumping water from the mines introduces oxygen via aeration, thereby oxidising the rock's pyrite. Pyrite contains sulfur, and one consequence of its oxidation is the introduction of significant amounts of sulphates into mine water. Consequently, the transportation water becomes highly alkaline. The total volume of formed alkaline water is . Another source of water pollution is aqueous leachates from oil shale ash and spent shale. About of toxic leachate from the Narva ash heaps inflows annually to the Narva River and further to the Gulf of Finland. The industry emits into the atmosphere annually about 200,000 tonnes of fly-ash, including heavy metals, carbonates, alkaline oxides (mainly calcium oxide (CaO)), and harmful organic substances (including PAHs). About 30% of the fly-ash is CaO, a portion of which is neutralised by atmospheric . Another source of air pollution is the dust that arises during deposition of oil shale ash and semi-coke. The most hazardous particles are those with a diameter of less than ; these particles are associated with an increase in cardiovascular mortality and premature deaths in Estonia. The combustion of oil shale releases more into the atmosphere than any other primary fuel. Generating 1 MWh of electricity in modern oil shale-fired boilers creates 0.9–1 tonnes of . In 2017, oil-shale related greenhouse gas emissions in Estonia accounted for 12.9 million tonnes or 69.1% of total energy-related emissions. Of the all energy-related emissions, heat and power generation accounted for 76%. According to the OECD, emissions in Estonia could be reduced by two-thirds if oil shale would be used for production of lighter oil products, instead of burning to generate electricity. Mitigation Various efforts have reduced the industry's environmental impact. Fluidised bed combustion generates fewer , , and fly-ash emissions, including PAHs, than the earlier technologies that burned pulverised oil shale. In 2010–2013, a €38 million project was implemented for the environmentally safe closing of of semi-coke and ash heaps. In Kiviõli, a semi-coke heap, the highest artificial hill in the Baltic countries, was converted into a ski centre. The former Aidu open-pit mine was converted into a rowing course. A part of the former Sirgala open pit mine has been used as a military training area. The study also shows that the rate of lung cancer among men in the region was higher compared to the Estonian average. ==See also==
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