Indirectly ionizing radiation is electrically neutral and does not interact strongly with matter, therefore the bulk of the ionization effects are due to secondary ionization.
Photon radiation Even though photons are electrically neutral, they can ionize
atoms indirectly through the
photoelectric effect and the
Compton effect. Either of those interactions cause the ejection of an electron from an atom at relativistic speeds, turning that electron into a (secondary) beta particle that will ionize other atoms. Since most of the ionized atoms are due to the
secondary beta particles, photons are indirectly ionizing radiation. Radiated photons are called
gamma rays if they are produced by a
nuclear reaction,
subatomic particle decay, or
radioactive decay within the nucleus. They are called
x-rays if produced outside the nucleus. The generic term "photon" is used to describe both. X-rays normally have a lower energy than gamma rays, and an older convention was to define the boundary as a wavelength of 10−11 m (or a photon energy of 100 keV). That threshold was driven by historic limitations of older X-ray tubes and low awareness of
isomeric transitions. Modern technologies and discoveries have shown an overlap between X-ray and gamma energies. In many fields they are functionally identical, differing for terrestrial studies only in origin of the radiation. In astronomy, however, where radiation origin often cannot be reliably determined, the old energy division has been preserved, with X-rays defined as being between about 120 eV and 120 keV, and gamma rays as being of any energy above 100 to 120 keV, regardless of source. Most astronomical "
gamma-rays" are known
not to originate from radioactivity but, rather, result from processes like those that produce astronomical X-rays, except driven by much more energetic electrons. Photoelectric absorption is the dominant mechanism in organic materials for photon energies below 100 keV, typical of classical X-ray tube originated
X-rays. At energies beyond 100 keV, photons ionize matter increasingly through the
Compton effect, and then indirectly through
pair production at energies beyond 5 MeV. The accompanying interaction diagram shows two Compton scatterings happening sequentially. In every scattering event, the gamma ray transfers energy to an electron, and it continues on its path in a different direction and with reduced energy.
Definition boundary for lower-energy photons The lowest ionization energy of any element is 3.89 eV, for
caesium. However, US Federal Communications Commission material defines ionizing radiation as that with a
photon energy greater than 10 eV (equivalent to a far
ultraviolet wavelength of 124
nanometers). Roughly, this corresponds to both the first
ionization energy of oxygen, and the ionization energy of hydrogen, both about 14 eV. In some
Environmental Protection Agency references, the ionization of a typical water molecule at an energy of 33 eV is referenced as the appropriate biological threshold for ionizing radiation: this value represents the so-called
W-value, the colloquial name for the
ICRU's
mean energy expended in a gas per ion pair formed, which combines ionization energy plus the energy lost to other processes such as
excitation. At 38 nanometers wavelength for
electromagnetic radiation, 33 eV is close to the energy at the conventional 10 nm wavelength transition between extreme ultraviolet and X-ray radiation, which occurs at about 125 eV. Thus, X-ray radiation is always ionizing, but only extreme-ultraviolet radiation can be considered ionizing under all definitions.
Neutrons Neutrons have a neutral electrical charge often misunderstood as zero electrical charge and thus often do not
directly cause ionization in a single step or interaction with matter. However, fast neutrons will interact with the protons in hydrogen via
linear energy transfer, energy that a particle transfers to the material it is moving through. This mechanism scatters the nuclei of the materials in the target area, causing direct ionization of the hydrogen atoms. When neutrons strike the hydrogen nuclei, proton radiation (fast protons) results. These protons are themselves ionizing because they are of high energy, are charged, and interact with electrons. Neutrons that strike other nuclei besides hydrogen, transfer less energy to the other particle if linear energy transfer does occur. But, for many nuclei struck by neutrons,
inelastic scattering occurs. Whether elastic or inelastic scatter occurs is dependent on the speed of the neutron, whether
fast or
thermal or somewhere in between. It is also dependent on the nuclei it strikes and its
neutron cross section. In inelastic scattering, neutrons are readily absorbed in a type of
nuclear reaction called
neutron capture and attributes to the
neutron activation of the nucleus. Neutron interactions with most types of matter in this manner usually produce
radioactive nuclei.
Oxygen-16, for example, undergoes neutron activation, rapidly decays by a proton emission forming
nitrogen-16, which decays to oxygen-16. The short-lived nitrogen-16 decay emits a powerful beta ray. This process can be written as: O (n,p) N (fast neutron capture possible with >11 MeV neutron) N → O + β (Decay t = 7.13 s) This high-energy β further interacts rapidly with other nuclei, emitting high-energy γ via
Bremsstrahlung While not a favorable reaction, the O (n,p) N reaction is a major source of X-rays emitted from the cooling water of a
pressurized water reactor and contributes enormously to the radiation generated by a water-cooled
nuclear reactor while operating. For the best shielding of neutrons, hydrocarbons that have an abundance of
hydrogen are used. In
fissile materials, secondary neutrons may produce
nuclear chain reactions, causing a larger amount of ionization from the
daughter products of fission. Outside the nucleus, free neutrons are unstable and have a mean lifetime of 14 minutes, 42 seconds. Free neutrons decay by emission of an electron and an electron antineutrino to become a proton, a process known as
beta decay: In the adjacent diagram, a neutron collides with a proton of the target material, and then becomes a fast recoil proton that ionizes in turn. At the end of its path, the neutron is captured by a nucleus in an (n,γ)-reaction that leads to the emission of a
neutron capture photon. Such photons always have enough energy to qualify as ionizing radiation. == Physical effects ==