. One of the main tasks a hydrogeologist typically performs is the prediction of future behavior of an aquifer system, based on analysis of past and present observations. Some hypothetical, but characteristic questions asked would be: • Can the aquifer support another
subdivision? • Will the
river dry up if the farmer doubles his
irrigation? • Did the chemicals from the
dry cleaning facility travel through the aquifer to my well and make me sick? • Will the plume of effluent leaving my neighbor's septic system flow to my drinking
water well? Most of these questions can be addressed through simulation of the hydrologic system (using numerical models or analytic equations). Accurate simulation of the aquifer system requires knowledge of the aquifer properties and boundary conditions. Therefore, a common task of the hydrogeologist is determining aquifer properties using
aquifer tests. In order to further characterize
aquifers and
aquitards some primary and derived physical properties are introduced below. Aquifers are broadly classified as being either confined or unconfined (
water table aquifers); the type of aquifer affects what properties control the flow of water in that medium (e.g., the release of water from storage for confined aquifers is related to the
storativity, while it is related to the specific yield for unconfined aquifers).
Aquifers An
aquifer is a water-bearing layer of rock, or of unconsolidated sediments, that will yield water in a usable quantity to a well or spring. Aquifers can be unconfined, where the top of the aquifer is defined by the
water table, or confined, where the aquifer exists underneath a confining bed. There are three aspects that control the nature of aquifers:
stratigraphy,
lithology, and geological formations and deposits. The stratigraphy relates the age and geometry of the many formations that compose the aquifer. The lithology refers to the physical components of an aquifer, such as the mineral composition and grain size. The structural features are the elements that arise due to deformations after deposition, such as fractures and folds. Understanding these aspects is paramount to understanding of how an aquifer is formed and how professionals can utilize it for groundwater engineering.
Hydraulic head Differences in hydraulic head (
h) cause water to move from one place to another; water flows from locations of high h to locations of low h. Hydraulic head is composed of pressure head (
ψ) and elevation head (
z). The head gradient is the change in hydraulic head per length of flowpath, and appears in
Darcy's law as being proportional to the discharge. Hydraulic head is a directly measurable property that can take on any value (because of the arbitrary datum involved in the
z term);
ψ can be measured with a pressure
transducer (this value can be negative, e.g., suction, but is positive in saturated aquifers), and
z can be measured relative to a surveyed datum (typically the top of the
well casing). Commonly, in wells tapping unconfined aquifers the water level in a well is used as a proxy for hydraulic head, assuming there is no vertical gradient of pressure. Often only
changes in hydraulic head through time are needed, so the constant elevation head term can be left out (
Δh = Δψ). A record of hydraulic head through time at a well is a
hydrograph or, the changes in hydraulic head recorded during the pumping of a well in a test are called
drawdown.
Porosity File:Well sorted vs poorly sorted porosity.png|thumb| [Left] High porosity,
well sorted [Right] Low porosity,
poorly sorted Porosity (
n) is a directly measurable aquifer property; it is a fraction between 0 and 1 indicating the amount of pore space between unconsolidated
soil particles or within a fractured rock. Typically, the majority of groundwater (and anything dissolved in it) moves through the porosity available to flow (sometimes called
effective porosity).
Permeability is an expression of the connectedness of the pores. For instance, an unfractured rock unit may have a high
porosity (it has many
holes between its constituent grains), but a low
permeability (none of the pores are connected). An example of this phenomenon is
pumice, which, when in its unfractured state, can make a poor aquifer. Porosity does not directly affect the distribution of hydraulic head in an aquifer, but it has a very strong effect on the migration of dissolved contaminants, since it affects groundwater flow velocities through an inversely proportional relationship.
Darcy's law is commonly applied to study the movement of water, or other fluids through porous media, and constitutes the basis for many hydrogeological analyses.
Water content Water content (
θ) is also a directly measurable property; it is the fraction of the total rock which is filled with liquid water. This is also a fraction between 0 and 1, but it must also be less than or equal to the total porosity. The water content is very important in
vadose zone hydrology, where the
hydraulic conductivity is a strongly
nonlinear function of water content; this complicates the solution of the unsaturated groundwater flow equation.
Hydraulic conductivity Hydraulic conductivity (
K) is the ease with which a
fluid (usually water) can move through the
pore space, or fracture network. Transmissivity is the product of hydraulic conductivity and the aquifer thickness (typically used as an indication of the ability of an aquifer to deliver water to a well).
Specific storage and specific yield .
Specific storage (
Ss) and its depth-integrated equivalent, storativity (
S=Ssb), are indirect aquifer properties (they cannot be measured directly); they indicate the amount of groundwater released from storage due to a unit depressurization of a confined aquifer. They are fractions between 0 and 1. Specific yield (
Sy) is also a ratio between 0 and 1 (
Sy ≤ porosity) and indicates the amount of water released due to drainage from lowering the water table in an unconfined aquifer. The value for specific yield is less than the value for porosity because some water will remain in the medium even after drainage due to intermolecular forces. Often the
porosity or effective porosity is used as an upper bound to the specific yield. Typically
Sy is orders of magnitude larger than
Ss.
Fault zone hydrogeology Fault zone hydrogeology is the study of how brittlely deformed rocks alter fluid flows in different
lithological settings, such as
clastic,
igneous and
carbonate rocks. Fluid movements, that can be quantified as
permeability, can be facilitated or impeded due to the existence of a
fault zone. This is because different mechanism and deformed rocks can alter the porosity and hence the permeability within fault zone. Fluids involved generally are
groundwater (fresh and marine waters) and
hydrocarbons (Oil and Gas). As fault zone is a zone of weakness that helps to increase the weathered zone thickness and hence the help in ground water recharge. Along with
faults,
fractures and
foliations also facilitate the groundwater mainly in hard rock terrains. Besides needing to understand where the groundwater is flowing, based on the other hydrologic properties discussed above, there are additional aquifer properties which affect how dissolved contaminants move with groundwater.
Hydrodynamic dispersion Hydrodynamic dispersivity (αL, αT) is an empirical factor which quantifies how much contaminants stray away from the path of the groundwater which is carrying it. Some of the contaminants will be "behind" or "ahead" the mean groundwater, giving rise to a longitudinal dispersivity (αL), and some will be "to the sides of" the pure advective groundwater flow, leading to a transverse dispersivity (αT). Dispersion in groundwater arises because each water "particle", passing beyond a soil particle, must choose where to go, whether left or right or up or down, so that the water "particles" (and their solute) are gradually spread in all directions around the mean path. This is the "microscopic" mechanism, on the scale of soil particles. More important, over long distances, can be the macroscopic inhomogeneities of the aquifer, which can have regions of larger or smaller permeability, so that some water can find a preferential path in one direction, some other in a different direction, so that the contaminant can be spread in a completely irregular way, like in a (three-dimensional) delta of a river. Dispersivity is actually a factor which represents our
lack of information about the system we are simulating. There are many small details about the aquifer which are effectively averaged when using a
macroscopic approach (e.g., tiny beds of gravel and clay in sand aquifers); these manifest themselves as an
apparent dispersivity. Because of this, α is often claimed to be dependent on the length scale of the problem — the dispersivity found for transport through 1 m3 of aquifer is different from that for transport through 1 cm3 of the same aquifer material.
Molecular diffusion Diffusion is a fundamental physical phenomenon, which
Albert Einstein characterized as
Brownian motion, that describes the random thermal movement of molecules and small particles in gases and liquids. It is an important phenomenon for small distances (it is essential for the achievement of
thermodynamic equilibria), but, as the time necessary to cover a distance by diffusion is proportional to the square of the distance itself, it is less effective for spreading a solute over macroscopic distances on a short time scale. The
diffusion coefficient, , is typically quite small, and its effect can often be neglected (unless groundwater flow velocities are extremely low, as they are in
clay aquitards). It is important not to confuse diffusion with dispersion, as the former is a physical phenomenon and the latter is an empirical hydrodynamic factor which is cast into a similar form as diffusion, because its a convenient way to mathematically describe and solve the question.
Retardation by adsorption The retardation factor is another very important feature that make the motion of the contaminant to deviate from the average groundwater motion. It is analogous to the
retardation factor of
chromatography. Unlike diffusion and dispersion, which simply spread the contaminant, the retardation factor changes its
global average velocity, so that it can be much slower than that of water. This is due to a chemico-physical effect: the
adsorption to the soil, which holds the contaminant back and does not allow it to progress until the quantity corresponding to the chemical adsorption equilibrium has been adsorbed. This effect is particularly important for less soluble contaminants, which thus can move even hundreds or thousands times slower than water. The effect of this phenomenon is that only more soluble species can cover long distances. The retardation factor depends on the chemical nature of both the contaminant and the aquifer. ==History and development==