'' in Paris
Early life and education Antoine-Laurent Lavoisier was born to a wealthy family of the nobility in Paris on 26 August 1743. The son of an attorney at the
Parlement of Paris, he inherited a large fortune at the age of five upon the death of his mother. Lavoisier began his schooling at the
Collège des Quatre-Nations,
University of Paris (also known as the Collège Mazarin) in Paris in 1754 at the age of 11. In his last two years (1760–1761) at the school, his scientific interests were aroused, and he studied
chemistry,
botany,
astronomy, and
mathematics. In the philosophy class he came under the tutelage of
Abbé Nicolas Louis de Lacaille, a distinguished mathematician and observational astronomer who imbued the young Lavoisier with an interest in meteorological observation, an enthusiasm which never left him. Lavoisier entered the school of law, where he received a bachelor's degree in 1763 and a licentiate in 1764. Lavoisier received a
law degree and was admitted to the
bar, but never practiced as a lawyer. However, he continued his scientific education in his spare time.
Early scientific work Lavoisier's education was filled with the ideals of the French
Enlightenment of the time, and he was fascinated by
Pierre Macquer's dictionary of chemistry. He attended lectures in the natural sciences. Lavoisier's devotion and passion for chemistry were largely influenced by
Étienne Condillac, a prominent French scholar of the 18th century. His first chemical publication appeared in 1764. From 1763 to 1767, he studied geology under
Jean-Étienne Guettard. In collaboration with Guettard, Lavoisier worked on a geological survey of
Alsace-Lorraine in June 1767. In 1764 he read his first paper to the
French Academy of Sciences, France's most elite scientific society, on the chemical and physical properties of
gypsum (hydrated
calcium sulfate), and in 1766 he was awarded a gold medal by the King for an essay on the problems of urban
street lighting. In 1768 Lavoisier received a provisional appointment to the Academy of Sciences. In 1769, he worked on the first geological map of France.
Lavoisier as a social reformer Research benefitting the public good While Lavoisier is commonly known for his contributions to the sciences, he also dedicated a significant portion of his fortune and work toward benefitting the public. Lavoisier was a humanitarian—he cared deeply about the people in his country and often concerned himself with improving the livelihood of the population by agriculture, industry, and the sciences.) It was very difficult to secure public funding for the sciences at the time, and additionally not very financially profitable for the average scientist, so Lavoisier used his wealth to open a very expensive and sophisticated laboratory in France so that aspiring scientists could study without the barriers of securing funding for their research. His participation in the collection of its taxes did not help his reputation when the
Reign of Terror began in France, as taxes and poor government reform were the primary motivators during the French Revolution. Lavoisier consolidated his social and economic position when, in 1771 at age 28, he married
Marie-Anne Pierrette Paulze, the 13-year-old daughter of a senior member of the
Ferme générale. A
portrait of Antoine and Marie-Anne Lavoisier was painted by the famed artist
Jacques-Louis David. Completed in 1788 on the eve of the Revolution, the painting was denied a customary public display at the
Paris Salon for fear that it might inflame anti-aristocratic passions. For three years following his entry into the
Ferme générale, Lavoisier's scientific activity diminished somewhat, for much of his time was taken up with official
Ferme générale business. He did, however, present one important memoir to the Academy of Sciences during this period, on the supposed conversion of water into earth by evaporation. By a very precise quantitative experiment, Lavoisier showed that the "earthy" sediment produced after long-continued reflux heating of water in a glass vessel was not due to a conversion of the water into earth but rather to the gradual disintegration of the inside of the glass vessel produced by the boiling water. He also attempted to introduce reforms in the French
monetary and taxation system to help the peasants.
Adulteration of tobacco The Farmers General held a monopoly of the production, import and sale of tobacco in France, and the taxes they levied on tobacco brought revenues of 30 million
livres a year. This revenue began to fall because of a growing black market in tobacco that was smuggled and adulterated, most commonly with ash and water. Lavoisier devised a method of checking whether ash had been mixed in with tobacco: "When a spirit of
vitriol,
aqua fortis or some other acid solution is poured on ash, there is an immediate very intense effervescent reaction, accompanied by an easily detected noise." Lavoisier also noticed that the addition of a small amount of ash improved the flavour of tobacco. Of one vendor selling adulterated goods, he wrote "His tobacco enjoys a very good reputation in the province... the very small proportion of ash that is added gives it a particularly pungent flavour that consumers look for. Perhaps the Farm could gain some advantage by adding a bit of this liquid mixture when the tobacco is fabricated." Lavoisier also found that while adding a lot of water to bulk the tobacco up would cause it to ferment and smell bad, the addition of a very small amount improved the product. Thereafter the factories of the Farmers General added, as he recommended, a consistent 6.3% of water by volume to the tobacco they processed. To allow for this addition, the Farmers General delivered to retailers seventeen ounces of tobacco while only charging for sixteen. To ensure that only these authorised amounts were added, and to exclude the black market, Lavoisier saw to it that a watertight system of checks, accounts, supervision and testing made it very difficult for retailers to source contraband tobacco or to improve their profits by bulking it up. He was energetic and rigorous in implementing this, and the systems he introduced were deeply unpopular with the tobacco retailers across the country. This unpopularity was to have consequences for him during the French Revolution.
Royal Commission on Agriculture Lavoisier urged the establishment of a Royal Commission on Agriculture. He then served as its Secretary and spent considerable sums of his own money in order to improve the agricultural yields in the
Sologne, an area where farmland was of poor quality. The humidity of the region often led to a blight of the rye harvest, causing outbreaks of
ergotism among the population. In 1788 Lavoisier presented a report to the Commission detailing ten years of efforts on his experimental farm to introduce new crops and types of livestock. His conclusion was that despite the possibilities of agricultural reforms, the tax system left tenant farmers with so little that it was unrealistic to expect them to change their traditional practices.
Gunpowder Commission (right) and mentor Antoine Lavoisier Lavoisier's researches on combustion were carried out in the midst of a very busy schedule of public and private duties, especially in connection with the
Ferme Générale. There were also innumerable reports for and committees of the Academy of Sciences to investigate specific problems on order of the royal government. Lavoisier, whose organizing skills were outstanding, frequently landed the task of writing up such official reports. In 1775 he was made one of four commissioners of gunpowder appointed to replace a private company, similar to the Ferme Générale, which had proved unsatisfactory in supplying France with its munitions requirements. As a result of his efforts, both the quantity and quality of French
gunpowder greatly improved, and it became a source of revenue for the government. His appointment to the Gunpowder Commission brought one great benefit to Lavoisier's scientific career as well. As a commissioner, he enjoyed both a house and a laboratory in the Royal Arsenal. Here he lived and worked between 1775 and 1792. Lavoisier was a formative influence in the formation of the
Du Pont gunpowder business because he trained
Éleuthère Irénée du Pont, its founder, on gunpowder-making in France; the latter said that the Du Pont gunpowder mills "would never have been started but for his kindness to me."
During the Revolution In June 1791, Lavoisier made a loan of 71,000 livres to
Pierre Samuel du Pont de Nemours to buy a printing works so that du Pont could publish a newspaper,
La Correspondance Patriotique. The plan was for this to include both reports of debates in the
National Constituent Assembly as well as papers from the Academy of Sciences. The revolution quickly disrupted the elder du Pont's first newspaper, but his son E.I. du Pont soon launched
Le Republicain and published Lavoisier's latest chemistry texts. which in March 1791 recommended the adoption of the
metric system. The new system of weights and measures was adopted by the
Convention on 1 August 1793. Lavoisier was one of the 27
Farmers General who, by order of the convention, were all to be detained. Although temporarily going into hiding, on 30 November 1793 he handed himself into the Port Royal convent for questioning. He claimed he had not operated on this commission for many years, having instead devoted himself to science. Lavoisier himself was removed from the commission on weights and measures on 23 December 1793, together with mathematician
Pierre-Simon Laplace and several other members, for political reasons. In 1792 Lavoisier was forced to resign from his post on the Gunpowder Commission and to move from his house and laboratory at the Royal Arsenal. On 8 August 1793, all the learned societies, including the Academy of Sciences, were suppressed at the request of
Abbé Grégoire. According to popular legend, the appeal to spare his life, in order that he could continue his experiments, was cut short by the judge,
Coffinhal: ''"La République n'a pas besoin de savants ni de chimistes; le cours de la justice ne peut être suspendu."'' ("The Republic needs neither scholars nor chemists; the course of justice cannot be delayed.") The judge Coffinhal himself would be executed less than three months later, in the wake of the
Thermidorian reaction. Lavoisier's importance to science was expressed by Lagrange who lamented the beheading by saying: ''"Il ne leur a fallu qu'un moment pour faire tomber cette tête, et cent années peut-être ne suffiront pas pour en reproduire une semblable."'' ("It took them only an instant to cut off this head, and a hundred years might not suffice to reproduce its like.")
Exoneration A year and a half after his execution, Lavoisier was completely exonerated by the French government. During the
White Terror, his belongings were delivered to his widow. A brief note was included, reading "To the widow of Lavoisier, who was falsely convicted".
Blinking experiment An
apocryphal story exists regarding Lavoisier's execution in which the scientist blinked his eyes to demonstrate that the head retained some consciousness after being severed. Some variants of the story include
Joseph-Louis Lagrange as being the scientist to observe and record Lavoisier's blinking. This story was not recorded in contemporary accounts of Lavoisier's death, and the execution site was too removed from the public for Lagrange to have viewed Lavoisier's alleged experiment. The story likely originated in a 1990s
Discovery Channel documentary about guillotines and then subsequently spread online, becoming what one source describes as an
urban legend. ==Contributions to chemistry==